Abstract
The separation of the binary mixture formic acid–water is difficult by conventional distillation since it forms maximum boiling azeotrope at atmospheric pressure. The separation by altering the column pressure is possible if the pressure has a considerable effect on the azeotropic composition. The previous studies of vapor–liquid equilibrium of binary system formic acid–water have shown that the azeotrope is sensitive to pressure. This work aims to study the effect of the concentration of formic acid in the binary mixture formic acid–water on the ease of separation using two distillation columns operating at different pressures, which are determined by the composition variation of the azeotrope with pressure. The process consists of two-column, the first column operating at pressure of 1.96 bar to recover water and the second column operating at pressure of 0.267 bar to recover formic acid. The best operating parameters have been determined to get the high recovery ratio of formic acid.
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References
Abrams DS, Prausnitz JM (1975) Statistical thermodynamics of liquid mixtures: a new expression for the excess Gibbs energy of partly or completely miscible systems. AIChE J 21(1):116–128. https://doi.org/10.1002/aic.690210115
Abu-Eishah SI, Luyben WL (1985) Design and control of two-column azeotropic distillation system. Ind Eng Chem Proc Des Dev 24:132–140. https://doi.org/10.1021/i200028a024
Berg L, Yeh A (1987) Dehydration of formic acid by extractive distillation. United States Patent. Serial N°4,642,166.
Cao Y, Hu J, Jia H, Bu G, Zhu Z, Wang Y (2017) Comparison of pressure-swing distillation and extractive distillation with varied-diameter column in economics and dynamic control. J Process Contr 49:9–25. https://doi.org/10.1016/j.jprocont.2016.11.005
Chalov NV, Aleksandrova OA (1957) Liquid-vapor phase equilibrium of formic acid-water at normal and low pressures. Gidroliz Lesokhim Prom 10:15–17
Chang T, Shih TT (1989) Development of an azeotropic distillation scheme for purification of tetrahydrofuran. Fluid Phase Equilib 52:161–168. https://doi.org/10.1016/0378-3812(89)80322-X
Frank TC (1997) Break azeotropes with pressure-swing sensitive distillation. Chem Eng Prog 12:52–63
Fulgueras AM, Poudel J, Kim DS, Cho J (2016) Optimization study of pressure-swing distillation for the separation process of a maximum-boiling azeotropic system of water ethylenediamine. Korean J Chem Eng 33:46–56. https://doi.org/10.1007/s11814-015-0100-4
Furter WF (1977) Extractive distillation by salt effect. Can J Chem Eng 55:229–239
Gilburd MM, Moin FB, Pazdersky YuA (1984) Equilibre de phases liquide-vapeur dans le système eau-acide formique aux pressions élevées. Zh Prikl Khim 57:915–917
Gmehling J, Onken U (1982) Vapor-liquid equilibrium data collection. Dechema Chem Data Ser 1(5):693
Herbinet O, Battin-Leclerc F (2011) Detailed product analysis during the flow temperature oxidation of n-butane. Phys Chem Phys 13:296–308. https://doi.org/10.1039/C0CP00539H
Ito T, Yoshida F (1963) Vapor-liquid equilibria of water-lower fatty acid systems: water-formic acid, water acetic acid and water-propionic acid. J Chem Eng Data 8:315
Lewis WK (1928) Dehydrating alcohol and the like. US. Patent Office, Serial N° 1,676,700.
Li W, Zhong L, He Y, Meng J, Yao F, Guo Y, Xu C (2015) Multiple steady-states analysis and unstable operating point stabilization in homogeneous azeotropic distillation with intermediate entrainer. Ind Eng Chem Res 54:7668–7686. https://doi.org/10.1021/acs.iecr.5b00572
Li X, Yang X, Wang S, Yang J, Wang L, Zhu Z, Cui P, WangY GJ (2019a) Separation of ternary mixture with double azeotropic system by a pressure-swing batch distillation integrated with quasi-continuous. Process Saf Environ Prot 128:85–94. https://doi.org/10.1016/j.psep.2019.05.040
Li X, Gen X, Cui P, Yang J, Zhu Z, Wang Y (2019b) Thermodynamic efficiency enhancement of pressure-swing distillation process via heat integration and heat pump technology. Appl Therm Eng 154:519–529. https://doi.org/10.1016/j.applthermaleng.2019.03.118
Liadosa E, Montón JB, Burguet M (2011) Separation of di-n-propyl ether and n-propyl alcohol by extractive distillation and pressure-swing distillation: Computer simulation and economic optimization. Chem Eng Proc 7:1266–1274. https://doi.org/10.1016/j.cep.2011.07.010
Luyben WL (2008) Comparison of extractive distillation and pressure swing distillation for acetone-methanol separation. Ind Eng Chem Res 47:2696–2707. https://doi.org/10.1021/ie701695u
Luyben WL (2013) Comparison of extractive distillation and pressure-swing distillation for acetone/chloroform separation. Comput Chem Engin 50:1–7. https://doi.org/10.1016/j.compchemeng.2012.10.014
Luyben WL (2015) Improved design of an extractive distillation system with an intermediate-boiling solvent. Sep Purif Technol 156:336–347. https://doi.org/10.1016/j.seppur.2015.10.020
Luyben WL (2017) Control of a triple-column pressure-swing distillation process. Sep Purif Technol 174:232–244. https://doi.org/10.1016/j.seppur.2016.10.020
Mangili PV (2020) Thermoeconomic and environmental assessment of pressure-swing distillation schemes for the separation of di-n-propyl ether and n-propyl alcohol. Chem Eng Process 148:107816. https://doi.org/10.1016/j.cep.2020.107816
Phimister JR, Seider WD (2000) Semi-continuous, pressure swing distillation. Ind Eng Chem Res 39:122–130. https://doi.org/10.1021/ie9904302
Shi P, Zhang Q, Zeng A, Ma Y, Yuan X (2020) Eco-efficient vapor recompression-assisted pressure-swing distillation process for the separation of a maximum-boiling Azeotrope. Energy 196:117095. https://doi.org/10.1016/j.energy.2020.117095
Takagi S (1939) Boiling points of the system of formic acid and water. Bull Chem Soc Jpn 14:508–509. https://doi.org/10.1246/bcsj.14.508
Wang SJ, Huang K (2012) Design and control of acetic acid dehydration system via heterogeneous azeotropic distillation using p-xylene as an entrainer. Chem Eng Process 60:65–76. https://doi.org/10.1016/j.ces.2004.06.041
Wang N, Ye Q, Ren X, Chen L, Zhang H, Fan Y, Cen H, Zhong J (2020) Performance enhancement of heat pump with preheater-assisted pressure-swing distillation process. Ind Eng Chem Res 59:4742–4755. https://doi.org/10.1021/acs.iecr.9b06918
Wei H, Wang F (2013) Design and control of dimethyl carbonate−methanol separation via pressure-swing distillation. Ind Eng Chem Res 33:11463–11478. https://doi.org/10.1021/ie3034976
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Mahida, B., Benyounes, H. & Shen, W. Process analysis of pressure-swing distillation for the separation of formic acid–water mixture. Chem. Pap. 75, 599–609 (2021). https://doi.org/10.1007/s11696-020-01329-5
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DOI: https://doi.org/10.1007/s11696-020-01329-5