1 Introduction

The first interest in the Zr-Ti-Cu system is associated with the search for eutectoid-forming alloys with good mechanical characteristics.[1] This concerns the composition region Zr-Zr2Cu-Ti2Cu-Ti, where eutectoid transformation (βZr, βTi) ⇄ (αZr, αTi) + (Zr,Ti)2Cu (γ-phase) occurs. However, the main ongoing interest in this system since the 1980 s is caused by finding the bulk glass forming ability in multicomponent Zr-, Ti- and Cu-based alloys[2,3,4,5] and others, which possess a combination of attractive properties. Based on the boundary binary systems, the possibility of glass formation by rapid quenching in ternary Zr-Ti-Cu alloys in a wide composition range was suggested by (Ref 6) which was later confirmed by many authors[7,8,9,10,11,12,13,14] and others.

This resulted in numerous studies of phase equilibria in Zr-Ti-Cu system. Most of them concerned partial and complete experimentally determined isothermal sections at 700 to 800 °C.[1,6,15,16,17,18,19,20,21,22] CALPHAD assessments of the system were performed by (Ref 23, 24). Few works[21,25,26,27] considered ternary compounds.

Experimental data on phase equilibria with participation of the melt is scarce. Thus, as-cast samples were studied in (Ref 28) the liquidus and solidus projections in the subsystem Zr-Zr2Cu-Ti2Cu-Ti were plotted by (Ref 29). Meanwhile, as amorphous alloys are obtained by the melt spinning technique, knowledge of the processes taking place in the crystallization interval becomes important.

Thus, in this work we report our results from experimental study of the solidus and liquidus projections of the system. Solid-state transformations, which occur between the solidus temperatures and 750 °C[21] are discussed, as well. Since the subsystem Zr-Zr2Cu-Ti2Cu-Ti was considered by us in (Ref 29) we focus here on the subsystem Zr2Cu-Cu-Ti2Cu.

The data on phase equilibria in the system and on related questions published before 2004 were assessed in (Ref 30). However, most of the papers on the subject were published after 2004. So, brief evaluation of the data concerning phase relations in the system seems desirable.

2 Literature Evaluation

The boundary binary phase diagrams are shown in Fig. 1 according to[31] (Ti-Cu) and[32] (Zr-Ti, Zr-Cu).

Fig. 1
figure 1

Phase diagrams of the boundary binary systems: (a) Ti-Zr[32] (b) Ti-Cu[31] (c) Zr-Cu[32]

The first study of the system was performed by Ence and Margolin,[1,15] where partial isothermal section at 750 °C for Ti-corner was experimentally determined and predicted for Zr-corner. The existence of a continuous solid solution between Zr2Cu and Ti2Cu (here γ-phase) was suggested. Later this was experimentally established at 700 °C by (Ref 16) and repeatedly confirmed.[17,18,19,20, 22, 29, 33]

Chebotnikov and Molokanov[33] experimentally determined the vertical section Zr2Cu-Ti2Cu and claimed that it is not quasibinary. The same conclusion results from experimental data[6] and thermodynamic calculation,[23] which is based on data from (Ref 6). Whilst, according to thermodynamic calculation[24] and our data,[29] the section is quasibinary. The reason for this discrepancy is based on different versions of Ti-Cu phase diagram used by different authors, where Ti2Cu compound was shown to melt either congruently or incongruently. In (Ref 29) we have experimentally shown the congruent melting of Ti2Cu. The section Zr2Cu-Ti2Cu, thus, is quasibinary, and the system Zr-Ti-Cu can be divided into two subsystems. It was assumed that the section of[33] might not pass strictly through the composition of Ti2Cu, and, thus, was not quasibinary.

According to experimental results[18,29] and thermodynamic calculation,[24] the γ-phase has insignificant homogeneity range with respect to copper (below 2 at.%). In the subsystem Zr-Zr2Cu-Ti2Cu-Ti the solidus surface is characterized by coexistence of γ and (βZr, βTi) (β-phase) in the entire composition region. Subsequently, the liquidus surface is formed by the fields of primary crystallization of these phases, separated by the monovariant eutectic curve L ⇄ β + γ. The solidus temperature has a minimum and in this point the above three-phase equilibrium becomes invariant.

The β and γ phases coexist in wide composition ranges below the solidus, as well, as shown in the isothermal sections at 703,[22] 750[19,20] and 800 °C.[17,18] The same result was obtained in CALPHAD modeling.[23,24]

In contrast,[6] shows an alternative two-phase equilibrium β + ternary Laves phase (here τ1) at 703 °C. In turn, Zr2Cu and Ti2Cu should not form a continuous solid solution. This result was later shown to be incorrect.

