Skip to main content
SpringerLink
Log in

Catalytic hydrodeoxygenation of pyrolysis bio-oil to jet fuel: A review

  • Review Article
  • Published:
Frontiers in Energy Aims and scope Submit manuscript

Abstract

Bio-oil from biomass pyrolysis cannot directly substitute traditional fuel due to compositional deficiencies. Catalytic hydrodeoxygenation (HDO) is the critical and efficient step to upgrade crude bio-oil to high-quality bio-jet fuel by lowering the oxygen content and increasing the heating value. However, the hydrocracking reaction tends to reduce the liquid yield and increase the gas yield, causing carbon loss and producing hydrocarbons with a short carbon-chain. To obtain high-yield bio-jet fuel, the elucidation of the conversion process of biomass catalytic HDO is important in providing guidance for metal catalyst design and optimization of reaction conditions. Considering the complexity of crude bio-oil, this review aimed to investigate the catalytic HDO pathways with model compounds that present typical bio-oil components. First, it provided a comprehensive summary of the impact of physical and electronic structures of both noble and non-noble metals that include monometallic and bimetallic supported catalysts on regulating the conversion pathways and resulting product selectivity. The subsequent first principle calculations further corroborated reaction pathways of model compounds in atom-level on different catalyst surfaces with the experiments above and illustrated the favored C–O/C=O scission orders thermodynamically and kinetically. Then, it discussed hydrogenation effects of different H-donors (such as hydrogen and methane) and catalysts deactivation for economical and industrial consideration. Based on the descriptions above and recent researches, it also elaborated on catalytic HDO of biomass and bio-oil with multi-functional catalysts. Finally, it presented the challenges and future prospective of biomass catalytic HDO.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Abbreviations

2,5-DMF:

2,5-dimethylfuran

4-MP:

4-methylphenol

5-HMF:

5-hydroxymethylfurfural

5-MFA:

5-methylfurfuryl alcohol

5-MFF:

5-methylfurfural

BTEX:

Benzene, toluene, ethylbenzene and xylenes

CHA:

Cyclohexane

CTH:

Catalytic transfer hydrogenaration

DCO:

Decarboxylation and/or decarbonylation

DDO:

Direct deoxygenation

DFT:

Density functional theory

DME:

Demethylation

DMO:

Demethoxylation

FA:

Furfuryl alcohol

FF:

Furfrual

H/C:

Hydrogen to carbon ratio

HAD:

Hydroxyalkylation

HCR:

Hydrocracking

HDO:

Hydrodeoxygenation

HHV:

Higher heating value

HYD:

Hydrogenation

MCH:

Methylcyclohexane

MF:

Methylfuran

MMP:

2-methoxy-4-methylphenol

MTHF:

Methyltetrahydrofuran

Ov :

Oxygen vacancy

THFA:

Tetrahydrofurfuryl alcohol

References

  1. International Energy Agency (IEA). Outlook—Key World Energy Statistics 2021—Analysis. 2023–11-13, available at the website of IEA

  2. International Energy Agency (IEA). Overview—World Energy Outlook 2021—Analysis. 2023–11-13, available at the website of IEA

  3. Alabi O, Abubakar A, Werkmeister A, et al. Keeping the lights on or off: Tracking the progress of access to electricity for sustainable development in Nigeria. GeoJournal, 2022, 88(2): 1535–1558

    Article  Google Scholar 

  4. Ganti G, Gidden M J, Smith C J, et al. Uncompensated claims to fair emission space risk putting Paris Agreement goals out of reach. Environmental Research Letters, 2023, 18(2): 024040

    Article  Google Scholar 

  5. Intergovernmental Panel on Climate Change (IPCC). IPCC meets to approve the final component of the Sixth Assessment Report. 2023–11-13, available at the website of IPCC

  6. US Energy Information Administration (EIA). International Energy Outlook 2023. 2023–11-13, available at the website of EIA

  7. Su C W, Pang L D, Qin M, et al. The spillover effects among fossil fuel, renewables and carbon markets: Evidence under the dual dilemma of climate change and energy crises. Energy, 2023, 274: 127304

    Article  Google Scholar 

  8. Ju Y, Liu R, Fu L. Engineering fronts in fields of Energy and Electrical Science and Technologies in the report of Engineering Fronts 2022. Frontiers in Energy, 2023, 17(1): 5–8

    Article  Google Scholar 

  9. Osman A I, Farghali M, Ihara I, et al. Materials, fuels, upgrading, economy, and life cycle assessment of the pyrolysis of algal and lignocellulosic biomass: A review. Environmental Chemistry Letters, 2023, 21(3): 1419–1476

    Article  Google Scholar 

  10. Mujtaba M, Fernandes Fraceto L, Fazeli M, et al. Lignocellulosic biomass from agricultural waste to the circular economy: A review with focus on biofuels, biocomposites and bioplastics. Journal of Cleaner Production, 2023, 402: 136815

    Article  Google Scholar 

  11. Bhoi P R, Ouedraogo A S, Soloiu V, et al. Recent advances on catalysts for improving hydrocarbon compounds in bio-oil of biomass catalytic pyrolysis. Renewable & Sustainable Energy Reviews, 2020, 121: 109676

    Article  Google Scholar 

  12. Popp J, Lakner Z, Harangi-Rákos M, et al. The effect of bioenergy expansion: Food, energy, and environment. Renewable & Sustainable Energy Reviews, 2014, 32: 559–578

    Article  Google Scholar 

  13. Dabros T M H, Stummann M Z, HøJ M, et al. transportation fuels from biomass fast pyrolysis, catalytic hydrodeoxygenation, and catalytic fast hydropyrolysis. Progress in Energy and Combustion Science, 2018, 68: 268–309

    Article  Google Scholar 

  14. Aviation Benefits Beyond Borders. Waypoint 2050. 2023–11-13, available at the website of Aviationbenefits

  15. Andrade M C, Gorgulho Silva C D O, de Souza Moreira L R, et al. Crop residues: Applications of lignocellulosic biomass in the context of a biorefinery. Frontiers in Energy, 2022, 16(2): 224–245

    Article  Google Scholar 

  16. Xu Y, Liu X, Qi J, et al. Compositional and structural study of ash deposits spatially distributed in superheaters of a large biomass-fired CFB boiler. Frontiers in Energy, 2021, 15(2): 449–459

    Article  Google Scholar 

  17. Pan P, Wu Y, Chen H. Performance evaluation of an improved biomass-fired cogeneration system simultaneously using extraction steam, cooling water, and feedwater for heating. Frontiers in Energy, 2022, 16(2): 321–335

    Article  Google Scholar 

  18. Guo S, Wei X, Che D, et al. Experimental study on influence of operating parameters on tar components from corn straw gasification in fluidized bed. Frontiers in Energy, 2021, 15(2): 374–383

    Article  Google Scholar 

  19. Khalifa O, Xu M, Zhang R, et al. Steam reforming of toluene as a tar model compound with modified nickel-based catalyst. Frontiers in Energy, 2022, 16(3): 492–501

