Frontiers of Materials Science

, Volume 11, Issue 2, pp 171–181 | Cite as

Development of Al- and Cu-based nanocomposites reinforced by graphene nanoplatelets: Fabrication and characterization

  • Abdollah Saboori
  • Matteo Pavese
  • Claudio Badini
  • Paolo Fino
Research Article

Abstract

Aluminum and copper matrix nanocomposites reinforced by graphene nanoplatelets (GNPs) were successfully fabricated by a wet mixing method followed by conventional powder metallurgy. The uniform dispersion of GNPs within the metal matrices showed that the wet mixing method has a great potential to be used as a mixing technique. However, by increasing the GNPs content, GNPs agglomeration was more visible. DSC and XRD of Al/GNPs nanocomposites showed that no new phase formed below the melting point of Al. Microstructural observations in both nanocomposites reveal the evident grain refinement effect as a consequence of GNPs addition. The interfacial bonding evaluation shows a poor interfacial bonding between GNPs and Al, while the interfacial bonding between Cu and GNPs is strong enough to improve the properties of the Cu/GNPs nanocomposites. In both composites, the coefficient of thermal expansion decreases as a function of GNPs while, their hardness is improved by increasing the GNPs content as well as their elastic modulus.

Keywords

nanocomposite aluminum copper graphene microstructure thermal expansion 

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References

  1. [1]
    Geim A K, Novoselov K S. The rise of graphene. Nature Materials, 2007, 6(3): 183–191CrossRefGoogle Scholar
  2. [2]
    Castro Neto A H, Guinea F, Peres N M R, et al. The electronic properties of graphene. Reviews of Modern Physics, 2009, 81(1): 109–162CrossRefGoogle Scholar
  3. [3]
    Balandin A A. Thermal properties of graphene and nanostructured carbon materials. Nature Materials, 2011, 10(8): 569–581CrossRefGoogle Scholar
  4. [4]
    Molitor F, Güttinger J, Stampfer C, et al. Electronic properties of graphene nanostructures. Journal of Physics: Condensed Matter, 2011, 23(24): 243201Google Scholar
  5. [5]
    Ovid’ko I A. Review on grain boundaries in graphene. Curved poly- and nanocrystalline graphene structures as new carbon allotropes. Reviews on Advanced Materials Science, 2012, 30(3): 201–224Google Scholar
  6. [6]
    Rashad M, Pan F, Yu Z, et al. Investigation on microstructural, mechanical and electrochemical properties of aluminum composites reinforced with graphene nanoplatelets. Progress in Natural Science: Materials International, 2015, 25(5): 460–470CrossRefGoogle Scholar
  7. [7]
    Rashad M, Pan F, Hu H, et al. Enhanced tensile properties of magnesium composites reinforced with graphene nanoplatelets. Materials Science and Engineering A, 2015, 630: 36–44CrossRefGoogle Scholar
  8. [8]
    Rashad M, Pan F, Tang A, et al. Effect of graphene nanoplatelets addition on mechanical properties of pure aluminum using a semipowder method. Progress in Natural Science: Materials International, 2014, 24(2): 101–108CrossRefGoogle Scholar
  9. [9]
    Kuilla T, Bhadra S, Yao D, et al. Recent advances in graphene based polymer composites. Progress in Polymer Science, 2010, 35(11): 1350–1375CrossRefGoogle Scholar
  10. [10]
    Potts J R, Dreyer D R, Bielawski C W, et al. Graphene-based polymer nanocomposites. Polymer, 2011, 52(1): 5–25CrossRefGoogle Scholar
  11. [11]
    Tapasztó O, Tapasztó L, Markó M, et al. Dispersion patterns of graphene and carbon nanotubes in ceramic matrix composites. Chemical Physics Letters, 2011, 511(4–6): 340–343CrossRefGoogle Scholar
  12. [12]
    Walker L S, Marotto V R, Rafiee M A, et al. Toughening in graphene ceramic composites. ACS Nano, 2011, 5(4): 3182–3190CrossRefGoogle Scholar
  13. [13]
