Abstract
The inhibition effect of new synthesized amphoteric and di-cationic surfactants, namely: 4-((((1-dodecylpyridin-1-ium bromide)-4-yl)methylene)amino)benzoate sodium (I) and 1-dodecyl-4-(((1-dodecylpyridin-1-ium-4-yl)imino)methyl)pyridin-1-ium bromide (II), respectively, on the corrosion of carbon steel in 1 M HCl have been investigated using electrochemical impedance spectroscopy, Tafel polarization and weight loss measurements. The inhibition efficiencies obtained from all methods employed are in good agreement with each other. Tafel polarization studies showed that the surfactants are mixed type inhibitors. The adsorption of two compounds onto the surface of carbon steel in 1 M HCl obeys the Langmuir isotherm. Adsorption thermodynamic parameters reveal that the adsorption of inhibitors is a mixture of physical and chemical adsorption.
Similar content being viewed by others
References
Prabakaran M, Vadivu K, Ramesh S, Periasamy V (2014) Enhanced corrosion resistance properties of mild steel in neutral aqueous solution by new ternary inhibitor system. J Mater Environ Sci 5:553–564
Hegazy MA, El-Tabei AS, Ahmed HM (2012) Synthesis of nonionic surfactants and their inhibitive action on carbon steel in hydrochloric acid. Corros Sci 64:115–125
Chakravarthy MP, Mohana KN (2013) Inhibition behaviour of some isonicotinic acid hydrazides on the corrosion of mild steel in hydrochloric acid solution. Int J Corros 2013:1–13
Hegazy MA, Atlam FM (2016) Three novel bolaamphiphiles as corrosion inhibitors for carbon steel in hydrochloric acid: experimental and computational studies. J Mol Liq 218:649–662
El-Tabei AS, Hegazy MA, Bedair AH, Sadeq MA (2014) Synthesis and inhibition effect of a novel Tri-cationic surfactant on carbon steel corrosion in 0.5 M H2SO4 solution. J Surfact Deterg 17:341–352
Hegazy MA, El-Etre AY, El-Shafaie M, Berry KM (2016) Novel cationic surfactants for corrosion inhibition of carbon steel pipelines in oil and gas wells applications. J Mol Liq 214:347–356
Negm NA, Badr EA, Tawfik SM, El Farargy AM (2014) Performance of nonionic surfactants derived from tannic acid in preventing the acidic dissolution of carbon steel. J Appl Chem 7:31–42
Zarrok H, Zarrouk A, Salghi R, Ramli Y, Hammouti B, Al-Deyab SS, Essassi EM, Oudda H (2012) Adsorption and Inhibition effect of 3-methyl-1-propargylquinoxalin-2(1H)-one on carbon steel corrosion in hydrochloric acid. Int J Electrochem Sci 7:8958–80973
Fouda AS, Attia AA, Negm AA (2014) Some thiophene derivatives as corrosion inhibitors for carbon steel in hydrochloric acid. J Metallurgy 2014:15
Karthikaiselvia R, Subhashini S (2014) Study of adsorption properties and inhibition of mild steel corrosion in hydrochloric acid media by water soluble composite poly (vinyl alcohol-o-methoxy aniline). J Assoc Arab Univ Basic Appl Sci 16:74–82
Hazzazi OA, Abdallah M, Gad EAM (2014) Inhibition effect of some cationic surfactants on the corrosion of carbon steel in sulphuric acid solutions: surface and structural properties. Int J Electrochem Sci 9:2237–2253
Issaadi S, Douadi T, Zouaoui A, Chafaa S, Khan MA, Bouet G (2011) Novel thiophene symmetrical Schiff base compounds as corrosion inhibitor for mild steel in acidic media. Corros Sci 53:1484–1488
Abdallah M, Al Jahdaly BA, Sobhi M, Ali AI (2015) Evaluation of some nonionic surfactants derived from hydroquinol compounds as corrosion inhibitors for carbon steel in hydrochloric acid. Int J Electrochem Sci 10:4482–4494
Fouda AS, Farahat MM, Abdallah M (2014) Cephalosporin antibiotics as new corrosion inhibitor for nickel in HCl solution. Res Chem Intermed 40:1249–1266
Abdallah M, Al Jahdaly BA, Al-Malyo OA (2015) Corrosion inhibition of carbon steel in hydrochloric acid solution using non-ionic surfactants derived from phenol compounds. Int J Electrochem Sci 10:2740–2754
Aysel Y, Özlem A (2011) Diphenolic Schiff bases as corrosion inhibitors for aluminum in 0.1 M HCl: potentiodynamic polarization and EQCM investigations. Corros Sci 53:3725–3732
