Abstract
Corrosion of embedded rebars is a classical deterioration mechanism of reinforced concrete structures exposed to chloride environments. Such environments can be attributed to the presence of seawater, deicing or sea-salts, which have high concentrations of chloride ion. Chloride ingress into concrete, essential for inducing rebar corrosion, is a complex interaction between many physical and chemical processes. The current study proposes two chloride ingress parameter models for fly ash concrete, namely: 1) surface chloride content under tidal exposure condition; and 2) chloride binding. First, inconsistencies in surface chloride content and chloride binding models reported in literature, due to them not being in line with past research studies, are pointed out. Secondly, to avoid such inconsistencies, surface chloride content and chloride binding models for fly ash concrete are proposed based upon the experimental work done by other researchers. It is observed that, proposed models are simple, consistent and in line with past research studies reported in literature.
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References
Schiessl P, Raupach M. Influence of concrete composition and microclimate on the critical chloride content in concrete. In: Page C L, Treadaway K W J, Bamforth P B, eds. Corrosion of reinforcement in concrete. London (UK): Elsevier Applied Science, 1990, 49–58
Glass G K, Buenfeld N R. The presentation of the chloride threshold level for corrosion of steel in concrete. Corrosion Science, 1997, 39 (5): 1001–1013
Zhang J Y, Lounis Z. Nonlinear relationships between parameters of simplified diffusion-based model for service life design of concrete structures exposed to chlorides. Cement and Concrete Composites, 2009, 31(8): 591–600
Kayyali O A, Qasrawi M S. Chloride binding capacity in cementfly- ash pastes. Journal of Materials in Civil Engineering, 1992, 4(1): 16–26
Cheewaket T, Jaturapitakkul C, Chalee W. Long term performance of chloride binding capacity in fly ash concrete in a marine environment. Construction & Building Materials, 2010, 24(8): 1352–1357
Saetta A V, Scotta R V, Vitaliani R V. Analysis of chloride diffusion into partially saturated concrete. ACI Structural Journal, 1993, 90 (5): 441–451
Song H W, Lee C H, Ann K Y. Factors influencing chloride transport in concrete structures exposed to marine environments. Cement and Concrete Composites, 2008, 30(2): 113–121
Bastidas-Arteaga E, Chateauneuf A, Sanchez-Silva M, Bressolette P, Schoefs F. A comprehensive probabilistic model of chloride ingress in unsaturated concrete. Engineering Structures, 2011, 33(3): 720–730
Bertolini L. Steel corrosion and service life of reinforced concrete structures. Structure and Infrastructure Engineering, 2008, 4(2): 123–137
O’Neill Iqbal P, Ishida T. Modeling of chloride transport coupled with enhanced moisture conductivity in concrete exposed to marine environment. Cement and Concrete Research, 2009, 39(4): 329–339
Baroghel-Bouny V, Thié ry M, Wang X. Modelling of isothermal coupled moisture–ion transport in cementitious materials. Cement and Concrete Research, 2011, 41(8): 828–841
Johannesson B F. A theoretical model describing diffusion of a mixture of different types of ions in pore solution of concrete coupled to moisture transport. Ciement and Concrete Research, 2003, 33(4): 481–488
Samson E, Marchand J. Modeling the effect of temperature on ionic transport in cementitious materials. Cement and Concrete Research, 2007, 37(3): 455–468
Martin-Perez B, Zibara H, Hooton R D, Thomas M D A. A study of the effect of chloride binding on service life predictions. Cement and Concrete Research, 2000, 30(8): 1215–1223
Ann K Y, Ahn J H, Ryou J S. The importance of chloride content at the concrete surface in assessing the time to corrosion of steel in concrete structures. Construction & Building Materials, 2009, 23(1): 239–245
Chalee W, Jaturapitakkul C, Chindaprasirt P. Predicting the chloride penetration of fly ash concrete in seawater. Marine Structures, 2009, 22(3): 341–353
Petcherdchoo A. Time dependent models of apparent diffusion coefficient and surface chloride for chloride transport in fly ash concrete. Construction & Building Materials, 2013, 38: 497–507
