Abstract
A simple solution-phase approach has been demonstrated for the large-scale synthesis of silver nanowires with diameters in the range of 15–25 nm, and lengths usually in the range of tens of micrometers. In the presence of gemini surfactant 1,3-bis(cetyldimethylammonium) propane dibromide (16-3-16), the growth of silver could be directed into a highly anisotropic mode to form uniform nanowires with aspect ratios up to about 2,000. X-ray photoelectron spectroscopy (XPS), transmission electron microscopy (TEM), energy-dispersive X-ray (EDX), X-ray powder diffraction (XRD), electron diffraction (ED), and UV-vis absorption spectroscopy, were used to characterize the as-prepared silver nanowires, indicating the formation of a highly pure phase, good crystallinity, as well as a uniform diameter.
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El-Sayed M A. Some interesting properties of metals confined in time and nanometer space of different shapes. Accounts Chem Res, 2001, 34: 257–264
Peng X G, Manna L, Yang W D, Wickham J, Scher E, Kadavanich A, Alivisatos A P. Shape control of CdSe nanocrystals. Nature, 2000, 404: 59–61
Lieber C M. One-dimensional nanostructures: Chemistry, physics and applications. Solid State Commun, 1998, 107: 607–616
Templeton A C, Wuelfing W P, Murray R W. Monolayer-protected cluster molecules. Accounts Chem Res, 2000, 33: 27–36
Zhou K B, Wang X, Sun X M, Peng Q, Li Y D. Enhanced catalytic activity of ceria nanorods from well-defined reactive crystal planes. J Catal, 2005, 229: 206–212
Xu J, Han X, Liu H, Hu Y. Synthesis and optical properties of silver nanoparticles stabilized by gemini surfactant. Colloid Surface A, 2006, 273: 179–183
Jin R C, Cao Y W, Mirkin C A, Kelly K L, Schatz G C, Zheng J G. Photoinduced conversion of silver nanospheres to nanoprisms. Science, 2001, 294: 1,901–1,903
Jiang P, Li S Y, Xie S S, Gao Y, Song L. Machinable long PVP-stabilized silver nanowires. Chem-Eur J, 2004, 10: 4,817–4,821
Wang Z H, Liu J W, Chen X Y, Wan J X, Qian Y T. A simple hydrothermal route to large-scale synthesis of uniform silver nanowires. Chem-Eur J, 2005, 11: 160–163
Wiley B, Sun Y G, Mayers B, Xia Y N. Shape-controlled synthesis of metal nanostructures: The case of silver. Chem-Eur J, 2005, 11: 454–463
Wang W, Huang J, Ren Z. Synthesis of germanium nanocubes by a low-temperature inverse micelle solvothermal technique. Langmuir, 2005, 21: 751–754
Feng J, Zeng H C. Size-controlled growth of Co3O4 nanocubes. Chem Mater, 2003, 15: 2,829–2,835
Sau T K, Murphy C J. Room temperature, high-yield synthesis of multiple shapes of gold nanoparticles in aqueous solution. J Am Chem Soc, 2004, 126: 8,648–8,649
Xu R, Zeng H C. Mechanistic investigation on salt-mediated formation of free-standing Co3O4 nanocubes at 95°C. J Phys Chem B, 2003, 107: 926–930
Xiong Y, Wiley B, Chen J, Li Z Y, Yin Y, Xia Y N. Corrosion-based synthesis of single-crystal Pd nanoboxes and nanocages and their surface plasmon properties. Angew Chem Int Edit, 2005, 44: 7,913–7,917
Sun X, Li Y. Ga2O3 and GaN semiconductor hollow spheres. Angew Chem Int Edit, 2004, 43: 3,827–3,831
Kong X Y, Ding Y, Wang Z L. Metal-semiconductor Zn-ZnO core-shell nanobelts and nanotubes. J Phys Chem B, 2004, 108: 570–574
Zheng X, Zhu L, Yan A, Wang X, Xie Y. Controlling synthesis of silver nanowires and dendrites in mixed surfactant solutions. J Colloid Interf Sci, 2003, 268: 357–361
Ma Y, Qi L, Shen W, Ma J. Selective synthesis of single-crystalline selenium nanobelts and nanowires in micellar solutions of nonionic surfactants. Langmuir, 2005, 21: 6,161–6,164
Wang X, Li Y. Selected-control hydrothermal synthesis of α-and β-MnO2 single crystal nanowires. J Am Chem Soc, 2002, 124: 2,880–2,881
Ni C, Hassan P A, Kaler E W. Structural characteristics and growth of pentagonal silver nanorods prepared by a surfactant method. Langmuir, 2005, 21: 3,334–3,337
Favie F, Walter E C, Zach M P, Benter T, Penner R M. Hydrogen sensors and switches from electroeposited palladium mesowire arrays. Science, 2001, 293: 2,227–2,231
