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Chemical Papers

, Volume 72, Issue 4, pp 897–902 | Cite as

Cu(II)Cr(III)-LDH: synthesis, characterization, intercalation properties and a catalytic application

  • Szilveszter Ziegenheim
  • Gábor Varga
  • Márton Szabados
  • Pál Sipos
  • István Pálinkó
Original Paper

Abstract

Optimum conditions were searched for the synthesis of Cu(II)Cr(III)-L(ayered)D(ouble)H(ydroxide), then the intercalation and catalytic properties were studied. For the optimization, the molar ratio of the metal ions, pH, temperature and ageing time were systematically varied. Applying this LDH as the host, the anionic form of l-proline was intercalated into the interlayer space with the direct anion-exchange method. For the structural characterization of the pristine and the intercalated products, powder X-ray diffractometry, IR spectroscopy, scanning and transmission electron microscopies as well as thermal methods were used. The catalytic properties were investigated in the oxidation of allylic alcohol. The reaction parameters such as the solvent, oxidant and the catalysts treatment were varied.

Keywords

Cu(II)Cr(III)-layered double hydroxide Synthesis Intercalation Structural characterization Catalytic properties 

Notes

Acknowledgements

This work was supported by the National Science Fund of Hungary through grant OTKA NKFI 106234. The financial help is highly appreciated.