The ternary Laves phase ZrTiCu4 with MgZn2 structure type was found by (Ref 25, 26). Later, its composition was corrected as ZrTiCu2 by (Ref 6) and confirmed in subsequent works.[27] Refined the crystal structure of the compound. According to[2,6] and thermodynamic assessments,[23,24] the phase melts congruently. The melting temperature at stoicheometric composition was experimentally established as 867 °C,[2] who plotted the isopleth ZrCu-TiCu. The temperature 883 °C was calculated by (Ref 23). According to[6] and subsequent works, τ1 phase has wide homogeneity range. The limits of the homogeneity range of the phase, as measured by different authors at different temperatures, are compared in Table 1. As one can see, these data agree well with each other. Some question arises concerning high Zr solubility in τ1 phase at 827 °C.[2]

Table 1 Limits of the homogeneity range of the ternary Laves phase

Available isothermal sections, both experimental and calculated, agree well on the main features. Thus, in the subsystem Zr2Cu-Cu-Ti2Cu the phases τ1 and Zr14Cu51 participate in two-phase equilibria with all other phases and, thus, define the character of phase equilibria. Subsequently, three-phase fields, established by different authors, are mostly similar. Some discrepancies are, however, present concerning the character of three-phase regions with participation of Zr-Cu compounds. For instance, τ1 + ZrCu equilibrium is reported for 703[6, 24] and 800 °C,[17, 18, 22, 24] however, it was not found at 750 °C.[19, 21] These discrepancies result from different solubilities of Ti in the above compounds established by different authors. Other inconsistencies in the results of different authors, even for the same temperatures, concern the location of the corners of some three-phase fields.

Note that the isothermal section at 703 °C of[6] significantly differs from the others. Most of these differences were eliminated in subsequent works, where the section at this temperature was experimentally determined[22] and calculated.[23, 24]

However, a major difference exists between the isothermal section at 750 °C[21] and the other works. In this work one more ternary compound τ2 was found. The composition of the compound was established as Zr22Ti14.5Cu63.5. The width of the homogeneity range of the phase does not exceed 1 at.%. The crystal structure was not resolved; however, it was established that it is hexagonal with cell size 12 × 9.8 Å. The formation mechanism of this phase was not established.

In (Ref 2) the isopleths ZrCu-TiCu was constructed. The section τ1-TiCu is shown as quasibinary of eutectic type, while in the ZrCu-τ1 part crystallization of ternary eutectic τ1 + γ + Zr14Cu51 is shown. However, this part represents a violation of the Gibbs’ phase rules. Note: that Zr14Cu51 compound is named ZrCu3.6.

3 Experimental

The starting materials for the preparation of alloys were electrolytic copper (99.99% (wt.)), iodide titanium (99.94% (wt.)) and zirconium (99.96% (wt.)). The alloys were melted in a vacuum arc furnace with a non-consumable tungsten electrode on a water-cooled copper hearth in an argon environment (pressure ~ 80 kPa). The atmosphere was additionally purified by molten titanium getter for at least 5 min. The ingots were turned over and remelted twice to homogenize the chemical composition of the samples. The mass of the ingots was about 10 g. The cooling rate of the ingots on the bottom of the furnace was ~ 100 °C/s. Mass losses during melting did not exceed 0.2% (wt.). Measurements of the composition of selected samples by local x-ray spectral analysis confirmed their agreement with the initial mixtures. The content of impurities (O, N, Ni, Zr, Si) according to chemical and spectral analyzes, measured on selected alloys, did not exceed 0.01% (wt.).

Temperatures of phase transformations were determined by differential thermal analysis (DTA) in the device with a tungsten-rhenium thermocouple W/WRe20.[34] Al, Ag, Au, Pd, Fe references were used to calibrate the thermocouple. The calibration error was ± 5 °C. Heating/cooling rates of ~ 20 or 40 °C/min were used. The experiments were carried out in He grade "A" atmosphere. Samples weighing up to 1.0 g were placed in Al2O3 or Sc2O3 crucibles. The investigation was conducted on cast and previously annealed (750 °C/536 h[20]) samples. The reproducibility of the data regarding the temperature of thermal effects was ± 3 °C.

For microstructural investigation the samples were polished using an aqueous suspension of Cr2O3. The microstructure of alloys and the composition of phases were determined by scanning electron microscopy (SEM) and local x-ray spectral analysis (LRSA) on Superprobe−733 and Superprobe−8200 devices. Pure copper, titanium and zirconium were used as standards.

Diffraction patterns were obtained on a DRON-3 device from metallographic sections using filtered Cu Kα radiation. The range of 2θ angles was 20-100°, the scanning step was 0.05-0.1°, and the exposure was 2 sec. The results were analyzed using the PowderCell software package. The lattice parameters were calculated by an iterative least squares method.

