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Reaction and characterization of crosslinking hyperbranched poly(amine-ester) with succine anhydride

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Abstract

Basing on hydroxyl terminated hyperbranched poly(amine-ester)s (HPAEs), the cross-linking reactions and preparation of ester-crosslinked HPAE films were investigated using succine anhydride (SA) as crosslink reagent. It was proved that the cross-linking reaction between HPAE and SA followed a two-step mechanism. This mechanism provides an efficient route to prepare HPAE/SA cross-linked films, in which, the precursor films were prepared by casting HPAE/SA solution at a lower temperature, and then curing the films at a higher temperature. By varying SA content, the solid HPAE/SA films with different cross-linking degrees were prepared successfully. The highest tensile strength of the cross-linked film could reach 59.60 MPa. With all water contact angle smaller than 74.3°, the crosslinked films demonstrated good hydrophilic properties.

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Authors and Affiliations

  1. Institute of Polymer Science, Zhejiang University, Hangzhou, 310027, China

    Xiao Ling, Wei Xiuzhen & Zhu Baoku

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  1. Xiao Ling
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  2. Wei Xiuzhen
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  3. Zhu Baoku
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Correspondence to Zhu Baoku.

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Translated from Journal of East University of Science and Technology (Natural Science Edition), 2006, 32(10): 1,164–1,168 [译自: 华东理工大学学报 (自然科学版)]

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Xiao, L., Wei, X. & Zhu, B. Reaction and characterization of crosslinking hyperbranched poly(amine-ester) with succine anhydride. Front. Chem. Eng. China 1, 355–359 (2007). https://doi.org/10.1007/s11705-007-0064-y

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  • DOI: https://doi.org/10.1007/s11705-007-0064-y

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