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Some Surface Properties of Polysorbates and Cetyl Trimethyl Ammonium Bromine Mixed Systems

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Journal of Surfactants and Detergents

Abstract

Mixed surfactant solutions consisting of cationic/nonionic surfactants were prepared in different compositions of the components in aqueous solution in order to determine the surface properties. The critical micelle concentration (CMC) of aqueous solutions of the individual surfactants cetyl trimethyl ammonium bromide (CTAB) and polysorbate nonionics, and their mixtures are determined at different proportions. The results show that there is synergistic behavior in mixtures at higher mole fraction of nonionic surfactant. The effect of the alkyl chain on the CMC is also determined.

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References

  1. Singh K, Marangoni DG (2007) Synergistic interactions in the mixed micelles of cationic gemini with zwitterionic surfactants: spacer and pH effects. J Colloid Interface Sci 315:620–626

    Article  CAS  Google Scholar 

  2. Holland PM, Rubingh DN (1992) Mixed surfactants systems. In: Mixed surfactant systems, ACS symposium series 50. American Chemical Society, Washington, DC

  3. Holland PM (1992) Modeling mixed surfactant systems. In: Holland PM, Rubingh DN (eds) Mixed surfactant systems, ACS symposium series 501. American Chemical Society, Washington, DC

  4. Rosen MJ (1986) Molecular interaction and synergism in binary mixtures of surfactants. In: Scamehorn JF (ed) Phenomena in mixed surfactant systems, ACS symposium series 311. American Chemical Society, Washington, DC

  5. Scamehorn JF (1986) An overview of phenomena involving surfactant mixtures. In: Scamehorn JF (ed) Phenomena in mixed surfactant systems. ACS symposium series 311; American Chemical Society, Washington, DC

  6. Rosen MJ (1989) Selection of surfactant pairs for optimization of interfacial properties. J Am Oil Chem Soc 66:1840–1843

    Article  CAS  Google Scholar 

  7. Nakano TY, Sugihara G, Nakashima T, Yu SC (2002) Thermodynamic study of mixed hydrocarbon/fluorocarbon surfactant system by conductometric and fluorimetric techniques. Langmuir 18:8777–8785

    Article  CAS  Google Scholar 

  8. Holland PM, Rubingh DN (1991) Cationic surfactants in mixed surfactant systems. Marcel Dekker, Santa Barbara

    Google Scholar 

  9. Chakraborty T, Ghosh S, Moulik SP (2005) Micellization and related behavior of binary and ternary surfactant mixtures in aqueous medium: cetyl pyridinium chloride, cetyl trimethyl ammonium bromide, and polyoxethylene (10) cetyl ether derived system. J Phys Chem B 109:14813–14823

    Article  CAS  Google Scholar 

  10. Sarmoria C, Puvvada S, Blankschtein D (1992) Prediction of critical micelle concentrations of nonideal binary surfactant mixtures. Langmuir 8:2690–2697

    Article  CAS  Google Scholar 

  11. Puvvada S, Blankschtein D (1992) Thermodynamic description of micellization, phase behavior, and phase separation of aqueous solutions of surfactants mixtures. J Phys Chem 96:5567–5579

    Article  CAS  Google Scholar 

  12. Puvvada S, Blankschtein D (1992) Theoretical and experimental investigations of micellar properties of aqueous solutions containing binary mixtures of nonionic surfactants. J Phys Chem 96:5579–5592

    Article  CAS  Google Scholar 

  13. Holland PM, Rubingh DN (1992) In: Holland PM, Rubingh DN (eds) Mixed Surfactant Systems, ACS symposium series 501. American Chemical Society, Washington, DC

  14. Shiloach A, Blankschtein D (1998) Predicting micellar solution properties of binary surfactant mixtures. Langmuir 14:1618–1636

    Article  CAS  Google Scholar 

  15. Shiloach A, Blankschtein D (1997) Prediction of critical micellar concentrations and synergism of binary surfactant mixtures containing zwitterionic surfactants. Langmuir 13:3968–3981

    Article  CAS  Google Scholar 

  16. Nagarajan R (1985) Molecular theory for mixed micelles. Langmuir 1:331–341

    Article  CAS  Google Scholar 

  17. Nagarajan R (1986) Micellization, mixed micellization and solubilization: the role of interfacial interactions. Adv Colloid Interface Sci 26:205–264

