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Wood Adhesives Based on Alkaline Extracts from Wastewater Biosolids and Mustard Protein

Journal of the American Oil Chemists' Society volume 89, pages 1315–1323 (2012)Cite this article

Abstract

This work reports on the dry adhesion strength of wood adhesives formulated with fractions of an alkaline extract obtained from wastewater activated sludge, a renewable and abundant resource. The extract was fractionated and desalted using ultrafiltration techniques. The effect of molecular weight and composition (protein and carbohydrate content) on the extract’s adhesion strength was assessed, as well as the effect of crosslinking using glutaraldehyde. The dry adhesion strength of adhesives formulated with soluble mustard seed protein isolate, a protein-rich alkaline extract, is also reported. In the presence of glutaraldehyde, an extract fraction with high protein content and low salt and hydroxide content showed adhesion strength close to that of the mustard protein adhesive and a commercial wood adhesive. It was further determined that the adhesion strength of the extract and its fractions was strongly correlated with their protein content.

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References

  1. Wang WH, Li XP, Zhang XQ (2008) A soy-based adhesive from basic modification. Pigment Resin Technol 37:93–97

    Article  Google Scholar 

  2. Wang Y, Mo X, Sun XS, Wang D (2007) Soy protein adhesion enhanced by glutaraldehyde crosslink. J Appl Polym Sci 104:130–136

    Article  CAS  Google Scholar 

  3. Haag AP (2006) Mechanical properties of bacterial exopolymeric adhesives and their commercial development. In: Smith AM, Callow JA (eds) Biological adhesives. Springer, Berlin, pp 1–19

    Chapter  Google Scholar 

  4. Park SK, Bae DH, Hettiarachchy NS (2000) Protein concentrate and adhesives from meat and bone meal. J Am Oil Chem Soc 77:1223–1227

    Article  CAS  Google Scholar 

  5. Kalapathy U, Hettiarachchy NS, Myers D, Hanna MA (1995) Modification of soy proteins and their adhesive properties on woods. J Am Oil Chem Soc 72:507–510

    Article  CAS  Google Scholar 

  6. Haag AP, Maier RM, Combie J, Geesey GG (2004) Bacterially derived biopolymers as wood adhesives. Int J Adhes Adhes 24:495–502

    Article  CAS  Google Scholar 

  7. Sellers T (2001) Wood adhesive innovations and applications in North America. For Prod J 51:12–72

    CAS  Google Scholar 

  8. Odozi TO, Agiri GO (1986) Wood adhesives from modified red onion skin tannin extract. Agric Wastes 17:59–65

    Article  CAS  Google Scholar 

  9. Liu Y, Li K (2002) Chemical modification of soy protein for wood adhesives. Macromol Rapid Commun 23:739–742

    Article  CAS  Google Scholar 

  10. Zhang Z, Hua Y (2007) Urea-modified soy globulin proteins (7S and 11S): effect of wettability and secondary structure on adhesion. J Am Oil Chem Soc 84:853–857

    Article  CAS  Google Scholar 

  11. Jiang Z, Qin D, Hse C, Kuo M, Luo Z, Wang G, Yu Y (2008) Preliminary study on chicken feather protein–based wood adhesives. J Wood Chem Technol 28:240–246

    Article  CAS  Google Scholar 

  12. Akaranta O, Wankasi D (1998) Development of wood adhesives using flavonoid-glycosides from orange mesocarp. Pigment Resin Technol 27:175–179

    Article  CAS  Google Scholar 

  13. Akaranta O, Donbebe W, Odozi TO (1996) Plywood adhesives based on red-onion-skin extract modified with cashewnut-shell liquid. Bioresour Technol 56:279–280

    Article  Google Scholar 

  14. Weimer PJ, Conner AH, Lorenz LF (2003) Solid residues from Ruminococcus cellulose fermentations as components of wood adhesive formulations. Appl Microbiol Biotechnol 63:29–34

    Article  CAS  Google Scholar 

  15. Weimer PJ, Koegel RG, Lorenz LF, Frihart CR, Kenealy WR (2005) Wood adhesives prepared from lucerne fiber fermentation residues of Ruminococcus albus and Clostridium thermocellum. Appl Microbiol Biotechnol 66:635–640

    Article  CAS  Google Scholar 

  16. Combie J, Steel A, Sweitzer R (2004) Adhesive designed by nature (and tested at Redstone Arsenal). Clean Technol Environ Policy 6:258–262

    Article  CAS  Google Scholar 

  17. Haag AP, Geesey GG, Mittleman MW (2006) Bacterially derived wood adhesive. Int J Adhes Adhes 26:177–183

    Article  CAS  Google Scholar 

  18. Barker DJ, Stuckey DC (1999) A review of soluble microbial products (SMP) in wastewater treatment systems. Water Res 33:3063–3082

    Article  CAS  Google Scholar 

  19. Frølund B, Palmgren R, Keiding K, Nielsen PH (1996) Extraction of extracellular polymers from activated sludge using a cation exchange resin. Water Res 30:1749–1758