Several samples previously annealed at 750 °C/536 h[20] were additionally annealed near solidus temperatures in an SShVL-0.6.2/16 resistance furnace. Each sample was placed in an Al2O3 crucible. These samples were studied by microscopy and microprobe methods.

4 Results and Discussion

4.1 Liquidus Projection

The liquidus projection of the Zr-Ti-Cu system is shown in Fig. 2. The part with less than 33.3 at.% Cu is adopted from (Ref 29). The liquidus temperatures along the section Zr2Cu-Ti2Cu are taken from (Ref 24). The part with more than 33.3 at.% Cu results from this investigation.

Fig. 2
figure 2

Liquidus projection from this investigation: ○–composition of studied alloys, △–microprobe measurements of eutectic compositions.

In the subsystem Zr2Cu-Cu-Ti2Cu, the liquidus projection is characterized by the presence of primary crystallization fields of γ, (Cu), τ1 and all phases based on Zr-Cu and Ti-Cu compounds which form with the participation of the melt in the binary systems. On the contrary,[23, 24] show a narrow primary field of Ti2Cu3, even though this compound forms in the solid state in the binary system (Fig. 1b). This result has not been confirmed by us. The primary fields of γ, τ1 and Zr14Cu51 are the widest. For the τ1 phase, this is consistent with the results of (Ref 6, 23, 24). The wide field of primary crystallization of Zr14Cu51 was calculated by (Ref 23, 24) and the wide primary field of γ was shown by (Ref 24).

The liquidus isotherms were constructed based on the DTA results (Table 2), and were additionally refined via the constructed vertical sections, so that each alloy was involved in at least two sections. The boundaries of the primary regions were established based on the microstructure (Fig. 3) and EPMA results (Table 3) of cast alloys.

Table 2 Liquidus and solidus temperatures of Zr-Ti-Cu alloys
Fig. 3
figure 3

Microstructures of as-cast Zr-Ti-Cu alloys: (a)Cu42Ti18.1Zr39.9, 47cast (b) Zr30Ti30Cu40, 19cast (c) Zr18.1Ti38.3Cu43.6, 45cast (d) Zr41.9Ti13.3Cu44.8, 3cast (e) Zr40Ti7.7Cu52.3, 2cast (f) Zr36Ti11Cu53, 72cast (g) Zr14.2Ti33.1Cu52.7, 41cast × 400 (h) Zr14.2Ti33.1Cu52.7, 41cast × 1500 (i) Zr15Ti15Cu70, 27cast (j) Zr20Ti20Cu60, 85cast (k) Zr7Ti29.5Cu63.5, 71cast (l) Zr5Ti20Cu75, 30cast (m) Zr5Ti29Cu66, 82cast (n) Zr4Ti15Cu81, 84cast

Table 3 Crystallization pass in as-cast Zr-Ti-Cu alloys, phase composition on the solidus surface and EPMA results

Alloys # 4, 18, 20, 21, 47 (Fig. 3a), 77 and # 19 (Fig. 3b) are located in the fields of primary crystallization of γ and τ1 phase, respectively, and alloy # 45 (Fig. 3c) is entirely eutectic γ + τ1. So, microstructures of these alloys define the position of the monovariant eutectic curve L ⇄ γ + τ1 as it is shown in Fig. 2. The primary field of the γ-phase, thus, extends from Zr-Cu to Ti-Cu system. Inside this field the saddle point occurs at 875 °C at 38 at.% Ti. It corresponds to the minimum melting temperature of the γ-phase. From this point the liquidus temperature increases towards both Cu and Zr-Ti sides. On the monovariant curve L ⇄ γ + τ1 occurs a flat temperature maximum at about 850 °C from which the temperature decreases towards ternary eutectics L ⇄ γ + τ1 + ZrCu (E8, 828 °C) and L ⇄ γ + τ1 + TiCu (E5, 848 °C). According to,[24] the second equilibrium is of transition type L + γ ⇄ τ1 + TiCu. In addition,[24] calculated one minimum (at 860 °C) and two maxima (868 and 864 °C) for the equilibrium L ⇄ γ + τ1.

In contrast to alloy # 47 (Fig. 3a) with primary γ-phase ZrCu crystallizes first in alloy # 3 (Fig. 3d). So, the monovariant curve L ⇄ γ + ZrCu passes between the compositions of these alloys.

The monovariant eutectic curve L ⇄ ZrCu + Zr7Cu10 limits the primary region of ZrCu on the copper-rich side. It passes between the compositions of alloys # 2 and 72 (Fig. 3e, f), where ZrCu and Zr7Cu10 are the primary phases, respectively. It is important that in both samples, after the crystallization of the primary phases, the γ-phase crystallizes. In both samples, this is a nonequilibrium phase. Its appearance might be associated with similar thermodynamic stability of Zr-Cu intermetallics similar enthalpies of formation of solid phases and enthalpies of mixing of the melt.[32] Among these phases ZrCu is less stable than Zr2Cu (γ) and Zr7Cu10. Equilibrium crystallization of alloy # 72 would end in ternary eutectic L ⇄ ZrCu + Zr7Cu10 + τ1 at 826 °C.

