Skip to main content
SpringerLink
Log in

Study on a green synthesis of μ-oxo-bis [tetraarylphenylporphyrinatoiron]

  • Research Article
  • Published:
Frontiers of Chemical Engineering in China Aims and scope Submit manuscript

Abstract

A novel method for the synthesis of μ-oxo-bis [tetraarylporphyrinatoiron] ([TRPPFe]2O) based on the reaction between tetraarylporphyrinironchloride (TRPPFeCl) and H2O in toluene was investigated in this paper. Three kinds of [TRPPFe]2O were synthesized by this novel synthetic method, and their structures were characterized by elemental analysis, IR spectra and UV-Vis spectroscopy.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Poltowicz J, Tabor E, Pamin K, Haber J. Effect of substituents in the manganese μ-oxo porphyrins catalyzed oxidation of cyclooctane with molecular oxygen. Inorg Chem Commun, 2005, 8: 1125–1127

    Article  CAS  Google Scholar 

  2. Pistorio B J, Chang C J, Nocera D G A. Phototriggered molecular spring for aerobic catalytic oxidation reactions. J Am Chem Soc, 2002, 124: 7884–7885

    Article  CAS  Google Scholar 

  3. She Y B, Feng L S, Wang A X, Li X Y. Synthesis of μ-oxo-bismetallotetraphenylporphyrin. Chinese Patent, 200710099095.7

  4. Lindsey J S, Schreiman I C, Hsu H C, Kearney P C, Marguerettaz A M. Rothemund and adler-longo reactions revisited: synthesis of tetraphenylporphyrins under equilibrium conditions. J Org Chem, 1987, 52: 827–836

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Institute of Green Chemistry and Fine Chemicals, Beijing University of Technology, Beijing, 100124, China

    Aixin Wang, Yuanbin She & Jing Fan

Authors
  1. Aixin Wang
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Yuanbin She
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Jing Fan
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Yuanbin She.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Wang, A., She, Y. & Fan, J. Study on a green synthesis of μ-oxo-bis [tetraarylphenylporphyrinatoiron]. Front. Chem. Eng. China 3, 219–221 (2009). https://doi.org/10.1007/s11705-009-0058-z

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11705-009-0058-z

Keywords

Search

Navigation