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Synthesis of a new iron(III) porphyrin acrylate-styrene copolymer and its catalysis for hydroxylation of cyclohexane

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Abstract

A new iron(III) porphyrin acrylate-styrene copolymer, P[(PorFe)A-S], was synthesized by the reaction of iron(III) porphyrin acrylate with styrene and characterized by UV-Vis, Infrared spectra (IR), inductively coupled plasmaatomic emission spectrometry (ICP) and molecular weight determination. Its catalytic activity in the hydroxylation of cyclohexane for model cytochrome P450 in the P[(PorFe) A-S]-O2-ascrobate-thiosalicylic acid system has been studied. It was found that the P[(PorFe)A-S] has a higher catalytic activity than non-supported iron(III) porphyrin and its high catalytic activity remained in reuse. The catalytic activity of P[(PorFe)A-S] was discussed in the view of the microenvironment of iron(III) porphyrin. It is proposed that the catalytic activity of the P[(PorFe)A-S] may be further enhanced by construction of a homophase catalytic system containing the iron(III) porphyrin acrylate-styrene copolymer.

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Authors and Affiliations

  1. School of Chemistry and Chemical Engineering, Sun Yat-sen University, Guangzhou, 510275, China

    Yu Hancheng, Li Xixian, Huang Jinwang & Ji Liangnian

  2. Pharmacological Department, Medical College of Shaoguan University, Shaoguan, 512026, China

    Chen Xianli

Authors
  1. Yu Hancheng
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  2. Chen Xianli
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  3. Li Xixian
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  4. Huang Jinwang
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  5. Ji Liangnian
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Corresponding author

Correspondence to Huang Jinwang.

Additional information

Translated from Acta Scientiarum Naturalium Universitatis Sunyatseni, 2006, 45(1): 61–63 [译自: 中山大学学报 (自然科学版)]

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Yu, H., Chen, X., Li, X. et al. Synthesis of a new iron(III) porphyrin acrylate-styrene copolymer and its catalysis for hydroxylation of cyclohexane. Front. Chem. Eng. China 1, 65–67 (2007). https://doi.org/10.1007/s11705-007-0013-9

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  • DOI: https://doi.org/10.1007/s11705-007-0013-9

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