    Article  Google Scholar 

  20. Li H, Hou C, Zhai Y, et al. Selective preparation for biofuels and high value chemicals based on biochar catalysts. Frontiers in Energy, 2023, 17(5): 635–653

    Article  Google Scholar 

  21. Yu H, Wu J, Wei W, et al. Synthesis of magnetic carbonaceous acid derived from waste garlic peel for biodiesel production via esterification. Frontiers in Energy, 2023, 17(1): 176–187

    Article  Google Scholar 

  22. Yan P, Nur Azreena I, Peng H, et al. Catalytic hydropyrolysis of biomass using natural zeolite-based catalysts. Chemical Engineering Journal, 2023, 476: 146630

    Article  Google Scholar 

  23. Liu X, Chen Z, Lu S, et al. Heterogeneous photocatalytic conversion of biomass to biofuels: A review. Chemical Engineering Journal, 2023, 476: 146794

    Article  Google Scholar 

  24. Bridgwater A. Fast pyrolysis processes for biomass. Renewable & Sustainable Energy Reviews, 2000, 4(1): 1–73

    Article  Google Scholar 

  25. Wang M, Dewil R, Maniatis K, et al. Biomass-derived aviation fuels: Challenges and perspective. Progress in Energy and Combustion Science, 2019, 74: 31–49

    Article  Google Scholar 

  26. Yang Y, Xu X, He H, et al. The catalytic hydrodeoxygenation of bio-oil for upgradation from lignocellulosic biomass. International Journal of Biological Macromolecules, 2023, 242: 124773

    Article  Google Scholar 

  27. Gea S, Hutapea Y A, Piliang A F R, et al. A comprehensive review of experimental parameters in bio-oil upgrading from pyrolysis of biomass to biofuel through catalytic hydrodeoxygenation. BioEnergy Research, 2023, 16(1): 325–347

    Article  Google Scholar 

  28. Ouedraogo A S, Bhoi P R. Recent progress of metals supported catalysts for hydrodeoxygenation of biomass derived pyrolysis oil. Journal of Cleaner Production, 2020, 253: 119957

    Article  Google Scholar 

  29. Figueirêdo M B, Jotic Z, Deuss P J, et al. Hydrotreatment of pyrolytic lignins to aromatics and phenolics using heterogeneous catalysts. Fuel Processing Technology, 2019, 189: 28–38

    Article  Google Scholar 

  30. Sun J, Shao S, Hu X, et al. Synthesis of oxygen-containing precursors of aviation fuel via carbonylation of the aqueous bio-oil fraction followed by C–C coupling. ACS Sustainable Chemistry & Engineering, 2022, 10(33): 11030–11040

    Article  Google Scholar 

  31. Wang H, Ruan H, Feng M, et al. One-pot process for hydrodeoxygenation of lignin to alkanes using Ru-based bimetallic and bifunctional catalysts supported on zeolite Y. ChemSusChem, 2017, 10(8): 1846–1856

    Article  Google Scholar 

  32. Xue S, Luo Z, Sun H, et al. Product regulation and catalyst deactivation during ex-situ catalytic fast pyrolysis of biomass over nickel-molybdenum bimetallic modified micro-mesoporous zeolites and clays. Bioresource Technology, 2022, 364: 128081

    Article  Google Scholar 

  33. Tian X, Wang Y, Zeng Z, et al. Research progress on the role of common metal catalysts in biomass pyrolysis: A state-of-the-art review. Green Chemistry, 2022, 24(10): 3922–3942

    Article  Google Scholar 

  34. Sun M, Zhang Y, Liu W, et al. Synergy of metallic Pt and oxygen vacancy sites in Pt–WO3−x catalysts for efficiently promoting vanillin hydrodeoxygenation to methylcyclohexane. Green Chemistry, 2022, 24(24): 9489–9495

    Article  Google Scholar 

  35. Shivhare A, Hunns J A, Durndell L J, et al. Metal-acid synergy: Hydrodeoxygenation of anisole over Pt/Al-SBA-15. ChemSusChem, 2020, 13(18): 4775–4775

    Article  Google Scholar 

  36. Teles C A, De Souza P M, Rabelo-Neto R C, et al. Reaction pathways for the HDO of guaiacol over supported Pd catalysts: Effect of support type in the deoxygenation of hydroxyl and methoxy groups. Molecular Catalysis, 2022, 523: 111491

    Article  Google Scholar 

  37. Feng S, Liu X, Su Z, et al. Low temperature catalytic hydrodeoxygenation of lignin-derived phenols to COLs over the Ru/SBA-15 catalyst. RSC Advances, 2022, 12(15): 9352–9362

    Article  Google Scholar 

  38. Zhang K, Meng Q, Wu H, et al. Selective hydrodeoxygenation of aromatics to COLs over Ru single atoms supported on CeO2. Journal of the American Chemical Society, 2022, 144(45): 20834–20846

    Article  Google Scholar 

  39. Cai T, Deng Q, Peng H, et al. Synthesis of renewable C–C cyclic compounds and high-density biofuels using 5-hydromethylfurfural as a reactant. Green Chemistry, 2020, 22(8): 2468–2473

    Article  Google Scholar 

  40. Yan P, Wang H, Liao Y, et al. Synthesis of renewable diesel and jet fuels from bio-based furanics via hydroxyalkylation/alkylation (HAA) over \({{\rm SO}_{4}^{2-}}/{{\rm TiO}_{2}}\) and hydrodeoxygenation (HDO) reactions Fuel, 2023, 342: 127685

    Article  Google Scholar 

  41. Gao Z, Zhou Z, Wang M, et al. Highly dispersed Pd anchored on heteropolyacid modified ZrO2 for high efficient hydrodeoxygenation of lignin-derivatives. Fuel, 2023, 334: 126768

    Article  Google Scholar 

  42. Wang L, Yang Y, Shi Y, et al. Single-atom catalysts with metal-acid synergistic effect toward hydrodeoxygenation tandem reactions. Chem Catalysis, 2022, 3(1): 100483

    Article  Google Scholar 

  43. Cho H J, Kim D, Xu B. Pore size engineering enabled selectivity control in tandem catalytic upgrading of cyclopentanone on zeolite-encapsulated Pt nanoparticles. ACS Catalysis, 2020, 10(15): 8850–8859

    Article  Google Scholar 

  44. Deng Q, Peng H, Yang Z, et al. A one-pot synthesis of high-density biofuels through bifunctional mesoporous zeolite-encapsulated Pd catalysts. Applied Catalysis B: Environmental, 2023, 337: 122982

    Article  Google Scholar 

  45. Ly H V, Kim J, Hwang H T, et al. Catalytic hydrodeoxygenation of fast pyrolysis bio-oil from saccharina japonica alga for bio-oil upgrading. Catalysts, 2019, 9(12): 1043

    Article  Google Scholar 

  46. Song Q L, Zhao Y P, Wu F P, et al. Selective hydrogenolysis of lignin-derived aryl ethers over Co/C@N catalysts. Renewable Energy, 2020, 148: 729–738

