Abstract
The ethanolysis of refined soybean oil was investigated through a 23 experimental design that was carried out under the following levels: ethanol:oil molar ratios (MR) of 6:1 and 12:1, NaOH concentrations of 0.3 and 1.0 wt% in relation to the oil mass, and reaction temperatures of 30 and 70 °C. The ethanol:oil MR and the alkali concentration had an almost equivalent influence on the reaction yield, whereas the influence of increased reaction temperatures was very limited and higher catalyst concentrations led to greater yield losses due to the formation of soap. Ethyl ester yields of 97.2% were obtained at 70 °C, MR of 12:1 and 0.3 wt% NaOH. Replacement of 0.3 wt% NaOH by 1.0 wt% KOH under the same reaction conditions led to lower ester yields. Likewise the former, KOH provided the maximum ester yield (95.6%) at the highest molar ratio (12:1), with the reaction temperature having little influence on the catalyst performance. Ester yields beyond 98% were only achieved when a second ethanolysis stage was included in the process. In this regard, the application of 2 wt% Magnesol® after the first ethanolysis stage eliminated the need for water washing prior to the second ethanolysis stage and helped to generate a final product with less contaminating unreacted glycerides.
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References
Ramos LP, Wilhelm HM (2005) Current status of biodiesel development in Brazil. Appl Biochem Biotechnol 121–124:807–820
Ma F, Hanna M (1999) Biodiesel production: a review. Biores Technol 70:1–15
Schuchardt U, Sercheli R, Vargas RM (1998) Transesterification of vegetable oils: a review. J Braz Chem Soc 9:199–210
Van Gerpen J, Knothe G (2004) Basics of the transesterification reaction. In: Knothe G, Krahl J, Van Gerpen J (eds) The biodiesel handbook. AOCS Press, Champaign, pp 26–41
Zhang Y, Dube MA, Mclean DD, Kates M (2003) Biodiesel production from waste cooking oil: 1. Process design and technological assessment. Biores Technol 89:1–16
Barnwal BK, Sharma MP (2005) Prospects of biodiesel production from vegetable oils in India. Renew Sustain Energy Rev 9:363–378
Freedman B, Pryde EH, Mounts TL (1984) Variables affecting the yields of fatty esters from transesterified vegetable oils. J Am Oil Chem Soc 61:1638–1643
Freedman B, Butterfield R, Pryde EH (1986) Transesterification kinetics of soybean oil. J Am Oil Chem Soc 63:1375–1380
Zagonel GF, Ramos LP (2003) Estudo de Otimização da Reação de Transesterificação Etílica do Óleo de Soja Degomado. Sci Technol J 1:35–43
Domingos AK, Saad EB, Wilhelm HM, Ramos LP (2005) Response surface methodology as a tool to optimize the ethanolysis of crude vegetable oils. In: Proceedings of the XI Congreso Latinoamericano de Grasas y Aceites, Buenos Aires, pp 318–321
Cordeiro CS (2003) Síntese e Caracterização de Biodiesel Etílico para Utilização em Motores do Ciclo Diesel. MSc Dissertation, Engineering, Federal University of Technology of Paraná, Curitiba, p 99
Vicente G, Martínez M, Aracil J (2004) Integrated biodiesel production: a comparison of different homogeneous catalysts systems. Biores Technol 92:297–305
Mittelbach M, Tritthart P, Junek H (1985) Diesel fuel derived from vegetable oils, II: Emission tests using rape oil methyl ester. Energy Agric 4:207–215
Ramos LP, Domingos AK, Kucek KT, Wilhelm HM (2003) Biodiesel: Um Projeto de Sustentabilidade Econômica e Sócio-ambiental para o Brasil. Biotecnol Ciência Desenvolvimento 31:28–37
Abiove, Associação Brasileira dos Produtores de Óleos Vegetais. http://www.abiove.com.br. Accessed September 2005
ANP, Agência Nacional do Petróleo, Resolução 42. http://www.anp.gov.br. Accessed November 2005
Lang X, Dalai AK, Bakhshi NN, Reaney MJ, Hertz PB (2001) Preparation and characterization of bio-diesels from various bio-oils. Biores Technol 80:53–62
ASTM, American Society Testing Methods, D6751: Standard specification for biodiesel fuel (B100) blend stock for distillate fuels, USA (2003)
Cooke BS, Abrams C, Bertram B (2003) Purification of biodiesel with adsorbent materials. US Patent 0509959P
Acknowledgments
This work was supported in part by research grants from LACTEC (Instituto de Tecnologia para o Desenvolvimento), CNPq (Conselho Nacional de Desenvolvimento Científico e Tecnológico), Fundação Araucária and Corn Products Brazil.
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Kucek, K.T., César-Oliveira, M.A.F., Wilhelm, H.M. et al. Ethanolysis of Refined Soybean Oil Assisted by Sodium and Potassium Hydroxides. J Amer Oil Chem Soc 84, 385–392 (2007). https://doi.org/10.1007/s11746-007-1048-2
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DOI: https://doi.org/10.1007/s11746-007-1048-2