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Preparation, characterization and evaluation of a hybrid polymeric coating with sorbent properties

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Abstract

A hybrid polymeric coating (PDMS–CNPrTEOS) with sorbent properties was prepared by the sol–gel method from hydroxyl-terminated poly(dimethylsiloxane) (OH-PDMS), and cyanopropyltriethoxysilane (CNPrTEOS) as an inorganic precursor, using trifluoroacetic acid (TFA) as a catalyst. A coating with the sol–gel solution was prepared on glass plates using the dip-coating method and subsequently characterized. Characterization by FTIR shows that cyano groups are present on the surface coating and contact angle tests show that the coating presents hydrophilic characteristics. The organic–inorganic polymer was stable up to 400 °C with a weight loss of 8 wt % and showed good stability after immersion for 60 min in vortex and 45 min in ultrasonic bath, in various solvents: water, methanol (MeOH), acetone, isooctane, ethyl acetate (AcOEt) and acetonitrile (ACN), and solutions at different pH (1–12) for 48 h (h). The PDMS–CNPrTEOS hybrid polymer was evaluated and was found to have the ability to extract simultaneously furanic compounds in aqueous solution when it is employed as a sorbent for stir bar sorptive extraction (SBSE).

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Acknowledgements

This work was supported by the Consejo Nacional de Ciencia y Tecnología, CONACyT (CB-167800). The authors are grateful to M. en C. Alejandra Núñez Pineda for her technical support in TGA measurements.

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Authors and Affiliations

  1. Cuerpo Académico de Química Fundamental y Aplicada, Facultad de Ingeniería Química, Universidad Autónoma de Yucatán, Periférico Norte Km 33.5, Tablaje Catastral 13615, Col. Chuburná de Hidalgo Inn, C.P. 97203, Mérida, YUC, Mexico

    M. J. Burgos-Tan, Y. Pérez-Padilla, A. Avila-Ortega, J. A. Barrón-Zambrano, C. Carrera-Figueiras & D. Muñoz-Rodríguez

  2. Centro Conjunto de Investigación en Química Sustentable UAEM-UNAM, Carretera Toluca-Atlacomulco Km 14.5, Campus “El Rosedal”, C.P. 50200, San Cayetano-Toluca, MEX, Mexico

    A. R. Vilchis-Néstor

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  1. M. J. Burgos-Tan
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  2. Y. Pérez-Padilla
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  3. A. Avila-Ortega
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  6. C. Carrera-Figueiras
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Correspondence to Y. Pérez-Padilla.

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Burgos-Tan, M.J., Pérez-Padilla, Y., Avila-Ortega, A. et al. Preparation, characterization and evaluation of a hybrid polymeric coating with sorbent properties. Chem. Pap. 71, 1205–1215 (2017). https://doi.org/10.1007/s11696-016-0113-4

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  • DOI: https://doi.org/10.1007/s11696-016-0113-4

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