Skip to main content
Log in

Chloride binding and time-dependent surface chloride content models for fly ash concrete

  • Research Article
  • Published:
Frontiers of Structural and Civil Engineering Aims and scope Submit manuscript

Abstract

Corrosion of embedded rebars is a classical deterioration mechanism of reinforced concrete structures exposed to chloride environments. Such environments can be attributed to the presence of seawater, deicing or sea-salts, which have high concentrations of chloride ion. Chloride ingress into concrete, essential for inducing rebar corrosion, is a complex interaction between many physical and chemical processes. The current study proposes two chloride ingress parameter models for fly ash concrete, namely: 1) surface chloride content under tidal exposure condition; and 2) chloride binding. First, inconsistencies in surface chloride content and chloride binding models reported in literature, due to them not being in line with past research studies, are pointed out. Secondly, to avoid such inconsistencies, surface chloride content and chloride binding models for fly ash concrete are proposed based upon the experimental work done by other researchers. It is observed that, proposed models are simple, consistent and in line with past research studies reported in literature.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. Schiessl P, Raupach M. Influence of concrete composition and microclimate on the critical chloride content in concrete. In: Page C L, Treadaway K W J, Bamforth P B, eds. Corrosion of reinforcement in concrete. London (UK): Elsevier Applied Science, 1990, 49–58

    Google Scholar 

  2. Glass G K, Buenfeld N R. The presentation of the chloride threshold level for corrosion of steel in concrete. Corrosion Science, 1997, 39 (5): 1001–1013

    Article  Google Scholar 

  3. Zhang J Y, Lounis Z. Nonlinear relationships between parameters of simplified diffusion-based model for service life design of concrete structures exposed to chlorides. Cement and Concrete Composites, 2009, 31(8): 591–600

    Article  Google Scholar 

  4. Kayyali O A, Qasrawi M S. Chloride binding capacity in cementfly- ash pastes. Journal of Materials in Civil Engineering, 1992, 4(1): 16–26

    Article  Google Scholar 

  5. Cheewaket T, Jaturapitakkul C, Chalee W. Long term performance of chloride binding capacity in fly ash concrete in a marine environment. Construction & Building Materials, 2010, 24(8): 1352–1357

    Article  Google Scholar 

  6. Saetta A V, Scotta R V, Vitaliani R V. Analysis of chloride diffusion into partially saturated concrete. ACI Structural Journal, 1993, 90 (5): 441–451

    Google Scholar 

  7. Song H W, Lee C H, Ann K Y. Factors influencing chloride transport in concrete structures exposed to marine environments. Cement and Concrete Composites, 2008, 30(2): 113–121

    Article  Google Scholar 

  8. Bastidas-Arteaga E, Chateauneuf A, Sanchez-Silva M, Bressolette P, Schoefs F. A comprehensive probabilistic model of chloride ingress in unsaturated concrete. Engineering Structures, 2011, 33(3): 720–730

    Article  Google Scholar 

  9. Bertolini L. Steel corrosion and service life of reinforced concrete structures. Structure and Infrastructure Engineering, 2008, 4(2): 123–137

    Article  Google Scholar 

  10. O’Neill Iqbal P, Ishida T. Modeling of chloride transport coupled with enhanced moisture conductivity in concrete exposed to marine environment. Cement and Concrete Research, 2009, 39(4): 329–339

    Article  Google Scholar 

  11. Baroghel-Bouny V, Thié ry M, Wang X. Modelling of isothermal coupled moisture–ion transport in cementitious materials. Cement and Concrete Research, 2011, 41(8): 828–841

    Article  Google Scholar 

  12. Johannesson B F. A theoretical model describing diffusion of a mixture of different types of ions in pore solution of concrete coupled to moisture transport. Ciement and Concrete Research, 2003, 33(4): 481–488

    Article  Google Scholar 

  13. Samson E, Marchand J. Modeling the effect of temperature on ionic transport in cementitious materials. Cement and Concrete Research, 2007, 37(3): 455–468

    Article  Google Scholar 

  14. Martin-Perez B, Zibara H, Hooton R D, Thomas M D A. A study of the effect of chloride binding on service life predictions. Cement and Concrete Research, 2000, 30(8): 1215–1223

    Article  Google Scholar 

  15. Ann K Y, Ahn J H, Ryou J S. The importance of chloride content at the concrete surface in assessing the time to corrosion of steel in concrete structures. Construction & Building Materials, 2009, 23(1): 239–245

    Article  Google Scholar 

  16. Chalee W, Jaturapitakkul C, Chindaprasirt P. Predicting the chloride penetration of fly ash concrete in seawater. Marine Structures, 2009, 22(3): 341–353

    Article  Google Scholar 

  17. Petcherdchoo A. Time dependent models of apparent diffusion coefficient and surface chloride for chloride transport in fly ash concrete. Construction & Building Materials, 2013, 38: 497–507

    Article  Google Scholar 

  18. Yuan Q, Shi C, De Schutter G, Audenaert K, Deng D. Chloride binding of cement-based materials subjected to external chloride environment–a review. Construction & Building Materials, 2009, 23(1): 1–13