Fouda AS, Abdallah M, Medhat M (2012) Some Schiff base compounds as inhibitors for corrosion of carbon steel in acidic media. Prot Met Phys Chem Surf 48:477–486
Saravanamoorthy S, Velmathi S (2013) Physiochemical interactions of chiral Schiff bases on high carbon steel surface: corrosion inhibition in acidic media. Prog Org Coat 76:1527–1535
Popova A, Christov M, Vasilev A (2011) Mono- and dicationic benzothiazolic quaternary ammonium bromides as mild steel corrosion inhibitors. Part II: electrochemical impedance and polarisation resistance results. Corros Sci 53:1770–1777
Hegazy MA, Abd El-Rehim SS, Badr EA, Kamel WM, Youssif AH (2015) Mono-, di- and tetra-cationic surfactants as carbon steel corrosion inhibitors. J Surfact Deterg 18:1033–1042
Popova A, Christov M, Vasilev A (2015) Mono- and dicationic benzothiazolic quaternary ammonium bromides as mild steel corrosion inhibitors. Part III: influence of the temperature on the inhibition process. Corros Sci 94:70–78
Hegazy MA, Abdallah M, Awad MK, Rezk M (2014) Three novel di-quaternary ammonium salts as corrosion inhibitors for API X65 steel pipeline in acidic solution. Part I: experimental results. Corros Sci 81:54–64
Labena A, Hegazy MA, Horn H, Müller E (2015) The biocidal effect of a novel synthesized gemini surfactant on environmental sulfidogenic bacteria: planktonic cells and biofilms. Mater Sci Eng 47:367–375
Khalaf AI, Hegazy MA (2013) Synthesis and characterization of cationic surfactants for preparation of organobentonite and study their effeteness on the properties of styrene butadiene rubber/bentonite composites. High Perform Polym 25:115–125
Labena A, Hegazy MA, Horn H, Müller E (2014) Cationic gemini surfactant as a corrosion inhibitor and a biocide for high salinity sulfidogenic bacteria originating from an oil-field water tank. J Surfact Deterg 17:419–431
Nabel NA, Nadia GK, Emad AB, Mohammed AM (2012) Gravimetric and electrochemical evaluation of environmentally friendly nonionic corrosion inhibitors for carbon steel in 1 M HCl. Corros Sci 65:94–103
Noor El-Din MR, Al-Sabagh AM, Hegazy MA (2012) Study of the inhibition efficiency for some novel surfactants on the carbon steel (Type H-11) pipelines in 0.5 M HCl solution by potentiodynamic technique. J Disp Sci Technol 33:1444–1451
El-Tabei AS, Hegazy MA (2015) Synthesis and characterization of a novel nonionic gemini surfactant as corrosion inhibitor for carbon steel in acidic solution. Chem Eng Commun 7:851–863
Hegazy MA, Aiad I (2015) 1-Dodecyl-4-(((3-morpholinopropyl)imino) methyl)pyridin-1-ium bromide as a novel corrosion inhibitor for carbon steel during phosphoric acid production. J Ind Eng Chem 31:91–99
Chitra S, Parameswari K, Sivakami C, Selvaraj A (2010) Sulpha Schiff Bases as corrosion inhibitors for mild steel in 1 M sulphuric acid. Chem Eng Res Bull 14:1–6
Obot IB, Obi-Egbedi NO, Odozi NW (2010) Acenaphtho[1,2-b]quinoxaline as a novel corrosion inhibitor for mild steel in 0.5 M H2SO4. Corros Sci 52:923–926
El-Tabei AS, Hegazy MA (2014) Application of the synthesized novel 3,6,9,12,15,18,21-heptaoxatricosane-1,23-diylbis(4-((4 (dimethylamino) benzylidene) amino)benzoate) as a corrosion inhibitor for carbon steel in acidic media. J Disp Sci Technol 35:1289–1299
Hegazy MA (2015) Novel cationic surfactant based on triazole as a corrosion inhibitor for carbon steel in phosphoric acid produced by dihydrate wet process. J Mol Liq 208:227–236
Fouda AS, El-desoky AM, Ead DM (2013) Anhydride derivatives as corrosion Inhibitors for carbon steel in hydrochloric acid solutions. Int J Electrochem Sci 8:8823–8847
Hegazy MA, Abd El Rehim SS, Badawi AM, Ahmed MY (2015) Studying the corrosion inhibition of carbon steel in hydrochloric acid solution by 1-dodecyl-methyl-1H-benzo[d][1,2,3]triazole-1-ium bromide. RSC Adv 5:49070–49079
Fouda AS, El-Desoky AM, Diab MA, Soliman AH (2014) Corrosion protection of carbon steel in hydrochloric acid solutions using heterocyclic compounds. Int J Adv Res 2:606–628