    Kvetková L, Duszová A, Hvizdoš P, et al. Fracture toughness and toughening mechanisms in graphene platelet reinforced Si3N4 composites. Scripta Materialia, 2012, 66(10): 793–796CrossRefGoogle Scholar
  14. [14]
    Porwal H, Grasso S, Reece M J. Review of graphene–ceramic matrix composites. Advances in Applied Ceramics, 2013, 112(8): 443–454CrossRefGoogle Scholar
  15. [15]
    Centeno A, Rocha V G, Alonso B, et al. Graphene for tough and electroconductive alumina ceramics. Journal of the European Ceramic Society, 2013, 33(15–16): 3201–3210CrossRefGoogle Scholar
  16. [16]
    Saboori A, Pavese M, Badini C, et al. Acta Metallurgica Sinica (English Letters), 2017 (in press)Google Scholar
  17. [17]
    Nieto A, Lahiri D, Agarwal A. Graphene NanoPlatelets reinforced tantalum carbide consolidated by spark plasma sintering. Materials Science and Engineering A, 2013, 582(11): 338–346CrossRefGoogle Scholar
  18. [18]
    Ramirez C, Miranzo P, Belmonte M, et al. Extraordinary toughening enhancement and flexural strength in Si3N4 composites using graphene sheets. Journal of the European Ceramic Society, 2014, 34(2): 161–169CrossRefGoogle Scholar
  19. [19]
    Fan Y, Estili M, Igarashi G, et al. The effect of homogeneously dispersed few-layer graphene on microstructure and mechanical properties of Al2O3 nanocomposites. Journal of the European Ceramic Society, 2014, 34(2): 443–451CrossRefGoogle Scholar
  20. [20]
    Wang J, Li Z, Fan G, et al. Reinforcement with graphene nanosheets in aluminum matrix composites. Scripta Materialia, 2012, 66(8): 594–597CrossRefGoogle Scholar
  21. [21]
    Chen L Y, Konishi H, Fehrenbacher A, et al. Novel nanoprocessing route for bulk graphene nanoplatelets reinforced metal matrix nanocomposites. Scripta Materialia, 2012, 67(1): 29–32CrossRefGoogle Scholar
  22. [22]
    Koltsova T, Nasibulina L I, Anoshkin I V, et al. New hybrid copper composite materials based on carbon nanostructures. Journal of Materials Science and Engineering B, 2012, 2(4): 240–246Google Scholar
  23. [23]
    Nasibulin A G, Koltsova T, Nasibulina L I, et al. A novel approach to composite preparation by direct synthesis of carbon nanomaterial on matrix or filler particles. Acta Materialia, 2013, 61(6): 1862–1871CrossRefGoogle Scholar
  24. [24]
    Kim Y, Lee J, Yeom M S, et al. Strengthening effect of singleatomic- layer graphene in metal–graphene nanolayered composites. Nature Communications, 2013, 4: 2114Google Scholar
  25. [25]
    Hwang J, Yoon T, Jin S H, et al. Enhanced mechanical properties of graphene/copper nanocomposites using a molecular-level mixing process. Advanced Materials, 2013, 25(46): 6724–6729CrossRefGoogle Scholar
  26. [26]
    Kuang D, Xu L, Liu L, et al. Graphene–nickel composites. Applied Surface Science, 2013, 273: 484–490CrossRefGoogle Scholar
  27. [27]
    Rashad M, Pan F, Tang A, et al. Synergetic effect of graphene nanoplatelets (GNPs) and multi-walled carbon nanotube (MWCNTs) on mechanical properties of pure magnesium. Journal of Alloys and Compounds, 2014, 603(9): 111–118CrossRefGoogle Scholar
  28. [28]
    Neubauer E, Kitzmantel M, Hulman M, et al. Potential and challenges of metal-matrix-composites reinforced with carbon nanofibers and carbon nanotubes. Composites Science and Technology, 2010, 70(16): 2228–2236CrossRefGoogle Scholar
  29. [29]
    Babu J S S, Prabhakaran Nair K, Unnikrishnan G, et al. Development of aluminum-based hybrid composites with graphite nanofibers/alumina short fibers: processing and characterization. Journal of Composite Materials, 2010, 44(16): 1929–1943CrossRefGoogle Scholar
  30. [30]
    Liu J, Khan U, Coleman J, et al. Graphene oxide and graphene nanosheet reinforced aluminium matrix composites: Powder synthesis and prepared composite characteristics. Materials & Design, 2016, 94: 87–94CrossRefGoogle Scholar
  31. [31]
