The influence of curing conditions on the mechanical properties and leaching of inorganic polymers made of fayalitic slag

  • Remus Ion Iacobescu
  • Valérie Cappuyns
  • Tinne Geens
  • Lubica Kriskova
  • Silviana Onisei
  • Peter Tom Jones
  • Yiannis Pontikes
Research Article

DOI: 10.1007/s11705-017-1622-6

Cite this article as:
Iacobescu, R.I., Cappuyns, V., Geens, T. et al. Front. Chem. Sci. Eng. (2017). doi:10.1007/s11705-017-1622-6
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Abstract

This study reports on the impact of the curing conditions on the mechanical properties and leaching of inorganic polymer (IP) mortars made from a water quenched fayalitic slag. Three similar IP mortars were produced by mixing together slag, aggregate and activating solution, and cured in three different environments for 28 d: a) at 20 °C and relative humidity (RH) ~ 50% (T20RH50), b) at 20 °C and RH≥90% (T20RH90) and c) at 60 °C and RH ~ 20% (T60RH20). Compressive strength (EN 196-1) varied between 19 MPa (T20RH50) and 31 MPa (T20RH90). This was found to be attributed to the cracks formed upon curing. Geochemical modelling and two leaching tests were performed, the EA NEN 7375 tank test, and the BS EN 12457-1 single batch test. Results show that Cu, Ni, Pb, Zn and As leaching occurred even at high pH, which varied between 10 and 11 in the tank test’s leachates and between 12 and 12.5 in the single batch’s leachates. Leaching values obtained were below the requirements for non-shaped materials of Flemish legislation for As, Cu and Ni in the single batch test.

Keywords

inorganic polymer geochemical leaching modelling heavy metals recycling non-ferrous fayalitic slag curing 

Copyright information

© Higher Education Press and Springer-Verlag Berlin Heidelberg 2017

Authors and Affiliations

  • Remus Ion Iacobescu
    • 1
  • Valérie Cappuyns
    • 2
    • 3
  • Tinne Geens
    • 4
  • Lubica Kriskova
    • 1
  • Silviana Onisei
    • 1
  • Peter Tom Jones
    • 1
  • Yiannis Pontikes
    • 1
  1. 1.Department of Materials EngineeringKU LeuvenLeuvenBelgium
  2. 2.Department of Earth and Environmental SciencesKU LeuvenLeuvenBelgium
  3. 3.Faculty of Economics and BusinessKU LeuvenBrusselsBelgium
  4. 4.Department of Healthcare and TechnologyKU LeuvenLeuvenBelgium

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