Primary Zr3Cu8 phase in alloy # 80 limits the primary region of Zr7Cu10 on the copper rich side. The monovariant curves L ⇄ ZrCu + τ1 and L ⇄ Zr7Cu10 + τ1 is shown tentatively in Fig. 2.

The small amount of primary TiCu phase in alloy # 41 (Fig. 3g) allowed us to plot the monovariant curve L ⇄ TiCu + τ1 as shown in Fig. 2. The location of the curve is supported by microprobe measurements of eutectic composition in alloy # 22 (Table 3). Consideration of intergranular space at magnification × 1500 (Fig. 3h) shows the presence of small amount of ternary eutectic TiCu + τ1 + Zr14Cu51, which indicates the composition of the eutectic melt following the monovariant curve L ⇄ TiCu + τ1 towards the ternary eutectic. The phases in it are well distinguished by the color intensity: TiCu-black, τ1-grey, Zr14Cu51-white. The composition of the ternary eutectic liquid agrees well with the relative amounts of the phases in eutectic structure. It was determined from EPMA data of alloy # 27 (Fig. 3i, Table 3). The appropriate point is plotted in Fig. 2. The temperature was established as 825 °C as an everage temperature of all alloys from the TiCu + τ1 + Zr14Cu51 three-phase region (Table 2).

Eutectic structure (Zr14Cu51 + τ1) of alloys # 79, 85 (Fig. 3j) allowed to separate the fields of primary crystallization of Zr14Cu51 and τ1 and, thus, to plot the monovariant eutectic curve L ⇄ Zr14Cu51 + τ1.

As a result of the above discussion, the region of primary crystallization of the τ1 phase was plotted. It is wide and located in the center of the system. The region is limited by the monovariant eutectic curves L ⇄ γ + τ1, L ⇄ ZrCu + τ1, L ⇄ Zr7Cu10 + τ1, L ⇄ Zr14Cu51 + τ1 and L ⇄ TiCu + τ1, each of which ends in a ternary eutectic. Consequently, each of these equilibria has a temperature maximum.

The field of the primary crystallization of Zr14Cu51 is also wide. It is limited by the following monovariant curves: L + Zr14Cu51 ⇄ Zr3Cu8, L ⇄ Zr7Cu10 + Zr14Cu51, L ⇄ Zr14Cu51 + τ1, L ⇄ Zr14Cu51 + TiCu, L ⇄ Zr14Cu51 + TiCu, L ⇄ Zr14Cu51 + Ti3Cu4, L ⇄ Zr14Cu51 + TiCu2, L ⇄ Zr14Cu51 + TiCu4, L ⇄ Zr14Cu51 + (Cu) and L + Zr14Cu51 ⇄ ZrCu5. Location of the curve L ⇄ Zr14Cu51 + τ1 was discussed above. Other equilibria are considered below.

Alloys # 43 and 71 (Fig. 3k) are close in composition and have entirely eutectic microstructures. Measurements of eutectic compositions (Table 3) showed their correspondence to the compositions of the alloys. In both alloys, three phases in eutectic are visible. According to XRD pattern of sample # 43 (Fig. 4a), these phases are Zr14Cu51, TiCu and Ti3Cu4. However, the grains of Ti3Cu4 were too small to measure its composition with EPMA. Considering that the solidus temperature in sample # 43 is somewhat higher than in sample # 71 (877 and 870 °C, respectively, Table 2), the eutectic in alloy # 71 was assigned to the ternary eutectic L ⇄ Zr14Cu51 + TiCu + Ti3Cu4, and the eutectic in sample # 43 is L ⇄ Zr14Cu51 + TiCu. The presence of small amount of the Ti3Cu4 phase in the eutectic of alloy # 43 can be explained by the change in the composition of the melt towards the ternary eutectic during crystallization.

Fig. 4
figure 4

XRD patterns of as-cast Zr-Ti-Cu alloys: (a) Zr8.2Ti30.4Cu61.4, 43cast (b) Zr4.1Ti21.7Cu74.2, 42cast (c) Zr12.5Ti12.5Cu75, 29cast

Crystallization in alloys # 30, (Fig. 3l) and 42 seems to be essentially non-equilibrium. This conclusion is based on the observation of three phases in the microstructure that appear to be primary. This might be related to the cooling rate in the arc furnace. Thus, at the initial stage of cooling, when the cooling rate is high, the melt can be enriched in other components, up to overenrichment compared to the equilibrium melt. In addition, at this stage, the release of heat may be greater than during equilibrium crystallization, which may lead to some increase in temperature and a change in the composition of the melt. As the furnace cools, the cooling rate decreases and the sample approaches equilibrium. This leads to processes that are impossible in equilibrium crystallization.

