Abstract
Kevlar® fiber (KF) is a synthesized product with strong mechanical properties. We used KF as a reinforcement to improve the mechanical properties of wood-flour/polypropylene (WF/PP) composites. KF was pretreated with NaOH to improve its compatibility with the thermoplastic matrix. Maleated polypropylene (MAPP) was used as a coupling agent to improve the interfacial adhesion between KF, WF, and PP. Incorporation of KF improved the mechanical properties of WF/PP composites. Treatment of KF with NaOH resulted in further improvement in mechanical strength. Addition of 3% MAPP and 2% hydrolyzed KF (HKF) led to an increment of 93.8% in unnotched impact strength, 17.7% in notched impact strength, 86.8% in flexure strength, 50.8% in flexure modulus, and 94.1% in tensile strength compared to traditional WF/PP composites. Scanning electron microscopy of the cryo-fractured section of WF/PP showed that the HKF surface was rougher than the virgin KF, and the KF was randomly distributed in the composites, which might cause a mechanical interlocking between KF and polypropylene molecules in the composites.
Similar content being viewed by others
Explore related subjects
Discover the latest articles and news from researchers in related subjects, suggested using machine learning.References
Bengtsson M, Gatenholm P, Oksman K. 2005. The effect of crosslinking on the properties of polyethylene/wood flour composites. Composites Science and Technology, 65(10): 1468–1479.
Clemons C. 2002. Wood-plastic composites in the United States: The interfacing of two industries. Forest Products Journal, 52(6): 10–18.
Cui YH, Tao J. 2009. Fabrication and Mechanical Properties of Glass Fiber-Reinforced Wood Plastic Hybid Composites. Journal of Applied Polymer Science, 112: 1250–1257.
Day RJ, Hewson KD, Lovell PA. 2002. Surface modification and its effect on the interfacial properties of model aramid-fibre/epoxy composites. Composites Science and Technology, 62(2): 153–166.
Guo F, Zhang ZZ, Liu WM, Su FH, Zhang HJ. 2009. Effect of plasma treatment of Kevlar fabric on the tribological behavior of Kevlar fabric/phenolic composites. Tribology International, 42(2): 243–249.
Jiang H, Kamdem DP. 2004. Development of poly (vinyl chloride)/wood composites. Journal of Vinyl and Additive Technology, 10(2): 59–69.
Jiang H, Kamdem DP, Bezubic B, Ruede P. 2003. Mechanical properties of poly (vinyl chloride)/wood flour/glass fiber hybrid composites. Journal of Vinyl and Additive Technology, 9(3): 138–145.
John K, Naidu SV. 2004. Tensile properties of unsaturated polyester-based sisal fiber-glass fiber hybrid composites. Journal of Reinforced Plastics and Composites, 23(17): 1815–1819.
John K, Naidu SV. 2004. Effect of fiber content and fiber treatment on flexural properties of sisal fiber/glass fiber hybrid composites. Journal of Reinforced Plastics and Composites, 23(15): 1601–1605.
John K, Naidu SV. 2004. Sisal fiber/glass fiber hybrid composites: the impact and compressive properties. Journal of Reinforced Plastics and Composites, 23(12): 1253–1258.
Lai SM, Yeh FC, Wang Y, Chan HC, Shen HF. 2003. Comparative study of maleated polyolefins as compatibilizers for polyethylene/wood flour composites. Journal of Applied Polymer Science, 87(3): 487–496.
Liu H, Wu Q, Han G, Yao F, Kojima Y, Suzuki S. 2008. Compatibilizing and toughening bamboo flour-filled HDPE composites: Mechanical properties and morphologies. Composites Part A: Applied Science and Manufacturing, 39(12): 1891–1900.
Li J, Xia YC. 2010. Interfacial characteristics of an epoxy composite reinforced with phosphoric acid-functionalized Kevlar fibers. Mechanics of Composite Materials, 46(2): 211–214.
Markarian J. 2002. Additive developments aid growth in wood-plastic composites. Plastics Additives and Compounding, 4(11): 18–21.
Mukherjee M, Das CK, Kharitonov AP. 2006. Fluorinated and oxyfluorinated short Kevlar fiber-reinforced ethylene propylene polymer. Polymer Composites, 27(2): 205–212.
Mukherjee M, Kumar S, Bose S, Das CK, Kharitonov AP. 2008. Polymer-Plastics Technology and Engineering, 47(6): 623–629.
Ou RX, Zhao H, Sui SJ, Song YM, Wang QW. 2010. Reinforcing effects of Kevlar fiber on the mechanical properties of wood-flour/high-density-polyethylene composites. Composites Part A: Applied Science and Manufacturing, 41(9): 1272–1278.
Sombatsompop N, Yotinwattanakumtorn C, Thongpin C. 2005. Influence of type and concentration of maleic anhydride grafted polypropylene and impact modifiers on mechanical properties of PP/wood sawdust composites. Journal of Applied Polymer Science, 97(2): 475–484.
Takayanagi M, Kajiyama T, Katayose T. 1982. Surface-modified kevlar fiber-reinforced polyethylene and ionomer. Journal of Applied Polymer Science, 27(10): 3903–3917.
Thwe MM, Liao K. 2003. Environmental effects on bamboo-glass/polypropylene hybrid composites. Journal of Materials Science and Technology, 38(2): 363–376.
Thwe MM, Liao K. 2003. Durability of bamboo-glass fiber reinforced polymer matrix hybrid composites. Composites Science and Technology, 63(3–4): 375–387.
Vaughan DJ. 1978. The use of coupling agents to enhance the performance of aramid reinforced composites. Polymer Engineering and Science, 18(2): 167–169.
Wang QW, Kaliaguine S, Ait-Kadi A. 1993. Catalytic grafting—a new technique for polymer fiber composites. III. Polyethylene-plasma-treated Kevlar fibers composites. Journal of Applied Polymer Science, 48(1): 121–136.
Yue CY, Padmanabhan K. 1999. Interfacial studies on surface modified Kevlar fibre/epoxy matrix composites. Composites Part B: Engineering, 30(2): 205–217.
Author information
Authors and Affiliations
Corresponding author
Additional information
Foundation project: This research was supported by the National Natural Science Foundation of China (Project Nos. 31010103905 and 31070507), Program for New Century Excellent Talents in University of Ministry of Education of China (NCET-11-0608), and the Fundamental Research Funds for the Central Universities (DL12DB02).
Rights and permissions
About this article
Cite this article
Yuan, Fp., Ou, Rx., Xie, Yj. et al. Reinforcing effects of modified Kevlar® fiber on the mechanical properties of wood-flour/polypropylene composites. Journal of Forestry Research 24, 149–153 (2013). https://doi.org/10.1007/s11676-013-0335-z
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s11676-013-0335-z