Hegazy MA, Nazeer AA, Shalabi K (2015) Electrochemical studies on the inhibition behavior of copper corrosion in pickling acid using quaternary ammonium salts. J Mol Liq 209:419–427
Mobin M, Sheerin M (2012) Alkanediyl-α,ω-bis(dimethyl cetylammonium bromide) gemini surfactants as novel corrosion inhibitors for mild steel in formic acid. Eletrochim Acta 15:837–847
El-Etre AY, Abd El Wanees S, Abdel Hamid Z, Fareed M (2015) Comparison of the corrosion inhibition by drugs for the corrosion of nickel in hydrochloric acid. J Am Sci 11:20–27
Ramazan S, Ece A, Gülfeza K (2011) Adsorption and corrosion inhibition effect of 2-((5-mercapto-1,3,4-thiadiazol-2-ylimino)methyl)phenol Schiff base on mild steel. Mater Chem Phys 125:796–801
Hegazy MA, Azzam EMS, Kandil NG, Badawi AM, Sami RM (2016) The performance of hydrophobic and hydrophilic moieties in synthesized thiol cationic surfactants on corrosion inhibition of carbon steel in HCl. Egypt J Petrol 24:493–503
Alizadeh A, Khamehchi E (2015) Modeling of micro-bubble surfactant multi-layer drilling fluid stability based on single bubble behavior under pressure and temperature in a deviated gas well. J Nat Gas Sci Eng 26:42–50
Gadow HS, Fouda AS (2014) Black tea as green corrosion inhibitor for carbon steel in 1 M hydrochloric acid solutions. Int J Adv Res 2:233–243
Abiola OK, James AO (2010) The effects of Aloe vera extract on corrosion and kinetics of corrosion process of zinc in HCl solution. Corros Sci 52:661–664
Alizadeh A, Khamehchi E (2015) A model for predicting size distribution and liquid drainage from micro-bubble surfactant multi-layer fluids using population balance. Colloid Polym Sci 293:3419–3427
Ahmad Al-Haj-Ali M, Nabeel Jarrah A, Mu’Azu NA, Rihan RO (2014) Thermodynamics and kinetics of inhibition of aluminum in hydrochloric acid by date palm leaf extract. J Appl Sci Environ Manag 18:543–551
Athareh D, Fatemeh B (2011) A new synthesized corrosion inhibitor for mild steel in 0.5 M H2SO4. GU J Sci 24:219–226
Ambrish S, Ebenso EE (2013) Use of glutamine as a new and effective corrosion inhibitor for mild steel in 1 M HCl Solution. Int J Electrochem Sci 8:12874–12883
Hegazy MA, Rashwan SM, Kamel MM, El Kotb MS (2015) Synthesis, surface properties and inhibition behavior of novel cationic gemini surfactant for corrosion of carbon steel tubes in acidic solution. J Mol Liq 211:126–134
Hegazy MA, El-Tabei AS, Bedair AH, Sadeq MA (2015) Synthesis and inhibitive performance of novel cationic and gemini surfactants on carbon steel corrosion in 0.5 M H2SO4 solution. RSC Adv 5:64633–64650
Hegazy MA, Abd El-Rehim SS, Badr EA, Kamel WM, Ahmed HY (2015) Mono-, di- and tetra-cationic surfactants as carbon steel corrosion inhibitors. J Surfact Deterg 18:1033–1042
Javadian S, Ruhi V, Asadzadeh Shahir A, Heydari A, Akbari J (2013) Imidazolium-based ionic liquids as modulators of physicochemical properties and nanostructures of CTAB in aqueous solution: the effect of alkyl chain length, hydrogen bonding capacity, and anion type. Ind Eng Chem Res 52:15838–15846
Adawy IA, Badr AE (2014) Synthesis and biological activity of some amide-based cationic surfactant complexes with Co (II) and Cu (II). J Appl Chem 7:9–19
El-Sukkary MMA, Shaker NO, Ismail DA, Ahmed SM, Zaki MF, Awad AI (2012) Surface parameters, biodegradability and antimicrobial activity of some amide ether carboxylates surfactants. Egypt J Petrol 21:37–43
Rosen MJ (1989) Surfactants and interfacial phenomena, 2nd edn. Wiley, New York
Author information
Authors and Affiliations
Corresponding author
Electronic supplementary material
Below is the link to the electronic supplementary material.
About this article
Cite this article
Hegazy, M.A., Azzam, E.M.S., Kandil, N.G. et al. Corrosion Inhibition of Carbon Steel Pipelines by Some New Amphoteric and Di-cationic Surfactants in Acidic Solution by Chemical and Electrochemical Methods. J Surfact Deterg 19, 861–871 (2016). https://doi.org/10.1007/s11743-016-1824-9
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s11743-016-1824-9