So, possible explanation of the microstructure (Fig. 3l) can be as follows. Alloys # 30 and 42 have a small amount of the primary Zr14Cu51-based phase (white grains). During its crystallization, the melt becomes depleted in zirconium and its composition falls into the region of primary crystallization of TiCu4, which crystallizes as large grey grains. Since the composition of both alloys under concideration is close to the monovariant eutectic L ⇄ Zr14Cu51 + TiCu4, this first non-equilibrium step is quite justified. During the crystallization of TiCu4, the melt becomes depleted in copper and its composition enters the region of primary crystallization of TiCu2 (dark-grey grains). Based on the microstructure (Fig. 3l), the process ends with the crystallization of the eutectic L ⇄ Zr14Cu51 + TiCu2 + TiCu4. These three phases are identified in the XRD patterns (Fig. 4b). Alloys # 82 and 84 (Fig. 3m, n) are entirely eutectic Zr14Cu51 + Ti3Cu4 + TiCu2 and Zr14Cu51 + TiCu4 + (Cu), respectively. The XRD pattern of alloy # 29 (Fig. 4c) confirms the phases in the first eutectic. The phases in alloy # 29 are well determined by microprobe measurements (Table 3).

The primary region of Zr3Cu8 was constructed based on this phase being primary in alloys # 66 and 80. The primary field of ZrCu5 is given tentatively. The region of the TiCu2 phase is plotted due to the location of the eutectic E4 and primary TiCu2 in sample # 83.

Thus, most invariant points of the melt in four-phase equilibria are of eutectic type. The temperatures of these equilibria with participation of τ1 phase are very close and vary within 20 °C. The compositions of ternary eutectics that were not experimentally established are derived from the intersection of the monovariant curves.

The presence of ternary eutectics necessitates the presence of maxima in temperatures of three-phase equilibria with the liquid.

As it is clear from the above discussion, the crystallization paths in many samples is rather complex. It is shown in Table 3 for each sample based on the microstructures.

4.2 Solid Phases

One of the more important features of the Zr-Ti-Cu system is the presence of the ternary Laves phase τ1 in the center of the system with a wide homogeneity range in the temperature range from 627 to 827 °C (Table 1). At solidus temperatures it is more elongated in the direction Zr/Ti-Cu and extends from ~ 39 to 54 at.% Cu, in comparison with 42.5 to 52 at.% Cu in the range of 627 to 827 °C. Completely single-phase microstructure of as-cast sample # 19 is shown in Fig. 3(b), confirming the Cu-poor boundary of the homogeneity range. The boundaries of the homogeneity range were determined by microprobe measurements (Table 3). According to our data, the solidus temperature of the phase is about 850 °C, while the congruent point was not established. These values are in satisfactory agreement with the data of (Ref 2) and (Ref 23) who reported the melting temperature as 867 and 883 °C, respectively.

The τ2 ternary compound (Zr22Ti14.5Cu63.5), reported in (Ref 21) was not observed by us in as-cast samples. The phase, thus, forms in the solid state.

Phases based on ZrCu, Zr7Cu10 and Zr14Cu51 also have extended homogeneity ranges. However, unlike τ1, their homogeity ranges extent along the copper isoconcentrates, which indicates the mutual substitution of Zr and Ti atoms. Ti solubility in these phases is 11, 9 and 12 at.%, respectively. Solubility of Ti in Zr3Cu8 is about 1 at.%. Solubility of Ti in ZrCu5 was not established. Solubility of Zr in Ti-Cu intermetallics is less than 2 at.%.

As discussed above, in samples # 2 and 72 the nonequilibrium γ-phase was observed. Nevertheless, its compositions measured by microprobe method (Table 3) were used to plot the copper-rich boundary of the homogeneity range of the phase on the solidus projection.

The crystal structures of the Zr-Ti-Cu phases are listed in Table 4.

Table 4 Crystallographic characteristics of intermediate phases of Zr-Ti-Cu system

4.3 Solidus Projection

The solidus projection of the Zr-Ti-Cu system obtained by the present investigation is shown in Fig. 5. It was plotted mainly based on the results for as-cast samples. The vertices of the three-phase regions were constructed based on the microprobe results (Table 3). In several cases, these results do not not to individual phases, but to their mixtures in various proportions as in the case of a thin grain of the measured phase, where the underlying grain or matrix is also captured by the electron probe. A similar situation exists for the coarse eutectics, where the measured composition could not be referred to the composition of the eutectic melt, but to the gross composition of two eutectic phases. For two-phase compositions, these values lie on the tie-lines and were used to construct the solidus projection. These values are also shown in Table 3. The solidus temperatures measured in as-cast samples (Table 2) are shown in Fig. 5.