    Article  Google Scholar 

  47. Kumar A, Biswas B, Saini K, et al. Py-GC/MS study of prot lignin with cobalt impregnated titania, ceria and zirconia catalysts. Renewable Energy, 2021, 172: 121–129

    Article  Google Scholar 

  48. Song W, Liu Y, Barath E, et al. Synergistic effects of Ni and acid sites for hydrogenation and C–O bond cleavage of substituted phenols. Green Chemistry, 2015, 17(2): 1204–1218

    Article  Google Scholar 

  49. Saidi M, Moradi P. Catalytic hydrotreatment of lignin-derived pyrolysis bio-oils using Cu/γ-Al2O3 catalyst: Reaction network development and kinetic study of anisole upgrading. International Journal of Energy Research, 2021, 45(6): 8267–8284

    Article  Google Scholar 

  50. Sirous-Rezaei P, Park Y K. Catalytic hydropyrolysis of lignin: Suppression of coke formation in mild hydrodeoxygenation of lignin-derived phenolics. Chemical Engineering Journal, 2020, 386: 121348

    Article  Google Scholar 

  51. Lonchay W, Bagnato G, Sanna A. Highly selective hydropyrolysis of lignin waste to benzene, toluene and xylene in presence of zirconia supported iron catalyst. Bioresource Technology, 2022, 361: 127727

    Article  Google Scholar 

  52. Afreen G, Mittal D, Upadhyayula S. Biomass-derived phenolics conversion to C10–C13 range fuel precursors over metal ion-exchanged zeolites: Physicochemical characterization of catalysts and process parameter optimization. Renewable Energy, 2020, 149: 489–507

    Article  Google Scholar 

  53. Zhang J, Mao D, Zhang H, et al. Improving furfural hydrogenation selectivity by enhanced Ni-TiO2 elccoronic interaction. Applied Catalysis A, General, 2023, 660: 119206

    Article  Google Scholar 

  54. Xue Y, Sharma A, Huo J, et al. Low-pressure two-stage catalytic hydropyrolysis of lignin and lignin-derived phenolic monomers using zeolite-based bifunctional catalysts. Journal of Analytical and Applied Pyrolysis, 2020, 146: 104779

    Article  Google Scholar 

  55. Yan P, Bryant G, Li M M J, et al. Shape selectivity of zeolite catalysts for the hydrodeoxygenation of biocrude oil and its model compounds. Microporous and Mesoporous Materials, 2020, 309: 110561

    Article  Google Scholar 

  56. Zheng N, Wang J. Distinctly different performances of two iron-doped charcoals in catalytic hydrocracking of pine wood hydropyrolysis vapor to methane or upgraded bio-oil. Energy & Fuels, 2020, 34(1): 546–556

    Article  MathSciNet  Google Scholar 

  57. Guan H, Ding W, Liu S, et al. Catalytic hydrothermal liquefaction of Chinese herb residue for the production of high-quality bio-oil. International Journal of Hydrogen Energy, 2023, 48(30): 11205–11213

    Article  Google Scholar 

  58. Ji N, Cheng S, Jia Z, et al. Fabricating bifunctional Co–Al2O3@USY catalyst via in-sttu growth method for mild hydrodeoxygenation of lignin to naphthenes. ChemCatChem, 2022, 14(12): e202200274

    Article  Google Scholar 

  59. Gamliel D P, Bollas G M, Valla J A. Bifunctional Ni-ZSM-5 catalysts for the pyrolysis and hydropyrolysis of biomass. Energy Technology, 2017, 5(1): 172–182

    Article  Google Scholar 

  60. Yang Y, Ochoa-Hernández C, De La Peña O’Shea V A, et al. Effect of metal-support interaction on the selective hydrodeoxygenation of anisole to aromatics over Ni-based catalysts. Applied Catalysis B: Environmental, 2014, 145: 91–100

    Article  Google Scholar 

  61. Guo H, Zhao J, Chen Y, et al. Mechanistic insights into hydrodeoxygenation of lignin derivatives over Ni single atoms supported on Mo2C. ACS Catalysis, 2024, 14(2): 703–717

    Article  Google Scholar 

  62. Hu Y, Li X, Liu M, et al. Ni-based nanoparticles catalyzed hydrodeoxygenation of ketones, ethers, and phenols to (cyclo) aliphatic compounds. ACS Sustainable Chemistry & Engineering, 2023, 11(42): 15302–15314

    Article  Google Scholar 

  63. Yan P, Tian X, Kennedy E M, et al. The role of Ni sites located in mesopores in the selectivity of anisole hydrodeoxygenation. Catalysis Science & Technology, 2022, 12(7): 2184–2196

    Article  Google Scholar 

  64. Wang W, Zhang H, Zhou F, et al. Al-doped core-shell-structured Ni@mesoporous silica for highly selective hydrodeoxygenation of lignin-derived aldehydes. ACS Applied Materials & Interfaces, 2023, 15(28): 33654–33664

    Article  Google Scholar 

  65. Chen C, Ji X, Xiong Y, et al. Ni/Ce co-doping metal-organic framework catalysts with oxygen vacancy for catalytic transfer hydrodeoxygenation of lignin derivatives vanillin. Chemical Engineering Journal, 2024, 481: 148555

    Article  Google Scholar 

  66. Gong X, Li N, Li Y, et al. The catalytic hydrogenation of furfural to 2-methylfuran over the Mg–Al oxides supported Co–Ni bimetallic catalysts. Molecular Catalysis, 2022, 531: 112651

    Article  Google Scholar 

  67. Strapasson G B, Sousa L S, Báfero G B, et al. Acidity modulation of Pt-supported catalyst enhances C–O bond cleavage over acetone hydrodeoxygenation. Applied Catalysis B: Environmental, 2023, 335: 122863

    Article  Google Scholar 

  68. Zhu L, Li W, Zhang H, et al. Bimetallic ruthenium- and zinc-doped beta zeolite for efficiently depolymerizing Kraft lignin. Fuel, 2023, 349: 128766

    Article  Google Scholar 

  69. Li X. Efficient hydrodeoxygenation of lignocellulose derivative oxygenates to aviation fuel range alkanes using Pd–Ru/hydroxyapatite catalysts. Fuel Processing Technology, 2022, 232: 107263

    Article  Google Scholar 

  70. Xia Q, Chen Z, Shao Y, et al. Direct hydrodeoxygenation of raw woody biomass into liquid alkanes. Nature Communications, 2016, 7(1): 11162

    Article  Google Scholar 

  71. Zhao M, Hu J, Wu S, et al. Hydrodeoxygenation of lignin-derived phenolics over facile prepared bimetallic RuCoNx/NC. Fuel, 2022, 308: 121979

    Article  Google Scholar 

  72. Resende K A, Teles C A, Jacobs G, et al. Hydrodeoxygenation of phenol over zirconia supported Pd bimetallic catalysts. The effect of second metal on catalyst performance. Applied Catalysis B: Environmental, 2018, 232: 213–231

    Article  Google Scholar 

  73. Zhao Y P, Wu F P, Song Q L, et al. Hydrodeoxygenation of lignin model compounds to alkanes over Pd-Ni/HZSM-5 catalysts. Journal of the Energy Institute, 2020, 93(3): 899–910

