Skip to main content
Log in

Charge, hydrophobic and spatial matching in the association of fluorescent reagents with ionic surfactants in aqueous solutions

  • Original Paper
  • Published:
Chemical Papers Aims and scope Submit manuscript

Abstract

The influence of charge, hydrophobicity, and spatial characteristics on the analytical signal of cationic and anionic surfactants in their association with fluorescent reagents in aqueous solutions is studied. The increase in the analytical signal of the surfactant and the shift in the position of the fluorescence wavelengths maximum with increasing contribution of the role of electrostatic interactions between the reagent particle and the ionic surfactant have been shown. The presence of extrema under conditions of hydrophobic matching in the study of the effect of hydrophobicity of the reagent and ionic surfactants on the surfactant analytical signal has been shown. The manifestation of the spatial matching between the interacting particles in the study of the influence of the spatial characteristics of the reagents and surfactants has also been shown. The influence of colloidal aggregation of associates formed in the reagent-surfactant system on the value of measurement of the analytical signal of the ionic surfactants in the methods of fluorescence and spectrophotometry has been investigated. The obtained effects made it possible to design an analytical system for the determination of sodium dodecyl sulfate with a fluorescent reagent.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7

Similar content being viewed by others

References

  • Atwood JL (2017) Comprehensive Supramolecular Chemistry II. Elsevier, the Netherlands

  • Azuma N, Ruba M, Asiri A, Bawazeer W (2017) Micellar and interfacial properties of amphiphilic drug–non-ionic surfactants mixed systems: surface tension, fluorescence and UV–vis studies. Coll Surf A 522:183–192. https://doi.org/10.1016/j.colsurfa.2017.02.093

    Article  CAS  Google Scholar 

  • Burakham R, Jakmunee J, Grudpan K (2006) Development of sequential injection-lab-at-valve (SI-LAV) micro-extraction instrumentation for the spectrophotometric determination of an anionic surfactant. Anal Sci 22:137–140. https://doi.org/10.2116/analsci.22.137

    Article  CAS  PubMed  Google Scholar 

  • Cortina M, Ecker C, Calvo D, Valle M (2008) Automated electronic tongue based on potentiometric sensors for the determination of a trinary anionic surfactant mixture. J Pharm Biomed Anal 46:213–218. https://doi.org/10.1016/j.jpba.2007.09.013

    Article  CAS  PubMed  Google Scholar 

  • Dolenko S (2013) Sorption-photometric method for determination of sodium dodecyl sulfate with methylene blue at presence of additions of non-ionic surfactant in water solution. J Water Chem Tech 35:212–220. https://doi.org/10.3103/S1063455X13030041

    Article  CAS  Google Scholar 

  • Fedorchuk O, Kulichenko S, Kochetov G (2010) Micellar extraction of anti-inflammatory drugs by modified phases of Triton X-100. Methods Objects Chem Anal 5:202–210 ([in Russian])

    Google Scholar 

  • Hampel M, Mauffret A, Pazdro K, Blasco J (2012) Anionic surfactant linear alkylbenzene sulfonates (LAS) in sediments from the Gulf of Gdańsk (southern Baltic Sea, Poland) and its environmental implications. Environ Monit Assess 184:6013–6023. https://doi.org/10.1007/s10661-011-2399-6

    Article  CAS  PubMed  Google Scholar 

  • Kasahara I, Hashimoto K, Kawabe T, Kunita A, Magawa K, Hata N, Taguchi S, Goto K (1995) Spectrophotometric determination of anionic surfactants in sea-water based on ion-pair extraction with bis[2-(5-trifluoromethyl-2-pyridylazo)-5-diethylaminophenolato]cobalt(III) as counter ion. Analyst 120:1803–1807. https://doi.org/10.1039/AN9952001803

    Article  CAS  Google Scholar 

  • Klenyn V, Shchepolev S, Lavrushyn V (1977) Characteristic functions of light scattering of dispersed systems. Yzd-vo Saratov un-ta, Saratov

    Google Scholar 

  • Klovak V, Kulichenko S, Lelyushok S (2020) Influence of colloid-chemical state of solutions on fluorescence and spectrophotometry analytical signals of surfactants in reaction with eosin Y. Chem Pap. https://doi.org/10.1007/s11696-020-01245-8

    Article  Google Scholar 

  • Klovak V, Lelyushok S, Ischenko M (2017) The micellar extraction preconcentration of Pb(II) with sulfarsazen into the phase of non-ionic surfactant Triton X-100. Methods Objects Chem Anal 12:140–144. https://doi.org/10.17721/moca.2017.140-144 [in Ukraininan]

  • Klovak V, Nechpai L, Lelyushok S, Kulichenko S, Zaporozhets O (2019) Fluorescence characteristics of associates of eosin Y with cationic surfactants in water-micellar systems of Triton X-100. Dopov Nac akad nauk Ukr 10:74–81 https://doi.org/10.15407/dopovidi2019.10.074 [in Ukraininan]

  • Kwon Y (2002) Handbook of essential pharmacokinetics, pharmacodynamics and drug metabolism for industrial scientists (partition and distribution coefficients). Kluwer Academic/Plenum Publishers, New York

    Google Scholar 

  • Latif M, Wanfi L, Hanif N, Roslan R, Ali M, Mushrifah I (2012) Composition and distribution of surfactants around Lake Chini. Malaysia Environ Monit Assess 184:1325–1334. https://doi.org/10.1007/s10661-011-2043-5

