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Preparation of the polysulfonamide/titania composites

  • Materials Science and Engineering
  • Published:
Journal of Shanghai University (English Edition)

Abstract

A series of polysulfonamide (PSA)/TiO2 modifier nano-composite films were successfully prepared by in-situ polymerization at a low temperature based on 4, 4-diaminodiphenylsulfone and terephthaloyl chloride in the common solvent N, N-dimethylacetamide (DMAc). It was shown that the nano particles were well dispersed in the polymer substrate. Meanwhile, PSA/TiO2/modifier composites exhibited good UV-resistant properties and mechanical properties. In addition, the composites’ heat stability improved. These prepared composites are promising in preparing spinning solution and might have potential application in heat-resistant fiber.

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References

  1. Shanghai Textile Research Institute. The synthesis of polysulfonamide fibers [J]. Synthetic Fiber in China, 1977, 2: 18–27.

    Google Scholar 

  2. Wang Xiao-feng, Zhang Yu-hua. Properties and application of aramid fibers [J]. China Textile Leader, 2005 (1): 18–23 (in Chinese).

  3. Xiao Chang-fa. Polybenzimidazole fiber and its application [J]. Hi-tech Fiber and Application, 2003, 28(3): 5–10 (in Chinese).

    Google Scholar 

  4. Wang Xiao-feng, Guang Bao-qiong. Preparation of polysulfonamide fiber: China, 1389604 [P]. 2003-01-08.

  5. Zhang Wen-shuan, Luo Yun-jun, Song Hai-xiang, Li Gen-chen, Liu Xiao-feng, Xu Hong-xia, Gao Yongzhong, Li Chun-pu. Study on mechanical property of PPS composite modified with nano-SiO2 [J]. Engineering Plastics Application, 2003, 31(8): 4–6 (in Chinese).

    Google Scholar 

  6. Shao Xin, Tian Jun, Liu Wei-min, Ma Chun-lin, Xue Qun-ji. Friction and wear properties of nanomaterial TiO2 particle filled poly (phthalazine ether sulfone ketone) composites [J]. Polymer Materials Science and Engineering, 2003, 19(3): 208–212 (in Chinese).

    Google Scholar 

  7. Yuan Hai-gen, Zeng Jin-fang, Yang Jie. The review of surface modification of aramid fibers [J]. Hi-tech Fiber and Application, 2005, 30(2): 26–33 (in Chinese).

    Google Scholar 

  8. Zhang Zai-li, Zhu Wan-hua, Jiang Rong. The view and development of separate technology and bioreactor of films [J]. Anhui Chemical Industry, 2001, 27(2): 24–27 (in Chinese).

    Google Scholar 

  9. Trushinshi B J, Dickson J M, Smyth T. Polysulfonamide thin-film composite reverse osmosis membranes [J]. Journal of Membrane Science, 1998, 143(1–2): 181–188.

    Article  Google Scholar 

  10. Dickson J M, Childs R F, Mcarry B E. Development of coating technique for the internal structure of polypropylene microfiltration membranes [J]. Journal of Membrane Science, 1998, 148(1): 25–36.

    Article  Google Scholar 

  11. Yoshio I, Mitsuru U, Takashi I. Synthesis of polysulfonamides from reactive di-1-benzotriazolyl 4,4-oxydibenzenesulfonate and aliphatic diamines [J]. Die Makromolekulare Chemie, 2003, 179(8): 2081–2083.

    Google Scholar 

  12. Yoshio I, Hikaru M. Preparation and properties of polysulfonamideimides [J]. Journal of Polymer Science Part A: Polymer Chemistry, 1973, 11(3): 611–620.

    Google Scholar 

  13. Mi H Y, Sung G L, Kil Y C. Synthesis and properties of polysulfonamides containing thiophene links [J]. Journal of Polymer Science Part A: Polymer Chemistry, 1988, 26(6): 1507–1517.