    Article  Google Scholar 

  74. Shu R, Li R, Liu Y, et al. Enhanced adsorption properties of bimetallic RuCo catalyst for the hydrodeoxygenation of phenolic compounds and raw lignin-oil. Chemical Engineering Science, 2020, 227: 115920

    Article  Google Scholar 

  75. Liu T, Tian Z, Zhang W, et al. Selective hydrodeoxygenation of lignin-derived phenols to alkyl COLs over highly dispersed RuFe bimetallic catalysts. Fuel, 2023, 339: 126916

    Article  Google Scholar 

  76. Sunil More G, Rajendra Kanchan D, Banerjee A, et al. Selective catalytic hydrodeoxygenation of vanillin to 2-methoxy-4-methyl phenol and 4-methyl cyclohexanol over Pd/CuFe2O4 and PdNi/CuFe2O4 catalysts. Chemical Engineering Journal, 2023, 462: 142110

    Article  Google Scholar 

  77. Li R, Qiu J, Chen H, et al. Hydrodeoxygenation of phenolic compounds and raw lignin-oil over bimetallic RuNi catalyst: An experimental and modeling study focusing on adsorption properties. Fuel, 2020, 281: 118758

    Article  Google Scholar 

  78. Zhang J, Sun K, Li D, et al. Pd-Ni bimetallic nanoparticles supported on active carbon as an efficient catalyst for hydrodeoxygenation of aldehydes. Applied Catalysis A, General, 2019, 569: 190–195

    Article  Google Scholar 

  79. Liu X. In-sttu studies on the synergistic effect of Pd–Mo bimetallic catalyst for anisole hydrodeoxygenation. Molecular Catalysis, 2022, 230: 112591

    Article  Google Scholar 

  80. Ding W, Li H, Zong R, et al. Controlled hydrodeoxygenation of biobased ketones and aldehydes over an alloyed Pd–Zr catalyst under mild conditions. ACS Sustainable Chemistry & Engineering, 2021, 9(9): 3498–3508

    Article  Google Scholar 

  81. Salakhum S, Yutthalekha T, Shetsiri S, et al. Bifunctional and bimetallic Pt–Ru/HZSM-5 nanoparticles for the mild hydrodeoxygenation of lignin-derived 4-propylphenol. ACS Applied Nano Materials, 2019, 2(2): 1053–1062

    Article  Google Scholar 

  82. Mortensen P M, Gardini D, Damsgaard C D, et al. Deactivation of Ni-MoS2 by bio-oil impurities during hydrodeoxygenation of phenol and octanol. Applied Catalysis A, General, 2016, 523: 159–170

    Article  Google Scholar 

  83. Chandler D S, Seufitelli G V S, Resende F L P. Catalytic route for the production of alkanes from hydropyrolysis of biomass. Energy & Fuels, 2020, 34(10): 12573–12585

    Article  Google Scholar 

  84. Li T, Su J, Wang H, et al. Catalytic hydropyrolysis of lignin using NiMo-doped catalysts: Catalyst evaluation and mechanism analysis. Applied Energy, 2022, 316: 119115

    Article  Google Scholar 

  85. Stummann M Z, HøJ M, Davidsen B, et al. Effect of the catalyst in fluid bed catalytic hydropyrolysis. Catalysis Today, 2020, 355: 96–109

    Article  Google Scholar 

  86. Su J, Li T, Luo G, et al. Co-hydropyrolysis of pine and HDPE over bimetallic catalysts: Efficient BTEX production and process mechanism analysis. Fuel Processing Technology, 2023, 249: 107845

    Article  Google Scholar 

  87. He C, Ruan T, Ouyang X, et al. Selective hydrodeoxygenation of monophenolics from lignin bio-oil for preparing cyclohexanol and its derivatives over Ni-Co/Al2O3-MgO catalyst. Industrial Crops and Products, 2023, 202: 117045

    Article  Google Scholar 

  88. Miao F, Luo Z, Zhou Q, et al. Study on the reaction mechanism of C8+ aliphatic hydrocarbons obtained directly from biomass by hydropyrolysis vapor upgrading. Chemical Engineering Journal, 2023, 464: 142639

    Article  Google Scholar 

  89. Khromova S A, Smirnov A A, Bulavchenko O A, et al. Anisole hydrodeoxygenation over Ni–Cu bimetallic catalysts: The effect of Ni/Cu ratio on selectivity. Applied Catalysis A, General, 2014, 470: 261–270

    Article  Google Scholar 

  90. Liu M, Zhang J, Zheng L, et al. Significant promotion of surface oxygen vacancies on bimetallic CoNi nanocatalysts for hydrodeoxygenation of biomass-derived vanillin to produce methylCOL. ACS Sustainable Chemistry & Engineering, 2020, 8(15): 6075–6089

    Article  Google Scholar 

  91. Blanco E, Carrales-Alvarado D, Belen Dongil A, et al. Effect of the support functionalization of mono- and bimetallic Ni/Co supported on graphene in hydrodeoxygenation of guaiacol. Industrial & Engineering Chemistry Research, 2021, 60(51): 18870–18879

    Article  Google Scholar 

  92. Zhang Y, Wang W, Fan G, et al. Defect-decorated NiFe bimetallic nanocatalysts for the enhanced hydrodeoxygenation of guaiacol. ChemCatChem, 2022, 14(19): e202200585

    Article  Google Scholar 

  93. Zhang Y, Fan G, Yang L, et al. Cooperative effects between Ni–Mo alloy sites and defective structures over hierarchical Ni–Mo bimetallic catalysts enable the enhanced hydrodeoxygenation activity. ACS Sustainable Chemistry & Engineering, 2021, 9(34): 11604–11615

    Article  Google Scholar 

  94. Han Q, Rehman M U, Wang J, et al. The synergistic effect between Ni sites and Ni–Fe alloy sites on hydrodeoxygenation of lignin-derived phenols. Applied Catalysis B: Environmental, 2019, 253: 348–358

    Article  Google Scholar 

  95. Lei X, Du X, Xin H, et al. Chemical-switching strategy for the production of green biofuel on NiCo/MCM-41 catalysts by tuning atmosphere. Fuel, 2022, 315: 123118

    Article  Google Scholar 

  96. Jaswal A, Singh P P, Kar A K, et al. Production of 2-methyl furan, a promising 2nd generation biofuel, by the vapor phase hydrodeoxygenation of biomass-derived furfural over TiO2 supported Cu Ni bimetallic catalysts. Fuel Processing Technology, 2023, 245: 107726

    Article  Google Scholar 

  97. Lu K L, Yin F, Wei X Y, et al. Promotional effect of metallic Co and Fe on Ni-based catalysts for p-cresol deoxygenation. Fuel, 2022, 321: 124033

    Article  Google Scholar 

  98. Zhou M H, Xue Y Q, Ge F. MOF-derived NiM@C catalysts (M = Co, Mo, La) for in-siiu hydrogenation/hydrodeoxygenation of lignin-derived phenols to cycloalkanes/COL. Fuel, 2022, 329: 125446