    Article  Google Scholar 

  20. Kroiss H (2004) What is the potential for utilizing the resources in sludge? Water Sci Technol 49:1–10

    CAS  Google Scholar 

  21. Reddy N, Tan Y, Li Y, Yang Y (2008) Effect of glutaraldehyde crosslinking conditions on the strength and water stability of wheat gluten fibers. Macromol Mater Eng 293:614–620

    Article  CAS  Google Scholar 

  22. Hopwood D (1969) A comparison of the crosslinking abilities of glutaraldehyde, formaldehyde and α-hydroxyadipaldehyde with bovine serum albumin and casein. Histochem Cell Biol 17:151–161

    CAS  Google Scholar 

  23. Xiao Z, Xie Y, Militz H, Mai C (2010) Effect of glutaraldehyde on water related properties of solid wood. Holzforschung 64:483–488

    Article  CAS  Google Scholar 

  24. García-Becerra FY, Acosta EJ, Allen DG (2010) Alkaline extraction of wastewater activated sludge biosolids. Bioresour Technol 101:6983–6991

    Article  Google Scholar 

  25. Marnoch R, Diosady LL (2006) Production of mustard protein isolates from oriental mustard seed (Brassica juncea L.). J Am Oil Chem Soc 83:65–69

    Article  CAS  Google Scholar 

  26. Wanasundara JPD (2011) Proteins of Brassicaceae oilseeds and their potential as a plant protein source. Crit Rev Food Sci Nutr 51:635–677

    Article  CAS  Google Scholar 

  27. Musale DA, Kulkarni SS (1998) Effect of membrane-solute interaction on ultrafiltration performance. J Macromol Sci Rev Macromol Chem Phys 4:615–636

    Article  Google Scholar 

  28. Musale DA, Kulkarni SS (1997) Relative rates of protein transmission through poly(acrylonitrile) based ultrafiltration membranes. J Membr Sci 136:13–23

    Article  CAS  Google Scholar 

  29. Jones KL, O’Melia CR (2000) Protein and humic acid adsorption onto hydrophilic membrane surfaces: effects of pH and ionic strength. J Membr Sci 165:31–46

    Article  CAS  Google Scholar 

  30. Hettiarachchy NS, Kalapathy U, Myers DJ (1995) Alkali-modified soy protein with improved adhesive and hydrophobic properties. J Am Oil Chem Soc 72:1461–1464

    Article  CAS  Google Scholar 

  31. Masuko T, Minami A, Iwasaki N, Majima T, Nishimura SI, Lee YC (2005) Carbohydrate analysis by a phenol-sulfuric acid method in microplate format. Anal Biochem 339:69–72

    Article  CAS  Google Scholar 

  32. Garcia-Becerra FY, Allen DG, Acosta EJ (2010) Surfactant-like properties of alkaline extracts from wastewater biosolids. J Surfactants Deterg 13:261–271

    Article  Google Scholar 

  33. Foley G (1999) Minimisation of process time in ultrafiltration and continuous diafiltration: the effect of incomplete macrosolute rejection. J Membr Sci 163:349–355

    Article  CAS  Google Scholar 

  34. Piccolo A (2001) The supramolecular structure of humic substances. Soil Sci 166:810–832

    Article  CAS  Google Scholar 

  35. Liu H, Fang HHP (2002) Extraction of extracellular polymeric substances (EPS) of sludges. J Biotechnol 95:249–256

    Article  CAS  Google Scholar 

  36. Kalapathy U, Hettiarachchy NS, Myers D, Rhee KC (1996) Alkali-modified soy proteins: effect of salts and disulfide bond cleavage on adhesion and viscosity. J Am Oil Chem Soc 73:1063–1066

    Article  CAS  Google Scholar 

  37. Ibañez MC, Ferrero C (2003) Extraction and characterization of the hydrocolloid from Prosopis flexuosa DC seeds. Food Res Int 36:455–460

    Article  Google Scholar 

  38. Kato A (2002) Industrial applications of maillard-type protein-polysaccharide conjugates. Food Sci Technol Res 8:193–199

    Article  CAS  Google Scholar 

Download references

Acknowledgments

The authors gratefully acknowledge the financial support from the Ontario Ministry of Economic Development and Innovation, Early Researcher Award program to E. Acosta, and from the Natural Sciences and Engineering Research Council of Canada (NSERC).

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Authors and Affiliations

  1. Department of Chemical Engineering and Applied Chemistry, University of Toronto, 200 College Street, Room 131, Toronto, ON, M5S3E5, Canada

    Flor Y. García-Becerra, Edgar J. Acosta & D. Grant Allen

Authors
  1. Flor Y. García-Becerra
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  2. Edgar J. Acosta
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  3. D. Grant Allen
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Correspondence to Edgar J. Acosta.

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García-Becerra, F.Y., Acosta, E.J. & Grant Allen, D. Wood Adhesives Based on Alkaline Extracts from Wastewater Biosolids and Mustard Protein. J Am Oil Chem Soc 89, 1315–1323 (2012). https://doi.org/10.1007/s11746-012-2024-z

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  • DOI: https://doi.org/10.1007/s11746-012-2024-z

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