References

  1. Aguirre JM, Gutiérrez A, Giraldo O (2011) Simple route for the synthesis of copper hydroxy salts. J Braz Chem Soc 22:546–551.  https://doi.org/10.1590/S0103-50532011000300019 CrossRefGoogle Scholar
  2. Al-Zahrani SM, Jibril BY, Abasaeed AE (2002) Selection of optimum chromium oxide-based catalysts for propane oxidehydrogenation. Catal Today 81:507–516.  https://doi.org/10.1016/S0920-5861(03)00149-4 CrossRefGoogle Scholar
  3. Carotenuto G, Tesser R, Di Serio M, Santacesaria E (2013) Kinetic study of ethanol dehydrogenation to ethyl acetate promoted by a copper/copper-chromite based catalyst. Catal Today 203:202–210.  https://doi.org/10.1016/j.cattod.2012.02.054 CrossRefGoogle Scholar
  4. Cavani F, Trifirò F, Vaccari A (1991) Hydratalcite-type anionic clays: preparation, properties and applications. Catal Today 11:173–301CrossRefGoogle Scholar
  5. Choudary BM, Madhi S, Chowdari NS, Kantam ML, Sreedhar B (2002) Layered double hydroxide supported nanopalladium catalyst for Heck-, Suzuki-, Sonogashira-, and Stille-type coupling reactions of chloroarenes. J Am Chem Soc 124:14127–14136.  https://doi.org/10.1021/ja026975w CrossRefGoogle Scholar
  6. Coiai S, Passaglia E, Hermann A, Augier S, Pratelli D, Streller RC (2009) The influence of the compatibilizer on the morphology and thermal properties of polypropylene-layered double hydroxide composites. Polym Compos 31:744–754.  https://doi.org/10.1002/pc.20857 Google Scholar
  7. Costantino U, Marmottini F, Nocchetti M, Vivan R (1998) New synthetic routes to hydrotalcite-like compounds. Eur J Inorg Chem 1998:1439–1446.  https://doi.org/10.1002/(SICI)1099-0682(199810)1998:10<1439:AID-EJIC1439>3.0.CO;2-1 CrossRefGoogle Scholar
  8. Crepaldi EL, Pavana PC, Valim JB (2000) Anion exchange in layered double hydroxides by surfactant salt formation. J Mater Chem 10:1337–1343.  https://doi.org/10.1039/A909436I CrossRefGoogle Scholar
  9. Grosso RP Jr, Suib SL, Weber RS, Schubert PF (1992) Main effects in the syntheses of Cu/Cr layered double hydroxides. Chem Mater 4:922–928.  https://doi.org/10.1021/cm00022a032 CrossRefGoogle Scholar
  10. He J, Wei M, Li B, Kang Y, Evans DG, Duan X (2006) Preparation of layered double hydroxides. Struct Bond 119:89–119.  https://doi.org/10.1007/430_006 CrossRefGoogle Scholar
  11. Isupov VP, Chupakhina LE, Mitrofanova RP (2000) Mechanochemical synthesis of double hydroxides. J Mater Synth Process 8:251–253.  https://doi.org/10.1023/A:1011376513081 CrossRefGoogle Scholar
  12. Markó IE, Tsukazaki M, Giles PR, Brown SM, Urch CJ (1997) Anaerobic copper-catalyzed oxidation of alcohols to aldehydes and ketones. Angew Chem Int Ed 36:2208–2210.  https://doi.org/10.1002/anie.199722081 CrossRefGoogle Scholar
  13. Marya YS, Ushakumarib L, Harikumarc B, Varghesed HT, Panicker CY (2009) FT-IR, FT-Raman and SERS spectra of l-proline. J Iran Chem Soc 6:138–144.  https://doi.org/10.1007/BF03246512 CrossRefGoogle Scholar
  14. Oh JM, Park DH, Choi SJ, Choy JH (2012) LDH nanocontainers as bio-reservoirs and drug delivery carriers. Recent Pat Nanotechnol 6:200–217.  https://doi.org/10.2174/187221012803531538 CrossRefGoogle Scholar
  15. Punniyamurthy T, Rout L (2008) Recent advances in copper-catalyzed oxidation of organic compounds. Coord Chem Rev 252:134–154.  https://doi.org/10.1016/j.ccr.2007.04.003 CrossRefGoogle Scholar
  16. Rives V (2001) Surface texture and electron microscopy studies of layered double hydroxides. In: Rives V (ed) Layered double hydroxides: present and future, 8th edn. Nova Science Publishers, Inc, New York, pp 257–282. ISBN 978-1-61209-289-8Google Scholar
  17. Sipiczki M, Kuzmann E, Pálinkó I, Homonnay Z, Sipos P, Kukovecz Á, Kónya Z (2014) Mössbauer and XRD study of intercalated CaFe-layered double hydroxides. Hyperfine Interact 226:171–179.  https://doi.org/10.1007/s10751-013-0925-3 CrossRefGoogle Scholar
  18. Tian L, Zhao Y, He S, Wei M, Duan X (2012) Immobilized Cu–Cr layered double hydroxide films with visible-light responsive photocatalysis for organic pollutants. Chem Eng J 184:261–268.  https://doi.org/10.1016/j.cej.2012.01.070 CrossRefGoogle Scholar
  19. Velu S, Shah N, Jyothi TM, Sivasanker S (1999) Effect of manganese substitution on the physicochemical properties and catalytic toluene oxidation activities of Mg–Al layered double hydroxides. Microporous Mesoporous Mater 33:61–75.  https://doi.org/10.1016/S1387-1811(99)00123-7 CrossRefGoogle Scholar
  20. Weckhuysen BM, Schoonheydt RA (1999) Olefin polymerization over supported chromium oxide catalysts. Catal Today 51:215–221.  https://doi.org/10.1016/S0920-5861(99)00046-2 CrossRefGoogle Scholar
  21. Williams GR, Clout A, Burlay JC (2013) A kinetic and mechanistic study into the formation of the Cu–Cr layered double hydroxide. Phys Chem Chem Phys 15:8616–8628CrossRefGoogle Scholar
  22. Zhao Y, Zhao Y, Waterhouse GIN, Zheng L, Cao X, Teng F, Wu L-Z, Tung C-H, O’Hare D, Zhang T (2017) Layered-double-hydroxide nanosheets as efficient visible-light-driven photocatalysts for dinitrogen fixation. Adv Mater.  https://doi.org/10.1002/adma.201703828 (In press) Google Scholar

Copyright information

© Institute of Chemistry, Slovak Academy of Sciences 2017

Authors and Affiliations

  1. 1.Department of Inorganic and Analytical ChemistryUniversity of SzegedSzegedHungary
  2. 2.Department of Organic Chemistry, Materials and Solution Structure Research Group, Institute of ChemistryUniversity of SzegedSzegedHungary
  3. 3.Department of Organic ChemistryUniversity of SzegedSzegedHungary

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