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Effect of cefoperazone sodium on the physicochemical properties of surfactants

  • Published:
Journal of Surfactants and Detergents

Abstract

The effects of cefoperazone sodium (CS), a pharmaceutical compound, on the critical micelle concentration (CMC) of surfactants with different charges [cetyl trimethylammonium bromide (CTAB), sodium dodecyl sulfate (SDS), and Triton X-100], the cloud point of Triton X-100, and the Krafft temperatures of SDS and CTAB were studied. The interaction of CS with differently charged surfactants was determined by ultraviolet and fluorescence spectrophotometry. The results show that with increasing CS concentration, the Krafft temperature increases and the CMC decreases in the SDS/H2O system, whereas the opposite results are obtained in the CTAB/H2O system. Both the cloud point and the CMC of Triton X-100 increase with the addition of CS. The above results are attributed to the different micellar interactions between CS and surfactants with different charges.

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Abbreviations

CMC:

critical micelle concentration

CP:

cloud point

CS:

cefoperazone sodium

CTAB:

cetyl trimethylammonium bromide

KT:

Krafft temperature

SDS:

sodium dodecyl sulfate

UV:

ultraviolet

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Authors and Affiliations

  1. School of Chemistry and Chemical Engineering, Yangzhou University, 225002, Yangzhou, People’s Republic of China

    Junhong Qian & Jinghua Gu

  2. School of Chemical Engineering, Jiangnan University, 214036, Wuxi, People’s Republic of China

    Jiding Xia

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  1. Junhong Qian
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  2. Jinghua Gu
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  3. Jiding Xia
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Correspondence to Junhong Qian.

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Qian, J., Gu, J. & Xia, J. Effect of cefoperazone sodium on the physicochemical properties of surfactants. J Surfact Deterg 8, 241–246 (2005). https://doi.org/10.1007/s11743-005-0352-4

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  • DOI: https://doi.org/10.1007/s11743-005-0352-4

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