Abstract
This paper describes an effervescence-assisted liquid phase microextraction (EA-LPME) method coupled to the SQT-FAAS system for determining trace levels of cadmium in domestic wastewater samples. Preconcentration of the cadmium ions was carried out by forming carbon dioxide bubbles with the help of effervescent tablets without the need for a dispersive solvent. 1-undecanol was used both as the extractant and solidifying agent for the tablets, and the complexation of the Cd metal was provided by diphenylcarbazone. To achieve maximum efficiency in the extraction process, optimization steps were investigated individually and optimized. Under the optimum conditions, LOD and LOQ values calculated for the developed method were 0.38 and 1.3 µg/L, respectively. An 84-fold enhancement in the detection power of the FAAS system was achieved with the proposed method. Developed EA-LPME-SQT-FAAS method was applied to domestic wastewater samples and the recovery results demonstrated high experimental precision (%RSD < 10) with percent recoveries close to 100%. Developed method is easy, sensitive and accurate for the determination of analyte.
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Abolghasemi MM, Piryaei M, Imani RM (2020) Deep eutectic solvents as extraction phase in head-space single-drop microextraction for determination of pesticides in fruit juice and vegetable samples. Microchem J 158:105041. https://doi.org/10.1016/j.microc.2020.105041
Acar O (2001) Determination of cadmium and lead in biological samples by Zeeman ETAAS using various chemical modifiers. Talanta 55(3):613–622. https://doi.org/10.1016/S0039-9140(01)00468-4
Amen R, Yaseen M, Mukhtar A, Klemeš JJ, Saqib S, Ullah S, Al-Sehemi AG, Rafiq S, Babar M, Fatt CL, Ibrahim M, Asif S, Qureshi KS, Akbar MM, Bokhari A (2020) Lead and cadmium removal from wastewater using eco-friendly biochar adsorbent derived from rice husk, wheat straw, and corncob. Clean Eng Technol 1:100006. https://doi.org/10.1016/j.clet.2020.100006
Arain MB, Yilmaz E, Soylak M (2016) Deep eutectic solvent based ultrasonic assisted liquid phase microextraction for the FAAS determination of cobalt. J Mol Liq 224(Part A):538–543
Arpa Ç, Albayati S, Yahya M (2018) Effervescence-assisted dispersive liquid-liquid microextraction based on deep eutectic solvent for preconcentration and FAAS determination of copper in aqueous samples. Int J Environ Anal Chem 98(10):938–953. https://doi.org/10.1080/03067319.2018.1517872
Borahan T, Zaman B, Polat BSA, Bakırdere EG, Bakırdere S (2021) An accurate and sensitive effervescence-assisted liquid phase microextraction method for the determination of cobalt after a Schiff base complexation by slotted quartz tube-flame atomic absorption spectrophotometry in urine samples. Anal Methods 13:703–711. https://doi.org/10.1039/D0AY02264K
de Dias FS, Guarino MEPA, Pereira ALC, Pedra PP, Bezerra MA, Marchetti SG (2019) Optimization of magnetic solid phase microextraction with CoFe2O4 nanoparticles unmodified for preconcentration of cadmium in environmental samples by flame atomic absorption spectrometry. Microchem J 146:1095–1101. https://doi.org/10.1016/j.microc.2019.02.005
Elik A, Altunay N, Gürkan R (2017) Microextraction and preconcentration of Mn and Cd from vegetables, grains and nuts prior to their determination by flame atomic absorption spectrometry using room temperature ionic liquid. J Mol Liq 247:262–268. https://doi.org/10.1016/j.molliq.2017.09.121
El-Sheikh AH, Nofal FS, Shtaiwi MH (2019) Adsorption and magnetic solid-phase extraction of cadmium and lead using magnetite modified with schiff bases. J Environ Chem Eng 7(4):103229. https://doi.org/10.1016/j.jece.2019.103229
Faraji M, Noormohammadi F, Adeli M (2020) Preparation of a ternary deep eutectic solvent as extraction solvent for dispersive liquid-liquid microextraction of nitrophenols in water samples. J Environ Chem Eng 8(4):103948. https://doi.org/10.1016/j.jece.2020.103948