Fig. 5
figure 5

Solidus projection from this investigation: ○–single-phase sample, ◐–two-phase sample, ●–three-phase sample, △–microprobe measurements.

According to our results, the solidus projection of Zr-Ti-Cu system is characterized by presence of the following three-phase regions: γ + τ1 + ZrCu, τ1 + ZrCu + Zr7Cu10, τ1 + Zr7Cu10 + -r14Cu51, Zr7Cu10 + Zr14Cu51 + Zr3Cu8, γ + τ1 + TiCu, τ1 + TiCu + Zr14Cu51, TiCu + Zr14Cu51 + Ti3Cu4, Zr14Cu51 + Ti3Cu4 + TiCu2, Zr14Cu51 + TiCu2 + TiCu4, Zr14Cu51 + TiCu4 + (Cu) and Zr14Cu51 + (Cu) + ZrCu5. Among them, the triangle Zr14Cu51 + (Cu) + ZrCu5 is shown tentatively.

The composition of the ZrCu and Zr7Cu10 phases of the region τ1 + ZrCu + Zr7Cu10 were well established by the microprobe measurements (Table 3). The composition of the τ1 phase could not be determined, as this phase was absent in as-cast samples because of extreme nonequilibrium crystallization. Instead, the location of this corner was determined by microprobe measurements of sample # 2, annealed at a subsolidus temperature of 820 °C, which at this temperature falls into three-phase region of interest. The microstructure of sample # 2 annealed at 820 °C is shown in Fig. 6(a), where three above phases are observed.

Fig. 6
figure 6

Microstructures of key alloys annealed at subsolidus temperatures: (a) Zr40Ti7.7Cu52.3, 2cast, ann. 750 °C/736 h + 820 °C/10 h (b) Zr20Ti25Cu55, 23cast, ann. 750 °C/736 h + 820 °C/10 h (c) Zr16Ti16Cu68, 74cast, ann. 750 °C/736 h + 800 °C/10 h

The character of the solidus projection plotted by us is for most features consistent with the results of thermodynamic modelling.[24] However, the region with the participation of Ti-Cu intermetallics is different. According to,[24] the Ti2Cu3 compound, which forms in the solid state in the binary system, appears on the solidus projection in the ternary. In our investigation Ti2Cu3 was not observed in as-cast samples, and, thus, does not participate in equilibria on the solidus projection. The microstructure of the sample # 30 (Fig. 3l) from the region Zr14Cu51 + TiCu4 + TiCu2 was discussed above. The XRD pattern of sample # 42 from this phase region (Fig. 4b) confirms the presence of these three phases. As a result, in contrast to Ti3Cu4 + Ti2Cu3 + Zr14Cu51 and Ti2Cu3 + TiCu4 + Zr14Cu51 regions,[24] our investigation showed the regions Zr14Cu51 + Ti3Cu4 + TiCu2 and Zr14Cu51 + TiCu2 + TiCu4 to exist on the solidus projection. Alloys # 30 are 42 are in the first region, sample # 29 is located in the second one (Fig. 4c).

Most invariant equilibria, according to the liquidus projection (Fig. 2), are of the eutectic type, which results in temperature maxima on monovariant curves, and these temperature maxima should also be present in two-phase fields of the solidus projection (Fig. 5). According to our results, most of these fields are narrow and none of the alloys are located within these. For alloys which are in two-phase regions, tie-lines are plotted according to microprobe measurements and the solidus temperatures are shown. The exact locations of the maximum tempertures for the tie-lines was established only for the regions γ + τ1 and τ1 + Zr14Cu51. As can be seen from Fig. 5, the temperature maximum for the γ + τ1 solidus is very flat.

4.4 Invariant Equilibria with Participation of the Melt

The superposition of the liquidus and solidus projections is shown in Fig. 7. It allows a better understanding of the processes occurring in the system during crystallization. The location of the invariant points of the liquid inside or outside the three-phase regions of the solidus projection indicates the eutectic or transition-type nature of the four-phase equilibria, respectively. Among these three equilibria are of the transition type, all others are eutectics. Invariant equilibria are listed in Table 5 in comparison with data from the literature.

Fig. 7
figure 7

Superposition of liquidus and solidus projections of the Zr-Ti-Cu system

Table 5 Invariant equilibria with participation of the melt

As mentioned above, the temperature maxima of the monovariant curves in the liquidus projection are connected to the maxima in two-phase fields of the solidus projections. Compositions of the melts in these points are located on the maximum tie-lines of the solidus surface. At these maximum tempertures the three-phase equilibria are invariant. The coordinates of three-phase invariant equilibria are also shown in Table 5.