    Article  Google Scholar 

  99. Zhou X, Rauchfuss T B. Production of hybrid diesel fuel precursors from carbohydrates and petrochemicals using formic acid as a reactive solvent. ChemSusChem, 2013, 6(2): 383–388

    Article  Google Scholar 

  100. Li L, Nie X, Chen Y, et al. Computational insights into the hydrodeoxygenation of phenolic compounds over Pt–Fe catalysts. Journal of Physical Chemistry, 2021, 125, 26: 14239–14252

    Google Scholar 

  101. Liu X, An W, Wang Y, et al. Hydrodeoxygenation of guaiacol over bimetallic Fe-alloyed (Ni, Pt) surfaces: Reaction mechanism, transition-state scaling relations and descriptor for predicting C–O bond scission reactivity. Catalysis Science & Technology, 2018, 8(8): 2146–2158

    Article  Google Scholar 

  102. Konadu D, Kwawu C R, Tia R, et al. Mechanism of guaiacol hydrodeoxygenation on Cu(111): Insights from density functional theory studies. Catalysts, 2021, 11(4): 523

    Article  Google Scholar 

  103. Fraga G, Yin Y, Konarova M, et al. Hydrocarbon hydrogen carriers for catalytic transfer hydrogenation of guaiacol. International Journal of Hydrogen Energy, 2020, 45(51): 27381–27391

    Article  Google Scholar 

  104. Gao M, Tan H, Zhu P, et al. Why phenol is selectively hydrogenated to cyclohexanol on Ru(0001): An experimental and theoretical study. Applied Surface Science, 2021, 558: 149880

    Article  Google Scholar 

  105. Zhou J, An W, Wang Z, et al. Hydrodeoxygenation of phenol over Ni-based bimetallic single-atom surface alloys: Mechanism, kinetics and descriptor. Catalysis Science & Technology, 2019, 9(16): 4314–4326

    Article  Google Scholar 

  106. Nie X, Zhang Z, Wang H, et al. Effect of surface structure and Pd doping of Fe catalysts on the selective hydrodeoxygenation of phenol. Catalysis Today, 2021, 371: 189–203

    Article  Google Scholar 

  107. Wu B, Li L, Wang H, et al. Role of MoOx/Ni(111) interfacial sites in direct deoxygenation of phenol toward benzene. Catalysis Science & Technology, 2023, 13(7): 2201–2211

    Article  Google Scholar 

  108. Tan H, Rong S, Zhao R, et al. Targeted conversion of model phenolics in pyrolysis bio-oils to arenes via hydrodeoxygenation over MoOx/BaO@SBA-15 catalyst. Chemical Engineering Journal, 2022, 438: 135577

    Article  Google Scholar 

  109. Itthibenchapong V, Chakthranont P, Sattayanon C, et al. Understanding the promoter effect of bifunctional (Pt, Ni, Cu)-MoO3−x/TiO2 catalysts for the hydrodeoxygenation of p-cresol: A combined DFT and experimental study. Applied Surface Science, 2021, 547: 149170

    Article  Google Scholar 

  110. Khan T S, Singh D, Samal P P, et al. Mechanistic investigations on the catalytic transfer hydrogenation of lignin-derived monomers over Ru catalysts: Theoretical and kinetic studies. ACS Sustainable Chemistry & Engineering, 2021, 9(42): 14040–14050

    Article  Google Scholar 

  111. Yan P, Tian X, Kennedy E M, et al. Influence of promoters (Fe, Mo, W) on the structural and catalytic properties of Ni/BEA for guaiacol hydrodeoxygenation. ACS Sustainable Chemistry & Engineering, 2021, 9(46): 15673–15682

    Article  Google Scholar 

  112. Liu R, An W, Stepped M. Stepped M@Pt(211) (M = Co, Fe, Mo) single-atom alloys promote the deoxygenation of lignin-derived phenolics: Mechanism, kinetics, and descriptors. Catalysis Science & Technology, 2021, 11(21): 7047–7059

    Article  Google Scholar 

  113. Tan Q, Wang G, Long A, et al. Mechanistic analysis of the role of metal oxophilicity in the hydrodeoxygenation of anisole. Journal of Catalysis, 2017, 347: 102–115

    Article  Google Scholar 

  114. Chia M, Pagán-Torres Y J, Hibbitts D, et al. Selective hydrogenolysis of polyols and cyclic ethers over bifunctional surface sites on rhodium–rhenium catalysts. Journal of the American Chemical Society, 2011, 133(32): 12675–12689

    Article  Google Scholar 

  115. Tan Q, Wang G, Nie L, et al. Different product distributions and mechanistic aspects of the hydrodeoxygenation of m-cresol over platinum and ruthenium catalysts. ACS Catalysis, 2015, 5(11): 6271–6283

    Article  Google Scholar 

  116. Deepa A K, Dhepe P L. Function of metals and supports on the hydrodeoxygenation of phenolic compounds. ChemPlusChem, 2014, 79(11): 1573–1583

    Article  Google Scholar 

  117. Runnebaum R C, Nimmanwudipong T, Block D E, et al. Catalytic conversion of compounds representative of lignin-derived bio-oils: A reaction network for guaiacol, anisole, 4-methylanisole, and cyclohexanone conversion catalysed by Pt/γ-Al2O3. Catalysis Science & Technology, 2012, 2(1): 113–118

    Article  Google Scholar 

  118. Furimsky E. Catalytic hydrodeoxygenation. Applied Catalysis A, General, 2000, 199(2): 147–190

    Article  Google Scholar 

  119. Kanchan D R, Banerjee A. Linear scaling relationships for furan hydrodeoxygenation over transition metal and bimetallic surfaces. ChemSusChem, 2023, 16(18): e202300491

    Article  Google Scholar 

  120. Fang W, Liu S, Steffensen A K. On the role of Cu+ and CuNi alloy phases in mesoporous CuNi catalyst for furfural hydrogenation. ACS Catalysis, 2023, 13(13): 8437–8444

    Article  Google Scholar 

  121. Chen L, Shi Y, Chen C, et al. Precise control over local atomic structures in Ni–Mo bimetallic alloys for the hydrodeoxygenation reaction: A combination between density functional theory and microkinetic modeling. Journal of Physical Chemistry C, 2022, 126(9): 4319–4328

    Article  Google Scholar 

  122. Zhang Z, Zhang Z, Zhang X, et al. Single pot selective conversion of furfural into 2-methylfuran over a Co-CoOx/AC bifunctional catalyst. Applied Surface Science, 2023, 612: 155871

    Article  Google Scholar 

  123. Hamid A H, Ali L, Shittu T, et al. Transformation of levoglucosan into liquid fuel via catalytic upgrading over Ni-CeO2 catalysts. Molecular Catalysis, 2023, 547: 113382

    Article  Google Scholar 

  124. Asada D, Ikeda T, Muraoka K, et al. Density functional theory study of deoxydehydration reaction by TiO2-supported monomeric and dimeric molybdenum oxide catalysts. Journal of Physical Chemistry C, 2022, 126(48): 20375–20387

