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Investigation of the Structure-Directing Effect of Surfactants on the Distribution of Silicate Species Using 29Si-NMR Spectroscopy

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Journal of Surfactants and Detergents

Abstract

Silicate anions were studied using 29Si NMR to investigate the structure-directing effect of a surfactant (sodium dodecylsulfate-SDS) on the distribution of silicate species present in alkaline silicate solutions. The distribution of the anions in the presence of polyelectrolytes was also investigated by 29Si NMR through the use of different bases including tetramethyl ammonium hydroxide (TMAOH) and sodium hydroxide (NaOH). Both SDS and the polyelectrolytic solutions were shown to stabilize low molecular weight silicate species and thus inhibit polymerization.

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Acknowledgments

This work was supported by CCP of and the University of Western Ontario, Canada.

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Authors and Affiliations

  1. Department of Chemistry, Faculty of Basic Sciences, University of Mazandaran, Babolsar, Iran

    Abdolraouf Samadi-Maybodi

  2. Faculty of Chemistry, Sharood Technology University, Sharood, Iran

    Naser Goudarzi

  3. Department of Chemistry, University of Western Ontario, N6A 5B7, London, ON, Canada

    Christopher W. Kirby & Yining Huang

Authors
  1. Abdolraouf Samadi-Maybodi
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  2. Naser Goudarzi
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  3. Christopher W. Kirby
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  4. Yining Huang
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Correspondence to Abdolraouf Samadi-Maybodi.

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Samadi-Maybodi, A., Goudarzi, N., Kirby, C.W. et al. Investigation of the Structure-Directing Effect of Surfactants on the Distribution of Silicate Species Using 29Si-NMR Spectroscopy. J Surfact Deterg 11, 49–54 (2008). https://doi.org/10.1007/s11743-007-1053-3

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  • DOI: https://doi.org/10.1007/s11743-007-1053-3

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