The sequence of the processes taking place during solidification are summarized in the Scheil reaction scheme (Fig. 8).

Fig. 8
figure 8

Scheil reaction scheme of the Zr-Ti-Cu system

4.5 Solid State Equilibria

Comparison of the constructed solidus projection (Fig. 5) and isothermal section at 750 °C[21] shows that the character of phase equilibria in the central part of the system is different. The principal differences are as follows:

  1. 1.

    The ternary compound τ2, which exists at 750 °C, is not present in the solidus projection. So, it forms in the solid state.

  2. 2.

    Instead of three-phase fields Zr14Cu51 + TiCu4 + TiCu2 and Zr14Cu51 + TiCu2 + Ti3Cu4 in the solidus projection, at 750 °C there are regions Zr14Cu51 + TiCu4 + Ti2Cu3 and Zr14Cu51 + Ti2Cu3 + Ti3Cu4. So, in this temperature range, a number of solid-state transformations occur involving the decomposition of TiCu2 and the formation of Ti2Cu3, like the Ti-Cu system.

  3. 3.

    The position of the corners of three-phase regions is essentially different, resulting from changes in the homogeneity ranges of the phases, which decrease with decreasing temperature.

To address these issues, several samples previously annealed at 750 °C[21] were annealed at sub-solidus temperatures and studied by microprobe method. Microstructures of key samples and microprobe results are shown in Fig. 6 and Table 6, respectively. These data are summarized in Fig. 9. Note that the temperatures inside the three-phase regions and on the tie-lines in Fig. 9 correspond to the annealing temperatures; therefore, the figure can be considered as superimposed fragments of isothermal sections at different temperatures.

Table 6 Microprobe data for the samples annealed close to solidus temperatures after annealing at 750 °C/736 h
Fig. 9
figure 9

Microprobe data and phase composition of the samples annealed at sub-solidus temperatures. The temperatures shown correspond to the annealing temperatures: ◐–two-phase sample, ●–three-phase sample, △–microprobe measurements (inset: details of the equilibria with τ2)

Changes in the phase composition of samples with temperature can be seen in isopleths at 40 and 70 at.% Cu (Fig. 10).

Fig. 10
figure 10

Isopleth of Zr-Ti-Cu system at 40 (a) and 70 (b) at.% Cu: ○–temperature of invariant equilibria in binary systems, ◐–two-phase sample, △–DTA data for as-cast samples, ▲–DTA data for annealed samples, □–boundaries of the phase fields at 750 °C[21], ∎–boundaries of the phase fields according to this investigation, •–temperatures taken from the isotherms

The isopleth at 40 at.% Cu (Fig. 10a) illustrates a limited temperature range for existence of the τ1 phase. Indeed, as-cast sample Zr30Ti30Cu40 (# 19) is single-phase (Fig. 3b), but it contains two phases (τ1 + γ) at 800 °C and below.

In this isopleth, the phase field boundaries obtained by us for as-cast and subsolidus annealed samples are compared with the experimental results of.[17,18,19, 21] As one can see, the data[17, 18, 21] for 800 and 750 °C along the section 40 at.% Cu agree well with our results for the solidus. Along other sections, a good agreement is only observed with the[21] data for 750 °C, which are preferred.

The isopleth at 70 at.% Cu (Fig. 10b), in addition to crystallization processes, illustrates the formation of the τ2 phase and transformations involving Ti-Cu compounds. The boundaries of the phase fields established by us at different temperatures (Fig. 9), and the boundaries at 750 °C[21] are shown in the isopleth.

4.5.1 Transformations Involving Ti-Cu Compounds

The solidus projection contains the fields Zr14Cu51 + TiCu4 + TiCu2 and Zr14Cu51 + TiCu2 + Ti3Cu4 with solidus temperatures of 864 and 850 °C, respectively. At 840 °C (Fig. 9a) none of these fields exist. Instead, the field Zr14Cu51 + TiCu4 + Ti2Cu3 exists at 750 °C.[21] It is natural to assume that TiCu2 decomposes with the formation of Ti2Cu3 by eutectoid reaction, similarly to the Ti-Cu binary system. The reaction, thus, is TiCu2 ⇄ Zr14Cu51 + TiCu4 + Ti2Cu3, and occurs above 840 °C.