    Article  Google Scholar 

  14. Lin Ji-quan, Fang Jian-hui, Deng Ying, Shi Li-yi. Application of ultrafiltration in pretreatment of seawater desallination [J]. Journal of Shanghai University (Natural Science Edition), 2006, 12(6): 610–614 (in Chinese).

    Google Scholar 

  15. Liu Yin-feng, Yuan Wei-jun, Chen Li-ming, Hua Jiadong. Synthesis of optically active polyamides [J]. Journal of Shanghai University (Natural Science Edition), 1999, 5(2): 165–168 (in Chinese).

    Google Scholar 

  16. Qi Xiu-xiu, Lu Jian-mei, Zhang Zheng-biao, Wang Li-hua, Zhu Xia-lin. Synthesis of polyamic acid sulfone and polyimide sulfone by microwave irradiation [J]. Journal of Chemical Engineering of Chinese Universities, 2003, 17(2): 151–156 (in Chinese).

    Google Scholar 

  17. Liu Yin-feng, Zhu Zi-kang. Study on polyamide imide sulfon. I. Synthesis of polyamic acid sulfone [J]. Journal of Shanghai University (Natural Science Edition), 1996, 28(4): 431–437 (in Chinese).

    Google Scholar 

  18. Evers R C. Preparation and thermal properties of some piperazine polysulfonamides [J]. Journal of Polymer Science Part A: Polymer Chemistry, 1967, 5(7): 1797–1801.

    Article  Google Scholar 

  19. Chen Jian-jun, Wang Zhi-yu, Qian Guo-dong, Fan Xian-ping. Preparation and UV shielding of homogeneous dispersion nanometer TiO2 [J]. Materials Protection, 2003, 36(11): 7–9 (in Chinese).

    Google Scholar 

  20. He Ying, Wang Jun-an, Zhang Wen-fei, Chen Xiaoban, Huang Zong-hao. Tunable morphology of ZnO nanostructures self-assembled by polymer complexation process [J]. Journal of Shanghai University (Natural Science Edition), 2008, 14(5): 514–520 (in Chinese).

    Google Scholar 

  21. Yang Chun-guang, Qiao Ai-ping, Hou Jin-biao, Zhao Ying-hua. The agglomeration cause and solution method of nano-powder [J]. Shanxi Chemical Industry, 2003, 23(1): 56–58 (in Chinese).

    Google Scholar 

  22. Zhang Zhong-yan, Xing Jion-nan, Shi Li-yi, Zhang Yi, Hu Wei. Production of nanosized TiO2 particles [J]. Journal of Shanghai University (Natural Science Edition), 2002, 8(1): 87–90 (in Chinese).

    Google Scholar 

  23. Rabek J F. Experimental methods in polymer chemistry [M]. New York: Wiley, 1980: 164–165.

    Google Scholar 

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Authors and Affiliations

  1. Research Center of Composite Materials, Shanghai University, Shanghai, 200072, P. R. China

    Zhi-yong Tang  (唐志勇)

  2. School of Materials Science and Engineering, Shanghai University, Shanghai, 200072, P. R. China

    Wen-ting Xu  (徐文婷) & Qing-hua Jia  (焦青华)

Authors
  1. Zhi-yong Tang  (唐志勇)
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  2. Wen-ting Xu  (徐文婷)
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  3. Qing-hua Jia  (焦青华)
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Corresponding author

Correspondence to Zhi-yong Tang  (唐志勇).

Additional information

Project supported by the Shanghai Leading Academic Discipline Project (Grant No.s30107), and the Science and Technology Commission of Shanghai Municipality (Grant No.0852nm00600)

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Tang, Zy., Xu, Wt. & Jia, Qh. Preparation of the polysulfonamide/titania composites. J. Shanghai Univ.(Engl. Ed.) 14, 460–463 (2010). https://doi.org/10.1007/s11741-010-0678-3

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  • DOI: https://doi.org/10.1007/s11741-010-0678-3

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