Abstract
The availability of active compounds is quite low, and a long extraction and isolation process is required. Mesoporous silica nanoparticles (MSNs) are promising materials with varying pore sizes and a large surface area that can be used for the extraction, isolation, and separation of active compounds from natural products. Molecularly imprinted mesoporous silica (MIP-MS), which is the combination of molecularly imprinted polymers (MIPs) and MSNs, exhibits some benefits such as improved binding capacity, reduced equilibrium time, high surface-to-volume ratio, and also good selectivity. The adsorption capacity of MIP-MS ranges from 11.9–45.31 mg/g, the imprinting factor ranges from 1.87–1.95, and the efficiency exceeds 90% after six repetitions. These properties are ideal for the isolation or separation of active compounds from natural products. This review aims to discover the potential of MIP-MS for the separation of active compounds from natural products, which is currently limited by the source of knowledge but has a great potential for its implementation. In this review, the essentials of MIP-MS, such as the synthesis methods of mesoporous silica, the application of mesoporous silica on MIPs for natural products, and the advantages of MIP-MS, will be discussed.
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Abbreviations
- 4-VP:
-
4-Vinylpyridine
- AIBN:
-
2,2-Azobis(isobutyronitrile)
- BET:
-
Brunauer–Emmett–Teller
- BMCM:
-
Boron-silica mesoporous
- CA:
-
Caffeic acid
- CTAB:
-
Cetyltrimethylammonium bromide
- DES:
-
Diethylstilbestrol
- ECG:
-
Epicatechin gallate
- EGCG:
-
Epigallocatechin gallate
- EGDMA:
-
Ethylene glycol dimethacrylate
- EO:
-
Ethylene oxide
- HPLC:
-
High-performance liquid chromatography
- HPLC–MS:
-
High-performance liquid chromatography-mass spectrometry
- HPMIPs:
-
Hollow MOLECULARLY imprinted mesoporous silica
- HS-SPME:
-
Headspace solid-phase microextraction
- IF:
-
Imprinting factors
- IUPAC:
-
International union of pure and applied chemistry
- M41S:
-
Molecular 41 sieves
- MAE:
-
Microwave-assisted extraction
- MA-HS-SPME:
-
Microwave-assisted headspace solid-phase microextraction
- MB:
-
Magnetic beads
- MIP:
-
Molecularly imprinted polymer
- MIP-MS:
-
Molecularly imprinted mesoporous silica
- MMIP:
-
Magnetic molecularly imprinted polymer
- mSiO2 :
-
Magnetic mesoporous silica
- MSNs:
-
Mesoporous silica nanoparticles
- PCA:
-
Protocatechuic acid
- PLE:
-
Pressurized liquid extraction
- PMO-IL:
-
Periodic mesoporous organosilica based on alkylimidazolium ionic liquid
- PO:
-
Propylene oxide
- RSD:
-
Repeatability relative standard deviation
- SBA:
-
Santa barbara amorphous
- SFE:
-
Supercritical fluid extraction
- SPE:
-
Solid-phase EXTRACTION
- SPME:
-
Solid-phase microextraction
- TEOS:
-
Tetraethylorthosilicate
- TMOS:
-
Tetramethylorthosilicate
- TMVS:
-
Tetramethoxyvinylsilane
- TPOS:
-
Tetrapropoxysilane
- UAE:
-
Ultrasonic-assisted extraction
- UHPLC-MS/MS:
-
Ultra-high-performance liquid chromatography tandem mass spectrometry
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Lie, K.R., Samuel, A.O. & Hasanah, A.N. Molecularly imprinted mesoporous silica: potential of the materials, synthesis and application in the active compound separation from natural product. Chem. Pap. 76, 2595–2613 (2022). https://doi.org/10.1007/s11696-022-02074-7
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DOI: https://doi.org/10.1007/s11696-022-02074-7