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Chemical Diffusion in Ni-V Solid Solution and in Ni3V

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Abstract

Diffusion in Ni-V solid-solution of A1 structure and Ni3V of D022 structure has been studied by interdiffusion experiments using single-phase (A1/A1 and D022/D022) and two-phase (A1/D022) diffusion couples. Concentration profiles in diffusion-annealed couples were measured by electron-probe microanalysis, and the chemical diffusion coefficient has been evaluated by Boltzmann-Matano analysis. The diffusion coefficient in the A1 phase agrees well with the data in the literature over the ranges of temperature from 900 to 1300 °C and composition from 0 to 25 mol.% V. The diffusion coefficient at 25 mol.% V in the ordered D022 phase, which exists below 1045 °C, is found to be smaller than the extrapolation from the A1 phase toward this temperature range. The much faster diffusion in the D022 phase reported by Khlomov et al. (Phys Met Metall 46(1): 173-175, 1978; Phys Met Metall 46(3):188-191, 1978) could have been caused by transient microstructural evolution - formation of new phases and grains - in their reaction diffusion experiments.

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Acknowledgments

We thank Professor KANENO Yasuyuki (Osaka Metropolitan University) for his continued encouragement and providing facilities for alloy preparation.

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Authors and Affiliations

  1. Osaka Metropolitan University Ringgold Standard Institution - Materials Science, Gakuencho 1-1, Naka-Ku, Sakai, Osaka, 599-8531, Japan

    Daisuke Inoue

  2. The University of Shiga Prefecture Ringgold Standard Institution - Materials Science, Hikone, Shiga, 522-8533, Japan

    Ryusuke Nakamura

  3. Osaka Metropolitan University Ringgold Standard Institution - Materials Science, Gakuencho 1-1, Naka-Ku, Sakai, Osaka, 599-8531, Japan

    Hiroshi Numakura

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  1. Daisuke Inoue
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Inoue, D., Nakamura, R. & Numakura, H. Chemical Diffusion in Ni-V Solid Solution and in Ni3V. J. Phase Equilib. Diffus. 44, 240–254 (2023). https://doi.org/10.1007/s11669-023-01038-y

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