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Thermodynamics of some ZrO2-containing ceramics

  • Materials Science And Engineering
  • Published:
Journal of Shanghai University (English Edition)

Abstract

Thermodynamic assessment in the ternary systems ZrO2-CeO2-Y2O2 , ZrO2-CeO2-Ce2O3 and the limiting binaries ZrO2-Y2O3, ZrO2-CeO2 ,CeO2-Y2O2, ZrO2-Ce2O3, CeO2-Ce2O3 as well as the modeling for oxides are reviewed comprehensively. Based on the recent estimations on the YO1,5-CeO2, ZrO2-CeO2 and ZrO2-YO1,5 systems, isothermal sections at 1 273 and 1 973 K of the ternary CeO2-ZrO2-YO1,5 system are calculated. In the system of ZrO2-CeO2-Ce2O3, the complex relation between the nonstoichiometry (y) in CeO−y , the composition of the ZrO2-CeO2 solid solution and the oxygen partial pressure (P o 2) for different ZrO2 containing solid solutions Ce2Zri2−y are evaluated from 1 473 to 1 773 K. The relation between the degree of Ce+4 reduction to Ce+3 under different P 0 2 in the fluorite CeO2−y and Ce z Zr1−z O2−x solid solutions at different temperatures can be used as a guide in the development of functional ceramics.

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Authors and Affiliations

  1. School of Materials Science and Engineering, Shanghai University, 200072, Shanghai, P. R. China

    Li Lin Ph. D. (Prof.) & Huang Shui-gen

  2. Department of Metallurgy and Materials Engineering, Katholieke Universiteit Leuven, B-3001, Heverlee, Belgium

    Omer Biest Van der, Huang Shui-gen & Jef Vleugels

  3. The State Key Lab of High Performance Ceramics and Superfine Microstructure, Shanghai Institute of Ceramics, Chinese Academy of Science, 200050, Shanghai, P. R. China

    Wang Pei-ling

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  1. Li Lin Ph. D.
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  2. Omer Biest Van der
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  3. Huang Shui-gen
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  4. Jef Vleugels
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  5. Wang Pei-ling
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Additional information

Project supported by Flanders-China Bilateral Project (Grant No. BIL 99/10), and Commission of European Communities in the Framework of the Growth Project “BIOGRAD” (Grant No. G5RD-CT2000-00354)

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Li, L., Van der Omer, B., Huang, Sg. et al. Thermodynamics of some ZrO2-containing ceramics. J. of Shanghai Univ. 10, 65–73 (2006). https://doi.org/10.1007/s11741-006-0107-5

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  • DOI: https://doi.org/10.1007/s11741-006-0107-5

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