    Article  Google Scholar 

  125. Banerjee A, Mushrif S H. Reaction pathways for the deoxygenation of biomass-pyrolysis-derived bio-oil on Ru: A DFT study using furfural as a model compound. ChemCatChem, 2017, 9(14): 2828–2838

    Article  Google Scholar 

  126. Wang X B, Xie Z Z, Guo L, et al. Mechanism of dibenzofuran hydrodeoxygenation on the surface of Pt(111): A DFT study. Catalysis Today, 2021, 364: 220–228

    Article  Google Scholar 

  127. Chen H, Liu J, Li W, et al. Mechanism insights into the decarbonylation of furfural to furan over Ni/MgO: A molecular simulation study. Energy & Fuels, 2023, 37(14): 10594–10602

    Article  Google Scholar 

  128. Zhang J, Jia Z, Yu S, et al. Regulating the Cu0–Cu+ ratio to enhance metal-support interaction for selective hydrogenation of furfural under mild conditions. Chemical Engineering Journal, 2023, 468: 143755

    Article  Google Scholar 

  129. Pino N, Sitthisa S, Tan Q, et al. Structure, activity, and selectivity of bimetallic Pd–Fe/SiO2 and Pd–Fe/γ-Al2O3 catalysts for the conversion of furfural. Journal of Catalysis, 2017, 350: 30–40

    Article  Google Scholar 

  130. Lin W, Chen Y, Zhang Y, et al. Surface synergetic effects of Ni-ReOx for promoting the mild hydrogenation of furfural to tetrahydrofurfuryl alcohol. ACS Catalysis, 2023, 13(17): 11256–11267

    Article  Google Scholar 

  131. Luo J, Cheng Y, Niu H, et al. Efficient Cu/FeOx catalyst with developed structure for catalytic transfer hydrogenation of furfural. Journal of Catalysis, 2022, 413: 575–587

    Article  Google Scholar 

  132. Zhao H, Liao X, Cui H, et al. Efficient Cu–Co bimetallic catalysts for the selective hydrogenation of furfural to furfuryl alcohol. Fuel, 2023, 351: 128887

    Article  Google Scholar 

  133. Yuan E, Wang C, Wu C, et al. Constructing a Pd–Co interface to tailor a d-band center for highly efficient hydroconversion of furfural over cobalt oxide-supported Pd catalysts. ACS Applied Materials & Interfaces, 2023, 15(37): 43845–43858

    Article  Google Scholar 

  134. Šivec R, Huš M, Likozar B, et al. Furfural hydrogenation over Cu, Ni, Pd, Pt, Re, Rh and Ru catalysts: Ab initio modelling of adsorption, desorption and reaction micro-kinetics. Chemical Engineering Journal, 2022, 436: 135070

    Article  Google Scholar 

  135. Xue J, Wang Y, Meng Y, et al. Theoretical investigation of decarbonylation mechanism of furfural on Pd(111) and M/Pd(111) (M = Ru, Ni, Ir) surfaces. Molecular Catalysis, 2020, 493: 111054

    Article  Google Scholar 

  136. Liu W, Yang Y, Chen L, et al. Atomically-ordered active sites in NiMo intermetallic compound toward low-pressure hydrodeoxygenation of furfural. Applied Catalysis B: Environmental, 2021, 282: 119569

    Article  Google Scholar 

  137. Shi Y. Exploring the reaction mechanisms of furfural hydrodeoxygenation on a CuNiCu(111) bimetallic catalyst surface from computation. ACS Omega, 2020, 5(29): 18040–18049

    Article  Google Scholar 

  138. Gunawan R, Cahyadi H S, Insyani R, et al. Density functional theory investigation of the conversion of 5-(hydroxymethyl)furfural into 2,5-dimethylfuran over the Pd(111), Cu(111), and Cu3Pd(111) surfaces. Journal of Physical Chemistry C, 2021, 125(19): 10295–10317

    Article  Google Scholar 

  139. Hsiao Y W, Zong X, Zhou J, et al. Selective hydrodeoxygenation of 5-hydroxymethylfurfural (HMF) to 2,5-dimethylfuran (DMF) over carbon supported copper catalysts using isopropyl alcohol as a hydrogen donor. Applied Catalysis B: Environmental, 2022, 317: 121790

    Article  Google Scholar 

  140. Zhang Y, Zhan S, Liu K, et al. Heterogeneous hydrogenation with hydrogen spillover enabled by nitrogen vacancies on boron nitride-supported Pd nanoparticles. Angewandte Chemie International Edition 62, 2023, 62(9): e202217191

    Article  Google Scholar 

  141. Kim H, Yang S, Lim Y H, et al. Enhancement in the metal efficiency of Ru/TiO2 catalyst for guaiacol hydrogenation via hydrogen spillover in the liquid phase. Journal of Catalysis, 2022, 410: 93–102

    Article  Google Scholar 

  142. Redina E A, Vikanova K V, Kapustin G I, et al. Selective room-temperature hydrogenation of carbonyl compounds under atmospheric pressure over platinum nanoparticles supported on ceria-zirconia mixed oxide. European Journal of Organic Chemistry, 2019, 2019(26): 4159–4170

    Article  Google Scholar 

  143. Kasabe M M, Kotkar V R, Dongare M K, et al. Phenol hydrogenation to COL catalysed by palladium supported on CuO/CeO2. Chemistry, an Asian Journal, 2023, 18(11): e202300119

    Article  Google Scholar 

  144. Yung M M, Foo G S, Sievers C. Role of Pt during hydrodeoxygenation of biomass pyrolysis vapors over Pt/HBEA. Catalysis Today, 2018, 302: 151–160

    Article  Google Scholar 

  145. Rong S, Tan H, Pang Z, et al. Synergetic effect between Pd clusters and oxygen vacancies in hierarchical Nb2O5 for lignin-derived phenol hydrodeoxygenation into benzene. Renewable Energy, 2022, 187: 271–281

    Article  Google Scholar 

  146. Rios-Escobedo R, Ortiz-Santos E, Colín-Luna J A, et al. Anisole hydrodeoxygenation: A comparative study of Ni/TiO2-ZrO2 and commercial TiO2 supported Ni and NiRu catalysts. Topics in Catalysis, 2022, 65(13–16): 1448–1461

    Article  Google Scholar 

  147. Zanuttini M S, Gross M, Marchetti G, et al. Furfural hydrodeoxygenation on iron and platinum catalysts. Applied Catalysis A, General, 2019, 587: 117217

    Article  Google Scholar 

  148. Guo L, Tian Y, He X, et al. Hydrodeoxygenation of phenolics over uniformly dispersed Pt–Ni alloys supported by self-pillared ZSM-5 nanosheets. Fuel, 2022, 322: 124082

    Article  Google Scholar 

  149. Wu X, Liu C, Wang H, et al. Origin of strong metal-support interactions between Pt and anatase TiO2 facets for hydrodeoxygenation of m-cresol on Pt/TiO2 catalysts. Journal of Catalysis, 2023, 418: 203–215

    Article  Google Scholar 

  150. Li T, Miao K, Zhao Z, et al. Understanding cellulose pyrolysis under hydrogen atmosphere. Energy Conversion and Management, 2022, 254: 115195