    Article  CAS  PubMed  Google Scholar 

  • Leaist DG (1991) Boltzmann transformation of taylor dispersion profiles to determine concentration-dependent diffusion coefficients. aqueous cetylpyridinium chloride near the critical micelle concentration. Ber Bunsen Phys Chem 95:113–117. https://doi.org/10.1002/bbpc.19910950202

    Article  CAS  Google Scholar 

  • Martínez-Barrachina S, Valle M (2006) Use of a solid-phase extraction disk module in a FI system for the automated preconcentration and determination of surfactants using potentiometric detection. Microchem J 83:48–54. https://doi.org/10.1016/j.microc.2006.01.022

    Article  CAS  Google Scholar 

  • Mchedlov-Petrossyan N, Vodolazkaya N, Doroshenko A (2003) Ionic equilibria of fluorophores in organized solutions: The influence of micellar microenvironment on protolytic and photophysical properties of rhodamine B. J Fluoresc 13:235–248. https://doi.org/10.1023/A:1025089916356

    Article  CAS  Google Scholar 

  • Miller AC (2008) Handbook of surface and colloid chemistry (solubilization in surfactant systems). CRC Press, Boca Raton

    Google Scholar 

  • Moskvin A (1996) Flow-injection flow-through analyzers. J Anal Chem 51:909 ([in Russian])

    Google Scholar 

  • Niu X, Xu Q, Li A, Li Y, Zhang X, Zhang Y, Xing G (2019) A BODIPY-carbazole hybrid as a fluorescent probe: the design, synthesis, and discrimination of surfactants and the determination of the CMC values. Analyst 144:6866–6870. https://doi.org/10.1039/C9AN01940E

    Article  CAS  PubMed  Google Scholar 

  • Premalatha N, Miranda LR (2019) Surfactant modified ZnO–Bi2O3 nanocomposite for degradation of lambda- cyhalothrin pesticide in visible light: a study of reaction kinetics and intermediates. J Environ Manage 246:259–266. https://doi.org/10.1016/j.jenvman.2019.05.155

    Article  CAS  PubMed  Google Scholar 

  • PubChem US National Library of Medicine National Center for Biotechnology Information. https://pubchem.ncbi.nlm.nih.gov/ (Accessed 27 July 2020)

  • Ruiz-Morales Y, Romero-Martínez A (2018) Coarse-grain molecular dynamics simulations to investigate the bulk viscosity and critical micelle concentration of the ionic surfactant sodium dodecyl sulfate (SDS) in aqueous solution. J Phys Chem B 122:3931–3943. https://doi.org/10.1021/acs.jpcb.7b10770

    Article  CAS  PubMed  Google Scholar 

  • Sànchez J, Valle M (2005) Determination of anionic surfactants employing potentiometric sensors—a review. Crit Rev Anal Chem 35:15–29. https://doi.org/10.1080/10408340590947899

    Article  CAS  Google Scholar 

  • Sánchez-Martínez M, Aguilar-Caballos M, Eremin S, Gómez-Hens A (2007) Long-wavelength fluorescence polarization immunoassay for surfactant determination. Talanta 72:243–248. https://doi.org/10.1016/j.talanta.2006.10.024

    Article  CAS  PubMed  Google Scholar 

  • Schalley C (2007) Analytical methods in supramolecular chemistry. Wiley-VCH Verlag GmbH & Co. KgaA, Weinheim

    Google Scholar 

  • Shevchenko H, Kulichenko S (2010) The influence of emulsions stabilized by non-ionic surfactants onto the formation and stability of associates of bromophenol blue with cationic surfactants. Visnyk Kyiv un-tu Khimiia 48:13–15 ([in Ukrainian])

    Google Scholar 

  • Shtykov S (2015) Nanoobjects and nanotechnologies in chemical analysis. Science, Moscow ([in Russian])

    Google Scholar 

  • Steed JW, Atwood JL (2013) Supramolecular chemistry, 2nd edn. Wiley, Chichester

    Google Scholar 

  • Strelkova K, Varygina O, Chernova R, Koblova O, Kostritsky A (2017) On interaction of synthetic food dye E133 with cetylpiridinium cations. Izv Saratov Univ 17:376–381. https://doi.org/10.18500/1816-9775-2017-17-4-376-381

  • Yakubovskaya A, Zavada O, Vodolazkaya N, Alekseeva V, Mchedlov-Petrossyan N (2005) The acid-base equilibria of rhodamine dyes in micellar solutions of colloidal surfactants. Kharkov Univ Bull 669:151–155 ([in Russian])

    CAS  Google Scholar 

  • Zhu C-Q, Wu Y-Q, Zheng H, Chen J-L, Zhuo S-J, Li Y-X (2004) Fluorescence enhancement method for measuring anionic surfactants with a hydrophobic cyanine dye. Anal Bioanal Chem 379:730–734. https://doi.org/10.1007/s00216-004-2648-4

    Article  CAS  PubMed  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Viktoriia Klovak.

Ethics declarations

Conflict of interest

On behalf of all authors, the corresponding author states that there is no conflict of interest.

Additional information

Publisher's Note

Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Klovak, V., Kulichenko, S. & Lelyushok, S. Charge, hydrophobic and spatial matching in the association of fluorescent reagents with ionic surfactants in aqueous solutions. Chem. Pap. 75, 2477–2484 (2021). https://doi.org/10.1007/s11696-020-01498-3

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11696-020-01498-3

Keywords

Navigation