Hemmati M, Rajabi M (2019) Switchable fatty acid based CO2-effervescence ameliorated emulsification microextraction prior to high performance liquid chromatography for efficient analyses of toxic azo dyes in foodstuffs. Food Chem 286:185–190. https://doi.org/10.1016/j.foodchem.2019.01.197
Hutton EA, van Elteren JT, Ogorevc B, Smyth MR (2004) Validation of bismuth film electrode for determination of cobalt and cadmium in soil extracts using ICP–MS. Talanta 63(4):849–855. https://doi.org/10.1016/j.talanta.2003.12.038
Jing X, He J, Zhao W, Huang X, Wang X (2020) Effervescent tablet-assisted switchable hydrophilicity solvent-based microextraction with solidification of floating organic droplets for HPLC determination of phenolic endocrine disrupting chemicals in bottled beverages. Microchem J 155:104680. https://doi.org/10.1016/j.microc.2020.104680
Kaya G, Yaman M (2008) Online preconcentration for the determination of lead, cadmium and copper by slotted tube atom trap (STAT)-flame atomic absorption spectrometry. Talanta 75(4):1127–1133. https://doi.org/10.1016/j.talanta.2008.01.008
Khan S, Kazi TG, Soylak M (2015) A green and efficient in-syringe ionic liquid-based single step microextraction procedure for preconcentration and determination of cadmium in water samples. J Ind Eng Chem 27:149–152. https://doi.org/10.1016/j.jiec.2014.12.028
Khan S, Yilmaz E, Kazi TG, Soylak M (2014) Vortex assisted liquid-liquid microextraction using triton X-114 for ultratrace cadmium prior to analysis. CLEAN – Soil Air Water 42(8):1083–1088. https://doi.org/10.1002/clen.201300486
Kumata H, Morimoto C, Horie A, Tanabe A, Fujimori E, Umemura T (2020) Elimination of interfering molybdenum oxyanion with an anion-exchange monolithic spin tip (AXTip) for precise determination of cadmium in human urine by ICP-MS. Talanta Open 2:100009. https://doi.org/10.1016/j.talo.2020.100009
Lisboa TP, de Faria LV, Matos MAC, Matos RC, de Sousa RA (2019) Simultaneous determination of cadmium, lead, and copper in the constituent parts of the illegal cigarettes by Square Wave Anodic Stripping Voltammetry. Microchem J 150:104183. https://doi.org/10.1016/j.microc.2019.104183
Liu X, Liu C, Wang P, Yao G, Liu D, Zhou Z (2018) Effervescence assisted dispersive liquid-liquid microextraction based on cohesive floating organic drop for the determination of herbicides and fungicides in water and grape juice. Food Chem 245:653–658. https://doi.org/10.1016/j.foodchem.2017.08.100
Liu Y, Chu Y, Hu Z, Zhang S, Ma S, Khan MS, Chen F, Zhang D, Guo L, Lau C (2020) High-sensitivity determination of trace lead and cadmium in cosmetics using laser-induced breakdown spectroscopy with ultrasound-assisted extraction. Microchem J 158:105322. https://doi.org/10.1016/j.microc.2020.105322
Maslov MM, Elik A, Demirbaş A, Katin KP, Altunay N (2020) Theoretical and experimental studies aimed at the development of vortex-assisted supramolecular solvent microextraction for determination of nickel in plant samples by FAAS. Microchem J 159:105491. https://doi.org/10.1016/j.microc.2020.105491
Moghadam AG, Rajabi M, Hemmati M, Asghari A (2017) Development of effervescence-assisted liquid phase microextraction based on fatty acid for determination of silver and cobalt ions using micro-sampling flame atomic absorption spectrometry. J Mol Liq 242:1176–1183. https://doi.org/10.1016/j.molliq.2017.07.038
Mohamadi M, Mostafavi A (2010) A novel solidified floating organic drop microextraction based on ultrasound-dispersion for separation and preconcentration of palladium in aqueous samples. Talanta 81(1–2):309–313. https://doi.org/10.1016/j.talanta.2009.12.004
Narin I, Soylak M, Kayakirilmaz K, Elci L, Dogan M (2003) Preparation of a Chelating Resin by Immobilizing 1-(2-Pyridylazo) 2-Naphtol on Amberlite XAD-16 and Its Application of Solid Phase Extraction of Ni(II), Cd(II), Co(II), Cu(II), Pb(II), and Cr(III) in Natural Water Samples. Anal Lett 36(3):641–658. https://doi.org/10.1081/AL-120018254