    Article  MATH  Google Scholar 

  19. Dhir R K, ElMohr M A K, Dyer T D. Chloride binding in GGBS concrete. Cement and Concrete Research, 1996, 26(12): 1767–1773

    Article  Google Scholar 

  20. Ishida T, Miyahara S, Maruya T. Chloride binding capacity of mortars made with various Portland cements and mineral admixtures. Journal of Advanced Concrete Technology, 2008, 6(2): 287–301

    Article  Google Scholar 

  21. Mangat P S, Limbachiya M C. Effect of initial curing on chloride diffusion in concrete repair materials. Cement and Concrete Research, 1999, 29(9): 1475–1485

    Article  Google Scholar 

  22. Luping T, Gulikers J. On the mathematics of time-dependent apparent chloride diffusion coefficient in concrete. Cement and Concrete Research, 2007, 37(4): 589–595

    Article  Google Scholar 

  23. Zibara H. Binding of external chlorides by cement pastes. Dissertation for the Doctoral Degree. Toronto: University of Toronto, 2001

    Google Scholar 

  24. Glass G K, Buenfeld N R. The influence of chloride binding on the chloride induced corrosion risk in reinforced concrete. Corrosion Science, 2000, 42(2): 329–344

    Article  Google Scholar 

  25. Amey S L, Johnson D A, Miltenberger M A, Farzam H. Predicting the service life of concrete marine structures: An environmental methodology. ACI Structural Journal, 1998, 95(2): 205–214

    Google Scholar 

  26. Costa A, Appleton J. Chloride penetration into concrete in marine environment- Part I: Main parameters affecting chloride penetration. Materials and Structures, 1999, 32(218): 252–259

    Article  Google Scholar 

  27. Pack S W, Jung M S, Song H W, Kim S H, Ann K Y. Prediction of time dependent chloride transport in concrete structures exposed to a marine environment. Cement and Concrete Research, 2010, 40(2): 302–312

    Article  Google Scholar 

  28. Bentz E C, Evans C M, Thomas M D A. Chloride diffusion modelling for marine exposed concretes. In: Page C L, Bamforth P B, Figg J W, eds. Corrosion of Reinforcement in Concrete Construction. Cambridge (UK): The Royal Society of Chemistry Publication, 1996, 136–145

    Google Scholar 

  29. Tang L P, Nilsson L O. Chloride binding-capacity and binding isotherms of opc pastes and mortars. Cement and Concrete Research, 1993, 23(2): 247–253

    Article  Google Scholar 

  30. Neville A. Chloride attack of reinforced-concrete—an overview. Materials and Structures, 1995, 28(176): 63–70

    Article  Google Scholar 

  31. Thomas M D A, Hooton R D, Scott A, Zibara H. The effect of supplementary cementitious materials on chloride binding in hardened cement paste. Cement and Concrete Research, 2012, 42 (1): 1–7

    Article  Google Scholar 

  32. Martin-Perez B, Pantazopoulou S J, Thomas M D A. Numerical solution of mass transport equations in concrete structures. Computers & Structures, 2001, 79(13): 1251–1264

    Article  Google Scholar 

  33. Dhir R K, Jones M R. Development of chloride-resisting concrete using flyash. Fuel, 1999, 78(2): 137–142

    Article  Google Scholar 

  34. Arya C, Buenfeld N R, Newman J B. Factors influencing chloridebinding in concrete. Cement and Concrete Research, 1990, 20(2): 291–300

    Article  Google Scholar 

  35. Byfors K, Hansson C M, Tritthart J. Pore solution expression as a method to determine the influence of mineral additives on chloride binding. Cement and Concrete Research, 1986, 16(5): 760–770

    Article  Google Scholar 

  36. Page C L, Short N R, Eltarras A. Diffusion of Chloride-Ions in Hardened Cement Pastes. Cement and Concrete Research, 1981, 11 (3): 395–406

    Article  Google Scholar 

  37. Baroghel-Bouny V, Wang X, Thiery M, Saillio M, Barberon F. Prediction of chloride binding isotherms of cementitious materials by analytical model or numerical inverse analysis. Cement and Concrete Research, 2012, 42(9): 1207–1224

    Article  Google Scholar 

  38. Shafei B, Alipour A, Shinozuka M. Prediction of corrosion initiation in reinforced concrete members subjected to environmental stressors: A finite‐element framework. Cement and Concrete Research, 2012, 42(2): 365–376

    Article  Google Scholar 

  39. Thomas M D A, Matthews J D. Performance of pfa concrete in a marine environment—10-year results. Cement and Concrete Composites, 2004, 26(1): 5–20

    Article  Google Scholar 

  40. McPolin D, Basheer P A M, Long A E, Grattan K T V, Sun T. Obtaining progressive chloride prof iles in cementitious materials. Construction & Building Materials, 2005, 19(9): 666–673

    Article  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to B. N. Rao.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Muthulingam, S., Rao, B.N. Chloride binding and time-dependent surface chloride content models for fly ash concrete. Front. Struct. Civ. Eng. 10, 112–120 (2016). https://doi.org/10.1007/s11709-015-0322-x

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11709-015-0322-x

Keywords

Navigation