Abstract
The original purpose of our work was finding commercial foaming agents for high-salinity reservoirs. During the study, the commercial lauramide amide oxide solution displayed different foaming properties in high-salinity water (salinity 220,000 mg/L) at different aging times and relatively low temperature (25 °C). Foam volume decreases drastically first with the increase of aging time. Then, with further aging, foam volume increases. However, in low-salinity water or at high temperature, no obvious foam volume variation was observed. Lauric acid in the commercial surfactant plays a key role. Under proper temperature and pH conditions, lauric acid will react with Ca2+. Calcium laurate generated from lauric acid in the commercial form and Ca2+ from water influences the foaming property significantly. At the beginning of calcium laurate generation, surfactants adsorb on calcium laurate and decelerate the diffusion velocity of lauramide amide oxide from the bulk phase to the air–water interface. With the increase of aging time, calcium laurate gathers, thus adsorption of lauramide amide oxide by calcium laurate decreases. Hence, the foaming volume increases.
References
Maeda H, Muroi S, Ishii M, et al. Effects of ionization on the critical micelle concentration and the surface excess of dodecyl dimethylamine oxide in salt solutions. J Colloid Interface Sci. 1995;175:497–505.
Zhao J, Dai C, Fang J, et al. Surface properties and adsorption behavior of cocamidopropyl dimethyl amine oxide under high temperature and high salinity conditions. Colloids Surf A. 2014;450:93–8.
Ge J, Wang Y. Surfactant enhanced oil recovery in a high temperature and high salinity carbonate reservoir. J Surfactants Deterg. 2015;18:1043–50.
Wang Y, Ge J, Zhang G, et al. Adsorption behavior of dodecyl hydroxypropyl sulfobetaine on limestone in high salinity water. RSC Adv. 2015;5:59738–44.
Kovscek AR, Radke CJ. Fundamentals of foam transport in porous media. In: Schramm LL, editor. Foams: fundamentals and applications in the petroleum industry. Washington, DC: American Chemical Society; 1994. p. 115–63.
Rosen MJ, Kunjappu JT. Surfactants and interfacial phenomena. New york: Wiley; 2012. p. 262.
Acknowledgements
Financial support by the National Natural Science Foundation of China (51574266 and 51474234) and the Natural Science Foundation of Shandong Province (no. ZR2011EEQ001, ZR2012EEM007) and the Fundamental Research Funds for the Central Universities (14CX06088A) and ‘‘Innovation Project of China University of Petroleum’’ (YCX2015012) are gratefully acknowledged.
Author information
Authors and Affiliations
Corresponding author
About this article
Cite this article
Wang, Y., Ge, J. & Zhang, G. Foaming Properties of Commercial Lauramide Amide Oxide in High-Salinity Water. J Surfact Deterg 20, 755–760 (2017). https://doi.org/10.1007/s11743-017-1944-x
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s11743-017-1944-x