    Article  Google Scholar 

  151. Wang H, Li T, Su J, et al. Noncatalytic hydropyrolysis of lignin in a high pressure micro-pyrolyzer. Fuel Processing Technology, 2022, 233: 107289

    Article  Google Scholar 

  152. Geng Y, Li H. Hydrogen spillover-enhanced heterogeneously catalyzed hydrodeoxygenation for biomass upgrading, ChemSusChem, 2022, 15(8): e202102495

    Article  Google Scholar 

  153. Alayoglu S, An K, Melaet G, et al. Pt-mediated reversible reduction and expansion of CeO2 in Pt nanoparticle/mesoporous CeO2 catalyst: In situ X-ray spectroscopy and diffraction studies under redox (H2 and O2) atmospheres. Journal of Physical Chemistry C, 2013, 117(50): 26608–26616

    Article  Google Scholar 

  154. Ahmed F, Alam M K, Muira R, et al. Adsorption and dissociation of molecular hydrogen on Pt/CeO2 catalyst in the hydrogen spillover process: A quantum chemical molecular dynamics study. Applied Surface Science, 2010, 256(24): 7643–7652

    Article  Google Scholar 

  155. Messou D, Bernardin V, Meunier F, et al. Origin of the synergistic effect between TiO2 crystalline phases in the Ni/TiO2-catalyzed CO2 methanation reaction. Journal of Catalysis, 2021, 398: 14–28

    Article  Google Scholar 

  156. Zhang S, Xia Z, Zhang M, et al. Boosting selective hydrogenation through hydrogen spillover on supported-metal catalysts at room temperature. Applied Catalysis B: Environmental, 2021, 297: 120418

    Article  Google Scholar 

  157. Shin H, Choi M, Kim H. A mechanistic model for hydrogen activation, spillover, and its chemical reaction in a zeolite-encapsulated Pt catalyst. Physical Chemistry Chemical Physics, 2016, 18(10): 7035–7041

    Article  Google Scholar 

  158. Newman C, Zhou X, Goundie B, et al. Effects of support identity and metal dispersion in supported ruthenium hydrodeoxygenation catalysts. Applied Catalysis A, General, 2014, 477: 64–74

    Article  Google Scholar 

  159. Moogi S, Jae J, Kannapu H P R, et al. Enhancement of aromatics from catalytic pyrolysis of yellow poplar: Role of hydrogen and methane decomposition. Bioresource Technology, 2020, 315: 123835

    Article  Google Scholar 

  160. Moogi S, Pyo S, Farooq A, et al. Biomass enhancement of bioaromatics production from food waste through catalytic pyrolysis over Zn and Mo-loaded HZSM-5 under an environment of decomposed methane. Chemical Engineering Journal, 2022, 446: 137215

    Article  Google Scholar 

  161. Austin D, Wang A, He P, et al. Catalytic valorization of biomass derived glycerol under methane: Effect of catalyst synthesis method. Fuel, 2018, 216: 218–226

    Article  Google Scholar 

  162. Peng H, Wang A, He P, et al. Solvent-free catalytic conversion of xylose with methane to aromatics over Zn–Cr modified zeolite catalyst. Fuel, 2019, 253: 988–996

    Article  Google Scholar 

  163. Cheng Y T, Huber G W. Production of targeted aromatics by using Diels–Alder classes of reactions with furans and olefins over ZSM-5. Green Chemistry, 2012, 14(11): 3114

    Article  Google Scholar 

  164. He P, Shan W, Xiao Y, et al. Performance of Zn/ZSM-5 for in situ catalytic upgrading of pyrolysis bio-oil by methane. Topics in Catalysis, 2016, 59(1): 86–93

    Article  Google Scholar 

  165. Wang A, Austin D, Qian H, et al. Catalytic valorization of furfural under methane environment. ACS Sustainable Chemistry & Engineering, 2018, 6(7): 8891–8903

    Article  Google Scholar 

  166. Tshikesho R S, Kumar A, Huhnke R L, et al. Catalytic co-pyrolysis of red cedar with methane to produce upgraded bio-oil. Bioresource Technology, 2019, 285: 121299

    Article  Google Scholar 

  167. Wang A, Austin D, Song H. Investigations of thermochemical upgrading of biomass and its model compounds: Opportunities for methane utilization. Fuel, 2019, 246: 443–453

    Article  Google Scholar 

  168. Tang P, Zhu Q, Wu Z, et al. Methane activation: The past and future. Energy & Environmental Science, 2014, 7(8): 2580–2591

    Article  Google Scholar 

  169. Doan H A, Wang X, Snurr R Q. Computational screening of supported metal oxide nanoclusters for methane activation: Insights into homolytic versus heterolytic C–H bond dissociation. Journal of Physical Chemistry Letters, 2023, 14(21): 5018–5024

    Article  Google Scholar 

  170. Xu Y, Liu S, Guo X, et al. Methane activation without using oxidants over Mo/HZSM-5 zeolite catalysts. Catalysis Letters, 1995, 30(1–4): 135–149

    Article  Google Scholar 

  171. Xu J, Zheng A, Wang X, et al. Room temperature activation of methane over Zn modified H-ZSM-5 zeolites: Insight from solid-state NMR and theoretical calculations. Chemical Science, 2012, 3(10): 2932

    Article  Google Scholar 

  172. Luzgin M V, Rogov V A, Arzumanov S S, et al. Understanding methane aromatization on a Zn-modified high-silica zeolite. Angewandte Chemie International Edition, 2008, 47(24): 4559–4562

    Article  Google Scholar 

  173. Gabrienko A A, Arzumanov S S, Luzgin M V, et al. Methane activation on Zn2+-exchanged ZSM-5 zeolites. The effect of molecular oxygen addition. Journal of Physical Chemistry C, 2015, 119(44): 24910–24918

    Article  Google Scholar 

  174. Wang A, Song H. Maximizing the production of aromatic hydrocarbons from lignin conversion by coupling methane activation. Bioresource Technology, 2018, 268: 505–513

    Article  Google Scholar 

  175. He P, Wang A, Meng S, et al. Impact of Al sites on the methane co-aromatization with alkanes over Zn/HZSM-5. Catalysis Today, 2019, 323: 94–104

    Article  Google Scholar 

  176. Wang A, Austin D, Karmakar A, et al. Methane upgrading of acetic acid as a model compound for a biomass-derived liquid over a modified zeolite catalyst. ACS Catalysis, 2017, 7(5): 3681–3692

    Article  Google Scholar 

  177. Du L, Luo Z, Wang K, et al. Catalytic co-conversion of poplar pyrolysis vapor and methanol for aromatics production via ex-situ configuration. Journal of Analytical and Applied Pyrolysis, 2022, 165: 105571

    Article  Google Scholar 

  178. Li S, Liu B, Truong J, et al. One-pot hydrodeoxygenation (HDO) of lignin monomers to C9 hydrocarbons co-catalysed by Ru/C and Nb2O5. Green Chemistry, 2020, 22(21): 7406–7416