    Mahesh V P, Nair P S, Rajan T P D, et al. Processing of surfacetreated boron carbide-reinforced aluminum matrix composites by liquid-metal stir-casting technique. Journal of Composite Materials, 2011, 45(23): 2371–2378CrossRefGoogle Scholar
  32. [32]
    Rohatgi P K, Gupta N, Alaraj S. Thermal expansion of aluminum–fly ash cenosphere composites synthesized by pressure infiltration technique. Journal of Composite Materials, 2006, 40(13): 1163–1174CrossRefGoogle Scholar
  33. [33]
    Motozuka S, Tagaya M, Ikoma T, et al. Preparation of copper–graphite composite particles by milling process. Journal of Composite Materials, 2012, 46(22): 2829–2834CrossRefGoogle Scholar
  34. [34]
    Singhal S K, Lal M, Sharma I, et al. Fabrication of copper matrix composites reinforced with carbon nanotubes using a combination of molecular-level-mixing and high energy ball milling. Journal of Composite Materials, 2013, 47(5): 613–621CrossRefGoogle Scholar
  35. [35]
    Jagannadham K. Volume fraction of graphene platelets in copper–graphene composites. Metallurgical and Materials Transactions A: Physical Metallurgy and Materials Science, 2013, 44(1): 552–559CrossRefGoogle Scholar
  36. [36]
    Jagannadham K. Thermal conductivity of copper–graphene composite films synthesized by electrochemical deposition with exfoliated graphene platelets. Metallurgical and Materials Transactions B: Process Metallurgy and Materials Processing Science, 2012, 43(2): 316–324CrossRefGoogle Scholar
  37. [37]
    Rashad M, Pan F, Tang A, et al. Improved strength and ductility of magnesium with addition of aluminum and graphene nanoplatelets (Al+ GNPs) using semi powder metallurgy method. Journal of Industrial and Engineering Chemistry, 2015, 23: 243–250CrossRefGoogle Scholar
  38. [38]
    Saboori A, Novara C, Pavese M, et al. An investigation on the sinterability and the compaction behavior of aluminum/graphene nanoplatelets (GNPs) prepared by powder metallurgy. Journal of Materials Engineering and Performance, 2017, 26(3): 993–999CrossRefGoogle Scholar
  39. [39]
    Zhou J, Wang Q, Sun Q, et al. Ferromagnetism in semihydrogenated graphene sheet. Nano Letters, 2009, 9(11): 3867–3870CrossRefGoogle Scholar
  40. [40]
    Kwon H, Kawasaki A. In: Attaf B, ed. Advances in Composite Materials for Medicine and Nanotechnology. InTech,2011, 429–444Google Scholar
  41. [41]
    Jamaati R, Amirkhanlou S, Toroghinejad M R, et al. Comparison of the microstructure and mechanical properties of as-cast A356/SiC MMC processed by ARB and CAR methods. Journal of Materials Engineering and Performance, 2012, 21(7): 1249–1253CrossRefGoogle Scholar
  42. [42]
    Kovácik J, Emmer Š. Thermal expansion of Cu/graphite composites: effect of copper coating. Kovove Materialy, 2011, 49(6): 411–416Google Scholar
  43. [43]
    Chawla N, Shen Y. Mechanical behavior of particle reinforced metal matrix composites. Advanced Engineering Materials, 2001, 3(6): 357–370CrossRefGoogle Scholar
  44. [44]
    Chu K, Jia C. Enhanced strength in bulk graphene–copper composites. Physica Status Solidi A: Applications and Materials Science, 2014, 211(1): 184–190CrossRefGoogle Scholar
  45. [45]
    Lee C, Wei X, Kysar J W, et al. Measurement of the elastic properties and intrinsic strength of monolayer graphene. Science, 2008, 321(5887): 385–388CrossRefGoogle Scholar
  46. [46]
    Dorfman S, Fuks D. Carbon diffusion in copper-based metal matrix composites. Sensors and Actuators A: Physical, 1995, 51(1): 13–16CrossRefGoogle Scholar

Copyright information

© Higher Education Press and Springer-Verlag Berlin Heidelberg 2017

Authors and Affiliations

  • Abdollah Saboori
    • 1
  • Matteo Pavese
    • 1
  • Claudio Badini
    • 1
  • Paolo Fino
    • 1
  1. 1.Department of Applied Science and TechnologyPolitecnico Di TorinoTorinoItaly

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