Yuan Q, Shi C, De Schutter G, Audenaert K, Deng D. Chloride binding of cement-based materials subjected to external chloride environment–a review. Construction & Building Materials, 2009, 23(1): 1–13
Dhir R K, ElMohr M A K, Dyer T D. Chloride binding in GGBS concrete. Cement and Concrete Research, 1996, 26(12): 1767–1773
Ishida T, Miyahara S, Maruya T. Chloride binding capacity of mortars made with various Portland cements and mineral admixtures. Journal of Advanced Concrete Technology, 2008, 6(2): 287–301
Mangat P S, Limbachiya M C. Effect of initial curing on chloride diffusion in concrete repair materials. Cement and Concrete Research, 1999, 29(9): 1475–1485
Luping T, Gulikers J. On the mathematics of time-dependent apparent chloride diffusion coefficient in concrete. Cement and Concrete Research, 2007, 37(4): 589–595
Zibara H. Binding of external chlorides by cement pastes. Dissertation for the Doctoral Degree. Toronto: University of Toronto, 2001
Glass G K, Buenfeld N R. The influence of chloride binding on the chloride induced corrosion risk in reinforced concrete. Corrosion Science, 2000, 42(2): 329–344
Amey S L, Johnson D A, Miltenberger M A, Farzam H. Predicting the service life of concrete marine structures: An environmental methodology. ACI Structural Journal, 1998, 95(2): 205–214
Costa A, Appleton J. Chloride penetration into concrete in marine environment- Part I: Main parameters affecting chloride penetration. Materials and Structures, 1999, 32(218): 252–259
Pack S W, Jung M S, Song H W, Kim S H, Ann K Y. Prediction of time dependent chloride transport in concrete structures exposed to a marine environment. Cement and Concrete Research, 2010, 40(2): 302–312
Bentz E C, Evans C M, Thomas M D A. Chloride diffusion modelling for marine exposed concretes. In: Page C L, Bamforth P B, Figg J W, eds. Corrosion of Reinforcement in Concrete Construction. Cambridge (UK): The Royal Society of Chemistry Publication, 1996, 136–145
Tang L P, Nilsson L O. Chloride binding-capacity and binding isotherms of opc pastes and mortars. Cement and Concrete Research, 1993, 23(2): 247–253
Neville A. Chloride attack of reinforced-concrete—an overview. Materials and Structures, 1995, 28(176): 63–70
Thomas M D A, Hooton R D, Scott A, Zibara H. The effect of supplementary cementitious materials on chloride binding in hardened cement paste. Cement and Concrete Research, 2012, 42 (1): 1–7
Martin-Perez B, Pantazopoulou S J, Thomas M D A. Numerical solution of mass transport equations in concrete structures. Computers & Structures, 2001, 79(13): 1251–1264
Dhir R K, Jones M R. Development of chloride-resisting concrete using flyash. Fuel, 1999, 78(2): 137–142
Arya C, Buenfeld N R, Newman J B. Factors influencing chloridebinding in concrete. Cement and Concrete Research, 1990, 20(2): 291–300
Byfors K, Hansson C M, Tritthart J. Pore solution expression as a method to determine the influence of mineral additives on chloride binding. Cement and Concrete Research, 1986, 16(5): 760–770
Page C L, Short N R, Eltarras A. Diffusion of Chloride-Ions in Hardened Cement Pastes. Cement and Concrete Research, 1981, 11 (3): 395–406
Baroghel-Bouny V, Wang X, Thiery M, Saillio M, Barberon F. Prediction of chloride binding isotherms of cementitious materials by analytical model or numerical inverse analysis. Cement and Concrete Research, 2012, 42(9): 1207–1224
Shafei B, Alipour A, Shinozuka M. Prediction of corrosion initiation in reinforced concrete members subjected to environmental stressors: A finite‐element framework. Cement and Concrete Research, 2012, 42(2): 365–376
Thomas M D A, Matthews J D. Performance of pfa concrete in a marine environment—10-year results. Cement and Concrete Composites, 2004, 26(1): 5–20
McPolin D, Basheer P A M, Long A E, Grattan K T V, Sun T. Obtaining progressive chloride prof iles in cementitious materials. Construction & Building Materials, 2005, 19(9): 666–673
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Muthulingam, S., Rao, B.N. Chloride binding and time-dependent surface chloride content models for fly ash concrete. Front. Struct. Civ. Eng. 10, 112–120 (2016). https://doi.org/10.1007/s11709-015-0322-x
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DOI: https://doi.org/10.1007/s11709-015-0322-x