Neves DSC, Souza AS, de Lemos LR (2020) Multivariate optimization of an aqueous two-phase extraction for determination of cadmium and manganese in food sample. Microchem J 159:105458. https://doi.org/10.1016/j.microc.2020.105458
Rajabi M, Abolhosseini M, Hosseini-Bandegharaei A, Hemmati M, Ghassab N (2020) Magnetic dispersive micro-solid phase extraction merged with micro-sampling flame atomic absorption spectrometry using (Zn-Al LDH)-(PTh/DBSNa)-Fe3O4 nanosorbent for effective trace determination of nickel(II) and cadmium(II) in food samples. Microchem J 159:105450. https://doi.org/10.1016/j.microc.2020.105450
Şahin ÇA, Durukan İ (2011) Ligandless-solidified floating organic drop microextraction method for the preconcentration of trace amount of cadmium in water samples. Talanta 85(1):657–661. https://doi.org/10.1016/j.talanta.2011.04.044
Shishov A, Sviridov I, Timofeeva I, Chibisova N, Moskvin L, Bulatov A (2017) An effervescence tablet-assisted switchable solvent-based microextraction: on-site preconcentration of steroid hormones in water samples followed by HPLC-UV determination. J Mol Liq 247:246–253. https://doi.org/10.1016/j.molliq.2017.09.120
Sixto A, Fiedoruk-Pogrebniak M, Rosende M, Cocovi-Solberg D, Knochen M, Miró M (2016) A mesofluidic platform integrating restricted access-like sorptive microextraction as a front end to ICP-AES for the determination of trace level concentrations of lead and cadmium as contaminants in honey. J Anal at Spectrom 31(2):473–481. https://doi.org/10.1039/C5JA00387C
Sorouraddin SM, Farajzadeh MA, Qarajeh HN (2019) Phthalic acid as complexing agent and co-disperser for analysis of zinc and cadmium at trace levels from high volumes of sample on the base of an effervescence-assisted dispersive liquid-liquid microextraction. Microchem J 147:886–893. https://doi.org/10.1016/j.microc.2019.04.005
Valasques GS, dos Santos AMP, de Souza VS, Teixeira LSG, Alves JPS, de Jesus SM, dos Santos WPC, Bezerra MA (2020) Multivariate optimization for the determination of cadmium and lead in crude palm oil by graphite furnace atomic absorption spectrometry after extraction induced by emulsion breaking. Microchem J 153:104401. https://doi.org/10.1016/j.microc.2019.104401
Worawit C, Alahmad W, Miró M, Varanusupakul P (2020) Combining graphite with hollow-fiber liquid-phase microextraction for improving the extraction efficiency of relatively polar organic compounds. Talanta 215:120902. https://doi.org/10.1016/j.talanta.2020.120902
Yang M, Wu X, Jia Y, Xi X, Yang X, Lu R, Zhang S, Gao H, Zhou W (2016) Use of magnetic effervescent tablet-assisted ionic liquid dispersive liquid–liquid microextraction to extract fungicides from environmental waters with the aid of experimental design methodology. Anal Chim Acta 906:118–127. https://doi.org/10.1016/j.aca.2015.12.019
Yuan Y, Wu Y, Wang H, Tong Y, Sheng X, Sun Y, Zhou X, Zhou Q (2020) Simultaneous enrichment and determination of cadmium and mercury ions using magnetic PAMAM dendrimers as the adsorbents for magnetic solid phase extraction coupled with high performance liquid chromatography. J Hazard Mater 386:121658. https://doi.org/10.1016/j.jhazmat.2019.121658
Zamadar M, Orr C, Uherek M (2016) Water soluble cationic porphyrin sensor for detection of Hg2+, Pb2+, Cd2+, and Cu2+. J Sens 2016:1905454. https://doi.org/10.1155/2016/1905454
Zhao W, Jing X, Tian Y, Feng C (2020) Magnetic Fe3O4 @ porous activated carbon effervescent tablet-assisted deep eutectic solvent-based dispersive liquid–liquid microextraction of phenolic endocrine disrupting chemicals in environmental water. Microchem J 159:105416. https://doi.org/10.1016/j.microc.2020.105416
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Borahan, T., Karlıdağ, N.E., Yağcı, Ö. et al. Effervescence-assisted liquid phase microextraction prior to slotted quartz tube-flame atomic absorption spectrometry for cadmium determination in domestic wastewater samples. Chem. Pap. 75, 6307–6314 (2021). https://doi.org/10.1007/s11696-021-01796-4
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DOI: https://doi.org/10.1007/s11696-021-01796-4