Three solid three-phase from higher temperatures form this invariant quilibrium. The equilibria TiCu2 + TiCu4 + Ti2Cu3 and Zr14Cu51 + TiCu2 + TiCu4 originate from the binary Ti-Cu system and the solidus, respectively. Another four-phase transformation should occur to form the Zr14Cu51 + TiCu2 + Ti2Cu3 equilibrium. Taking into account the existence of the equilibrium Zr14Cu51 + TiCu2 + Ti3Cu4 on the solidus projection and the Zr14Cu51 + Ti2Cu3 + Ti3Cu4 equilibrium at 750 °C, the region Zr14Cu51 + TiCu2 + Ti2Cu3 forms by transition-type equilibrium TiCu2 + Ti3Cu4 ⇄ Zr14Cu51 + Ti2Cu3. This should occur between 850 °C (solidus temperature of the Zr14Cu51 + TiCu2 + Ti3Cu4 region) and 840 °C, and higher than the eutectoid one. Thus, between 850 and 840 °C two invariant four-phase equilibria occur, as shown in Fig. 10b.

4.5.2 Formation of the Ternary Compound τ2

The τ2 ternary compound was first observed in (Ref 21) at 750 °C. In our investigation it was observed in samples # 23 and 41, annealed at 820 °C (Fig. 6b, 9a). The compound, thus, forms above 820 °C. At both temperatures it is in two-phase equilibrium with TiCu. In sample #67 annealed at this temperature the τ2 compound was not observed (Fig. 9a). After annealing at 800 °C sample # 75 (Table 6, Fig. 9b) contains four phases, Zr14Cu51 + Zr7Cu10 + τ1 + τ2. Although this sample is not in equilibrium it allows to assume that between 800 and 820 °C invariant four-phase equilibrium occurs. The compositions of the phases point to the transition type equilibrium Zr14Cu51 + τ1 ⇄ Zr7Cu10 + τ2. Similarly, in samples # 69 and 74 annealed at 800 °C (Fig. 6c, 9b) phases Zr14Cu51 + TiCu + τ1 + τ2 are present indicating invariant transformation Zr14Cu51 + τ1 ⇄ TiCu + τ2. One of the three-phase equilibria, Zr14Cu51 + τ1 + τ2, is part of both invariant reactions. Thus, the τ2 phase forms by invariant three-phase transformation Zr14Cu51 + τ1 ⇄ τ2, as shown in Fig. 10(b). The microstructure of sample #74 (Fig. 6c) shows typical peritectic formation of the τ2 ternary compound. The temperature of its formation was measured in sample Zr22Ti14,5Cu63,5 (# 68) as 827 °C.

The solid state transformations are listed in Table 7 and presented in the reaction scheme (Fig. 8).

Table 7 Solid state invariant equilibria

5 Conclusions

As a result of a complex experimental study of phase equilibria in the Zr-Ti-Cu system, liquidus and solidus projections, the Scheil reaction scheme, and isopleths for a number of isoconcentrates were constructed for the first time. The phase equilibria are defined by the phases Zr14Cu51 and τ1, being in equilibria with all other phases on the solidus projection and having the widest fields of primary crystallization on the liquidus projection.

The τ1 phase has wide homogeneity range, which extends from 39 to 54 at.% Cu and from 21 to 31 at.% Ti. Compounds Zr14Cu51 and ZrCu dissolve up to 12 at.% Ti, Zr7Cu10 dissolves 9 at.% Ti. The homogeneity ranges of these phases are located along the copper isoconcentrates. The solubility of the third component in other binary compounds does not exceed 2 at.%.

The solidus projection is characterized by presence of the following three-phase regions: γ + τ1 + ZrCu, τ1 + ZrCu + Zr7Cu10, τ1 + Zr7Cu10 + Zr14Cu51, Zr7Cu10 + Zr14Cu51 + Zr3Cu8, γ + τ1 + TiCu, τ1 + TiCu + Zr14Cu51, TiCu + Zr14Cu51 + Ti3Cu4, Zr14Cu51 + Ti3Cu4 + TiCu2, Zr14Cu51 + TiCu2 + TiCu4, Zr14Cu51 + TiCu4 + (Cu) and Zr14Cu51 + (Cu) + ZrCu5. The regions Zr7Cu10 + Zr14Cu51 + Zr3Cu8 and Zr14Cu51 + (Cu) + ZrCu5 form by transition-type reactions, the rest by eutectic reactions. The temperatures of eutectic reactions are within 825-880 °C. Ten invariant three-phase eutectic equilibria occur in the system.

In contrast to the literature data, it is shown that TiCu2 participates in equilibria with the melt and decomposes by eutectoid reaction TiCu2 ⇄ Zr14Cu51 + TiCu4 + Ti2Cu3. This equilibrium and TiCu2 + Ti3Cu4 ⇄ Zr14Cu51 + Ti2Cu3 occur between 840 and 850 °C.

It is shown for the first time that the ternary compound τ2 forms by invariant three-phase reaction Zr14Cu51 + τ1 ⇄ τ2 at 827 °C.