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NiFeRuOx nanosheets on Ni foam as an electrocatalyst for efficient overall alkaline seawater splitting

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Abstract

The electrocatalyst NiFeRuOx/NF, comprised of NiFeRuOx nanosheets grown on Ni foam, was synthesized using a hydrothermal process followed by thermal annealing. NiFeRuOx/NF displays high electrocatalytic activity and stability for overall alkaline seawater splitting: 98 mV@ 10 mA·cm−2 in hydrogen evolution reaction, 318 mV@ 50 mA·cm−2 in oxygen evolution reaction, and a cell voltage of 1.53 V@ 10 mA·cm−2, as well as 20 h of durability. A solar-driven system containing such a bifunctional NiFeRuOx/NF has an almost 100% Faradaic efficiency. The NiFeRuOx coating around Ni foam is an anti-corrosion layer and also a critical factor for enhancement of bifunctional performances.

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Acknowledgements

This study was supported by National Key R&D Program of China (Grant Nos. 2022YFB3805600 and 2022YFB3805604), South Africa’s National Research Foundation through the SARChI Chair in Materials Electrochemistry and Energy Technologies (Grant No. 132739), National Natural Science Foundation of China (Grant No. 22293020), National 111 project (Grant No. B20002), Program for Innovative Research Team in University of Ministry of Education of China (Grant No. IRT_15R52), Sino-German Centre’s COVID-19 Related Bilateral Collaborative Project (Grant No. C-0046), Guangdong Basic and Applied Basic Research Foundation (Grant No. 2022A1515010137), Shenzhen Science and Technology Program (Grant Nos. GJHZ20210705143204014, JCYJ20210324142010029, and KCXFZ20211020170006010).

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Authors and Affiliations

  1. State Key Laboratory of Advanced Technology for Materials Synthesis and Processing & International School of Materials Science and Engineering & School of Materials Science and Engineering & Shenzhen Research Institute & Laoshan Laboratory, Wuhan University of Technology, Wuhan, 430070, China

    Yu Liu, Lin Chen, Yong Wang, Yuan Dong, Liang Zhou, Kenneth I. Ozoemena & Xiao-Yu Yang

  2. Instituto de Química, Universidade de São Paulo, 05508-080, São Paulo, Brazil

    Susana I. Córdoba de Torresi

  3. Molecular Sciences Institute, School of Chemistry, University of the Witwatersrand, Johannesburg, 2050, South Africa

    Kenneth I. Ozoemena & Xiao-Yu Yang

Authors
  1. Yu Liu
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  2. Lin Chen
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  3. Yong Wang
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  4. Yuan Dong
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  5. Liang Zhou
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  6. Susana I. Córdoba de Torresi
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  7. Kenneth I. Ozoemena
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  8. Xiao-Yu Yang
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Correspondence to Xiao-Yu Yang.

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Liu, Y., Chen, L., Wang, Y. et al. NiFeRuOx nanosheets on Ni foam as an electrocatalyst for efficient overall alkaline seawater splitting. Front. Chem. Sci. Eng. 17, 1698–1706 (2023). https://doi.org/10.1007/s11705-023-2334-8

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  • DOI: https://doi.org/10.1007/s11705-023-2334-8

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