Cui Y, Wei Q Q, Park H K, Lieber C M. Nanowire nanosensors for highly sensitive and selective detection of biological and chemical species. Science, 2001, 293: 1,289–1,292
Gudiksen M S, Lauhon L J, Wang J, Smith D C, Lieber C M. Growth of nanowire superlattice structures for nanoscale photonics and electronics. Nature, 2002, 415: 617–620
Hu J T, Odom T W, Lieber C M. Chemistry and physics in one dimension: Synthesis and properties of nanowires and nanotubes. Accounts Chem Res, 1999, 32, 435–445
Sun L, Searson P C, Chien C L. Magnetic anisotropy in prismatic nickel nanowires. Appl Phys Lett, 2001, 79: 4,429–4,431
Peng X G. Mechanisms for the shape-control and shape-evolution of colloidal semiconductor nanocrystals. Adv Mater, 2003, 15: 459–463
Zong R L, Zhou J, Li Q, Du B, Li B, Fu M, Qi X W, Li L T, Buddhudu S. Synthesis and optical properties of silver nanowire arrays embedded in anodic alumina membrane. J Phys Chem B, 2004, 108: 16,713–16,716
Choi J, Sauer G, Nielsch K, Wehrspohn R B, Gosele U. Hexagonally arranged monodisperse silver nanowires with adjustable diameter and high aspect ratio. Chem Mater, 2003, 15: 776–779
Wu Y, Livneh T, Zhang Y X, Cheng G, Wang J, Tang J, Moskovits M, Stucky G D. Templated synthesis of highly ordered mesostructured nanowires and nanowire arrays. Nano Lett, 2004, 4: 2,337–2,342
Day T M, Unwin P R, Wilson N R, Macpherson J V. Electrochemical templating of metal nanoparticles and nanowires on single-walled carbon nanotube networks. J Am Chem Soc, 2005, 127: 10,639–10,647
Braun E, Eichen Y, Sivan U, Ben-Yoseph G. DNA-templated assembly and electrode attachment of a conducting silver wire. Nature, 1998, 391: 775–778
Zhang D, Qi L, Ma J, Cheng H. Formation of silver nanowires in aqueous solutions of a double-hydrophilic block copolymer. Chem Mater, 2001, 13: 2,753–2,755
Jana N R, Gearheart L, Murphy C J. Wet chemical synthesis of silver nanorods and nanowires of controllable aspect ratio. Chem Commun, 2001, 617–618
Zhou Y, Yu S H, Wang C Y, Li X G, Zhu Y R, Chen Z Y. A novel ultraviolet irradiation photoreduction technique for the preparation of single-crystal Ag nanorods and Ag dendrites. Adv Mater, 1999, 11: 850–852
Wang C, Chen M, Zhu G, Lin Z. A novel soft-template technique to synthesize metal Ag nanowire. J Colloid Interf Sci, 2001, 243: 362–364
Zhou Y, Yu S H, Cui X P, Wang C Y, Chen Z Y. Formation of silver nanowires by a novel solid-liquid phase are discharge method. Chem Mater, 1999, 11: 545–546
Zhu J J, Liu S W, Palchik O, Koltypin Y, Gedanken A. Shape-controlled synthesis of silver nanoparticles by pulse sonoelectrochemical methods. Langmuir, 2000, 16: 6,396–6,399
Xu J, Hu J, Peng C, Liu H, Hu Y. A simple approach to the synthesis of silver nanowires by hydrothermal process in the presence of gemini surfactant. J Colloid Interf Sci, 2006, 298: 689–693
Chen Q B, Wei Y H, Shi Y H, Liu H L, Hu Y. Measurement of surface tension and electrical conductivity of cationic gemini surfactants. Journal of East China University of Science and Technology, 2003, 29: 33–37 (in Chinese)
Gao Y, Jiang P, Liu D F, Yuan H J, Yan X Q, Zhou Z P, Wang J X, Song L, Liu L F, Zhou W Y, Wang G, Wang C Y, Xie S S. Evidence for the monolayer assembly of poly(vinylpyrrolidone) on the surfaces of silver nanowires. J Phys Chem B, 2004, 108: 12,877–12,881
Sun Y G, Mayers B, Herricks T, Xia Y N. Polyol synthesis of uniform silver nanowires: A plausible growth mechanism and the supporting evidence. Nano Lett, 2003, 3: 955–960
Sun Y G, Yin Y D, Mayers B T, Herricks T, Xia Y N. Uniform silver nanowires synthesis by reducing AgNO3 with ethylene glycol in the presence of seeds and poly(vinylpyrrolidone). Chem Mater, 2002, 14: 4,736–4,745
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Xu, J., Liu, W., Liu, H. et al. Controlled synthesis of uniform silver nanowires with high aspect ratios in aqueous solutions of gemini surfactant. Front. Chem. Eng. China 1, 221–227 (2007). https://doi.org/10.1007/s11705-007-0040-6
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DOI: https://doi.org/10.1007/s11705-007-0040-6