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Study on a green synthetic method of TRPPMCl (M = Fe, Mn, Co)

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Abstract

A green synthetic method using mixted solvents of di-methyl formamide (DMF) and acids instead of single DMF to synthesize metalloporphyrins (TRPPMCl) from TRPPH2 and MCl2 metallization was proposed in this paper. A series of TRPPMCl (M = Fe, Mn, Co) were synthesized through this innovative synthetic method, and these complexes were characterized with various spectroscopic techniques, including IR and UV-Vis spectroscopy. The results showed that the metallization time was markedly reduced from about 10 h to 0.5 h in contrast with the conventional synthetic methods.

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Authors and Affiliations

  1. Institute of Green Chemistry and Fine Chemicals, Beijing University of Technology, Beijing, 100124, China

    Jing Fan, Yuanbin She & Aixin Wang

Authors
  1. Jing Fan
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  2. Yuanbin She
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  3. Aixin Wang
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Correspondence to Yuanbin She.

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Fan, J., She, Y. & Wang, A. Study on a green synthetic method of TRPPMCl (M = Fe, Mn, Co). Front. Chem. Eng. China 3, 222–223 (2009). https://doi.org/10.1007/s11705-009-0059-y

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  • DOI: https://doi.org/10.1007/s11705-009-0059-y

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