    Article  CAS  Google Scholar 

  18. Nagarajan R, Ruckenstein E (1991) Theory of surfactant self-assembly: a predictive molecular thermodynamic approach. Langmuir 7:2934–2969

    Article  CAS  Google Scholar 

  19. Nagarajan R (1992) Micellization of binary surfactant mixtures. In: Holland PM, Rubingh DN (eds) Mixed surfactants systems, ACS symposium series 501, American Chemical Society, Washington, DC

  20. Ljunggren S, Eriksson JC (1987) A theoretical study of the effect of long-chain aliphatic alcohols on the stability of surfactant micelles. Prog Colloid Polym Sci 74:38–47

    Article  Google Scholar 

  21. Shiloach A, Blankschtein D (1998) Prediction of critical micelle concentrations of nonideal ternary surfactant mixtures. Langmuir 14:4105–4114

    Article  CAS  Google Scholar 

  22. Szymczyk K, Janczuk B (2007) The adsorption at solution-air interface and volumetric properties of mixtures of cationic and nonionic surfactants. Colloids Surf A 293:39–50

    Article  CAS  Google Scholar 

  23. Chakraborty T, Ghosh S (2008) A unique survey of applicability of theories of mixed adsorbed film and mixed micellization. J Surf Deterg 11:323–334

    Article  CAS  Google Scholar 

  24. Chou TH, Lin YS, Li WT, Chang CH (2008) Phase behavior and morphology of equimolar mixed cationic-anionic surfactant monolayers at the air/water interface: isotherm and Brewster angle microscopy analysis. J Colloid Interface Sci 321:384–392

    Article  CAS  Google Scholar 

  25. Chen L, Xiao JX, Ruan K, Ma J (2002) Homogeneous solutions of equimolar mixed cationic-anionic surfactants. Langmuir 18:7250–7252

    Article  CAS  Google Scholar 

  26. Dar AA, Rather GM, Das AR (2007) Mixed micelle formation and solubilization behavior toward polycyclic aromatic hydrocarbons of binary and ternary cationic-nonionic surfactant mixtures. J Phys Chem B 111:3122–3132

    Article  CAS  Google Scholar 

  27. Islam MN, Okano T, Kato T (2002) Surface phase behavior of a mixed system of anionic-nonionic surfactants studied by brewster angle microscopy and polarization modulation infrared reflection-absorption spectroscopy. Langmuir 18:10068–10074

    Article  CAS  Google Scholar 

  28. Penfold J, Staples E, Tucker I (2002) Neutron small angle scattering studies of micellar growth in mixed anionic- nonionic surfactants, sodium dodecyl sulfate, SDS, and hexaethylene glycol monododecyl ether, C12E6, in the presence and absence of solubilized alkane, hexadecane. J Phys Chem B 106:8891–8897

    Article  CAS  Google Scholar 

  29. Sulthana SB, Rao PVC, Bhat SGT, Nakano TY, Sugihara G, Rakshit AK (2000) Solution properties of nonionic surfactants and their mixtures: polyoxyethylene (10) alkyl ether [CnE10] and MEGA-10. Langmuir 16:980–987

    Article  CAS  Google Scholar 

  30. Ghosh S (2001) Surface chemical and micellar properties of binary and ternary surfactant mixtures (Cetyl Pyridinium Chloride, Tween-40, and Brij-56) in an aqueous medium. J Colloid Interface Sci 244:128–138

    Article  CAS  Google Scholar 

  31. Ghosh S, Moulik SP (1998) Interfacial and micellization behaviors of binary and ternary mixtures of amphiphiles (Tween-20, Brij-35, and Sodium Dodecyl Sulfate) in aqueous medium. J Colloid Interface Sci 208:357–366

    Article  CAS  Google Scholar 

  32. Moulik SP, Ghosh S (1997) Surface chemical and micellization behaviours of binary and ternary mixtures of amphiphiles (Triton X-100, Tween-80 and CTAB) in aqueous medium. J Molecular Liquids 72:145–161

    Article  CAS  Google Scholar 

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Acknowledgments

Taliha Sidim gratefully acknowledges the financial support of the Research Fund of Trakya University, Turkey.

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Correspondence to Taliha Sidim.

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Sidim, T., Arda, M. Some Surface Properties of Polysorbates and Cetyl Trimethyl Ammonium Bromine Mixed Systems. J Surfact Deterg 14, 409–414 (2011). https://doi.org/10.1007/s11743-010-1243-2

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  • DOI: https://doi.org/10.1007/s11743-010-1243-2

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