    Article  Google Scholar 

  179. Lu Q, Yang X, Zhu X. Analysis on chemical and physical properties of bio-oil pyrolyzed from rice husk. Journal of Analytical and Applied Pyrolysis, 2008, 82(2): 191–198

    Article  Google Scholar 

  180. Pidtasang B, Sukkasi S, Pattiya A. Effect of in-situ addition of alcohol on yields and properties of bio-oil derived from fast pyrolysis of eucalyptus bark. Journal of Analytical and Applied Pyrolysis, 2016, 120: 82–93

    Article  Google Scholar 

  181. Kim Y M, Jae J, Kim B S, et al. Catalytic co-pyrolysis of torrefied yellow poplar and high-density polyethylene using microporous HZSM-5 and mesoporous Al-MCM-41 catalysts. Energy Conversion and Management, 2017, 149: 966–973

    Article  Google Scholar 

  182. Ahmed M H M, Batalha N, Mahmudul H M D, et al. A review on advanced catalytic co-pyrolysis of biomass and hydrogen-rich feedstock: Insights into synergistic effect, catalyst development and reaction mechanism. Bioresource Technology, 2020, 310: 123457

    Article  Google Scholar 

  183. Wu P, Zhao D, Lu G, et al. Supported Pd–Au bimetallic nanoparticles as an efficient catalyst for the hydrodeoxygenation of vanillin with formic acid at room temperature. Green Chemistry, 2022, 24(3): 1096–1102

    Article  Google Scholar 

  184. Alemán-Vázquez L O, Cano-Domínguez J L, García-Gutiérrez J L. Effect of tetralin, decalin and naphthalene as hydrogen donors in the upgrading of heavy oils. Procedia Engineering, 2012, 42: 532–539

    Article  Google Scholar 

  185. Shafaghat H, Lee I G, Jae J, et al. Pd/C catalyzed transfer hydrogenation of pyrolysis oil using 2-propanol as hydrogen source. Chemical Engineering Journal, 2019, 377: 119986

    Article  Google Scholar 

  186. Boscagli C, Raffelt K, Grunwaldt J D. Reactivity of platform molecules in pyrolysis oil and in water during hydrotreatment over nickel and ruthenium catalysts. Biomass and Bioenergy, 2017, 106: 63–73

    Article  Google Scholar 

  187. Boscagli C, Yang C, Welle A, et al. Effect of pyrolysis oil components on the activity and selectivity of nickel-based catalysts during hydrotreatment. Applied Catalysis A, General, 2017, 544: 161–172

    Article  Google Scholar 

  188. Ambursa M M, Juan J C, Yahaya Y, et al. A review on catalytic hydrodeoxygenation of lignin to transportation fuels by using nickel-based catalysts. Renewable & Sustainable Energy Reviews, 2021, 138: 110667

    Article  Google Scholar 

  189. Lan X, Hensen E J M, Weber T. Hydrodeoxygenation of guaiacol over Ni2P/SiO2-reaction mechanism and catalyst deactivation. Applied Catalysis A, General, 2018, 550: 57–66

    Article  Google Scholar 

  190. Khanh Tran Q, Vu Ly H, Anh Vo T, et al. Highly selective hydrodeoxygenation of wood pallet sawdust pyrolysis oil to methyl phenol derivatives using cobalt and iron on activated carbon supported catalysts. Energy Conversion and Management: X, 2022, 14: () 100184

    Article  Google Scholar 

  191. Tian Y, Guo L, Qiao C, et al. Dynamics-driven tailoring of sub-nanometric Pt–Ni bimetals confined in hierarchical zeolite for catalytic hydrodeoxygenation. Applied Catalysis B: Environmental, 2023, 336: 122945

    Article  Google Scholar 

  192. Chen S, Yan P, Yu X, et al. Conversion of lignin to high yields of aromatics over Ru–ZnO/SBA-15 bifunctional catalysts. Renewable Energy, 2023, 215: 118919

    Article  Google Scholar 

  193. Hita I, Cordero-Lanzac T, Kekäläinen T, et al. In-depth analysis of raw bio-oil and its hydrodeoxygenated products for a comprehensive catalyst performance evaluation. ACS Sustainable Chemistry & Engineering, 2020, 8(50): 18433–18445

    Article  Google Scholar 

  194. Cordero-Lanzac T, Palos R, Hita I, et al. Revealing the pathways of catalyst deactivation by coke during the hydrodeoxygenation of raw bio-oil. Applied Catalysis B: Environmental, 2018, 239: 513–524

    Article  Google Scholar 

  195. Wu T, Dang Q, Wu Y, et al. Catalytic hydropyrolysis of biomass over NiMo bimetallic carbon-based catalysts. Journal of Environmental Chemical Engineering, 2023, 11(3): 110024

    Article  Google Scholar 

  196. Wang J, Jiang J, Li D, et al. Integrated hydropyrolysis and vapor-phase hydrodeoxygenation process with Pd/Al2O3 for production of advanced oxygen-containing biofuels from cellulosic wastes. Fuel Processing Technology, 2024, 254: 107948

    Article  Google Scholar 

  197. Liu Y, Chen L, Chen Y, et al. Pilot study on production of aviation fuel from catalytic conversion of corn stover. Bioresource Technology, 2023, 372: 128653

    Article  Google Scholar 

  198. Ma D, Lu S, Liu X, et al. Depolymerization and hydrodeoxygenation of lignin to aromatic hydrocarbons with a Ru catalyst on a variety of Nb-based supports. Chinese Journal of Catalysis, 2019, 40(4): 609–617

    Article  Google Scholar 

  199. Li R, Zhao Z, Zhang B, et al. Catalytic hydroprocessing of white pine pyrolysis bio-oil over cobalt-molybdenum carbide in a continuous packed-bed reactor. BioEnergy Research, 2021, 14(2): 588–597

    Article  Google Scholar 

  200. Onwudili J A, Scaldaferri C A. Catalytic upgrading of intermediate pyrolysis bio-oil to hydrocarbon-rich liquid biofuel via a novel two-stage solvent-assisted process. Fuel, 2023, 352: 129015

    Article  Google Scholar 

Download references

Acknowledgements

This work was supported by the National Natural Science Foundation of China (Grant No. 52236011).

Author information

Authors and Affiliations

  1. State Key Laboratory of Clean Energy Utilization, Zhejiang University, Hangzhou, 310027, China

    Zhongyang Luo, Wanchen Zhu, Feiting Miao & Jinsong Zhou

Authors
  1. Zhongyang Luo
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Wanchen Zhu
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Feiting Miao
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Jinsong Zhou
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Zhongyang Luo.

Ethics declarations

Competing Interests The authors declare that they have no competing interests.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Luo, Z., Zhu, W., Miao, F. et al. Catalytic hydrodeoxygenation of pyrolysis bio-oil to jet fuel: A review. Front. Energy (2024). https://doi.org/10.1007/s11708-024-0943-7

Download citation

  • Received:

  • Accepted:

  • Published:

  • DOI: https://doi.org/10.1007/s11708-024-0943-7

Keywords

Search

Navigation