Skip to main content
Log in

Trans FA in sunflower oil at different steps of refining

  • Published:
Journal of the American Oil Chemists' Society

Abstract

The contents of total trans FA of sunflower oils at different stages of refining processes were determined by capillary GLC. The contents of 18∶1, 18∶2, and 18∶3 trans acids were 0.22±0.03, 2.31±0.23, and 0.03±0.01%, respectively, in physically refined sunflower oils, and 0.05±0.01, 0.69±0.26, and 0.02±0.01%, respectively, in chemically refined sunflower oils. The total trans FA contents drastically increased at the end of the physical refining process. The total trans FA contents of chemically refined sunflower oils were <1%. Because of the high temperature applied in the last stage of physical refining, the content of total trans FA was higher than in chemically refined sunflower oils. The last-stage conditions should be carefully evaluated to reduce the formation of trans FA during physical refining.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. Cvengros, J., Physical Refining of Edible Oils, J. Am. Oil Chem. Soc. 72:1193–1196 (1995).

    CAS  Google Scholar 

  2. Jawad I.M., S.P. Kochhar, and B.J.F. Hudson, Quality Characteristics of Physically Refined Soya Bean Oil: Effects of Pretreatment and Processing Time and Temperature, J. Food Technol. 18:353–360 (1983).

    Article  CAS  Google Scholar 

  3. Karaali, A., The Effects of Refining on the Chemical Composition of Turkish Sunflower Seed Oil, Fette Seifen Anstrichm. 87:112–117 (1985).

    Article  CAS  Google Scholar 

  4. Hénon G., Z. Kemény, K. Recseg, F. Zwobada, and K. Kővári, Degradation of α-Linolenic Acid During Heating, J. Am. Oil Chem. Soc. 74:1615–1617 (1997).

    Google Scholar 

  5. Ruiz-Mendez, M.V., G. Marquez-Ruiz, and M.C. Dobarganes, Relationships Between Quality of Crude and Refined Edible Oils Based on Quantitation of Minor Glyceridic Compounds, Food Chem. 60:549–554 (1997).

    Article  CAS  Google Scholar 

  6. Schwarz, W., Formation of trans Polyalkenoic Fatty acids During Vegetable Oil Refining, Eur. J. Lipid Sci. Technol. 102: 648–649 (2000).

    Article  CAS  Google Scholar 

  7. Kellens, M., Current Developments in Oil Refining Technology, Technical Report De Smet-Belgium, Antwerp, Belgium, 1997, pp. 35–48.

  8. Official Methods and Recommended Practices of the American Oil Chemists’ Society, 4th edn., American Oil Chemists’ Society, Champaign, 1992, Method Ce 2-66.

  9. Ferrari, R.Ap., E. Schulte, W. Esteves, L. Brühl, and K.D. Mukherjee, Minor Constituents of Vegetable Oils During Industrial Processing, J. Am. Oil Chem. Soc. 73:587–592 (1996).

    CAS  Google Scholar 

  10. Bruehl, L., Determination of trans Fatty Acids in Cold Pressed Oils and in Dried Seed, Fett/Lipid 98:380–383 (1996).

    Article  CAS  Google Scholar 

  11. Wolff, R.L., Further Studies on Artificial Geometrical Isomers of α-Linolenic Acid in Edible Linolenic Acid-Containing Oils, J. Am. Oil Chem. Soc. 70:219–224 (1993).

    CAS  Google Scholar 

  12. Segers, J.C., Pretreatment of Edible Oils for Physical Refining, Ibid. 60:214A-216A (1983).

    Google Scholar 

  13. Jawad, I.M., S.P. Kochhar, and B.J.F. Hudson, The Physical Refining of Edible Oils. 1: Effect on Component Fatty Acids and on Triglycerides, Food Sci. Technol. 17:289–293 (1983).

    Google Scholar 

  14. Ackman, R.G., and S.N. Hooper, Linolenic Acid artifacts from the Deodorization of Oil, J. Am. Oil Chem. Soc. 51:42–49 (1974).

    CAS  Google Scholar 

  15. Čmolik, J., W. Schwarz, Z. Svoboda, J. Pokorný, Z. Réblová, M. Doležal, and H. Valentová, Effect of Plant-Scale Alkali Refining and Physical Refining on the Quality of Rapeseed Oil, Eur. J. Lipid Sci. Technol. 102:15–22 (2000).

    Article  Google Scholar 

  16. Greyt, W., O. Radanyi, M. Kellens, and A. Huyghebaert, Contribution of trans-Fatty Acids from Vegetable Oils and Margarines to the Belgian Diet, Fett/Lipid 98:30–33 (1996).

    Article  Google Scholar 

  17. Bruggen, P.C., G.S.M.J.E. Duchateau, M.M.W. Mooren, and H.J. van Oosten, Precision of Low trans Fatty Acid Level Determination in Refined Oils. Results of a Collaborative Capillary Gas-Liquid Chromatography Study, J. Am. Oil Chem. Soc. 75:483–488 (1998).

    Google Scholar 

  18. Hénon, G., Z. Kemény, K. Recseg, F. Zwobada, and K. Kővári, Deodorization of Vegetable Oils. Part I: Modeling the Geometrical Isomerization of Polyunsaturated Fatty Acids, Ibid. 76:73–81 (1999).

    Google Scholar 

  19. Wollf, R.L., Cis-trans Isomerization of Octadecatrieonic Acids During Heating. Study of Pinolenic (cis-5, cis-9, cis-12 18∶3) Acid Geometrical Isomers in Heated Pine Seed Oil, Ibid. 71:1129–1134 (1994).

    Google Scholar 

  20. Aro, A., J. Van Amelsvoort, W. Becker, M.A. van Erp-Baart, A. Kafatos, T. Leth, and G. van Poppels, Trans Fatty Acids in Dietary Fats and Oils from 14 European Countries: The TRANS-FAIR Study, J. Food Compos. Anal. 11:150–160 (1998).

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Murat Tasan.

About this article

Cite this article

Tasan, M., Demirci, M. Trans FA in sunflower oil at different steps of refining. J Amer Oil Chem Soc 80, 825–828 (2003). https://doi.org/10.1007/s11746-003-0779-9

Download citation

  • Received:

  • Accepted:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11746-003-0779-9

Key Words

Navigation