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Journal of Phase Equilibria and Diffusion

, Volume 39, Issue 2, pp 166–175 | Cite as

450 °C and 600 °C Isothermal Sections of the Zn-Cr-Si Ternary Phase Diagram

  • Yangtian Yan
  • Xuping Su
  • Ya Liu
  • Yuwen Ding
Article
  • 97 Downloads

Abstract

The 450 and 600 °C isothermal sections of the Zn-Cr-Si system were experimentally constructed using scanning electron microscopy equipped with energy dispersive x-ray spectrometry, and x-ray diffraction. Six three-phase regions in the 450 °C section and five three-phase regions in the 600 °C section were identified experimentally. No ternary compound was found. Si has low solubility in CrZn17. The Zn solubility in CrSi2, Cr5Si3, and Cr3Si are all less than 2.2 at.%. The CrSi phase cannot be in equilibrium with the η-Zn phase. Thermodynamic extrapolation of the Zn-Cr-Si system was carried out and showed good agreement with experimentally determined phase relationships.

Keywords

Zn-Cr-Si system isothermal section phase equilibria thermodynamics 

Notes

Acknowledgments

Financial support from the National Science Foundation of China (Grant Nos. 51471037 and 51671036) and a project funded by the Priority Academic Program Development of Jiangsu higher education institutions are greatly acknowledged.

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Copyright information

© ASM International 2018

Authors and Affiliations

  1. 1.Jiangsu Key Laboratory of Materials Surface Science and TechnologyChangzhou UniversityChangzhouPeople’s Republic of China
  2. 2.Jiangsu Collaborative Innovation Center of Photovoltaic Science and EngineeringChangzhou UniversityChangzhouPeople’s Republic of China

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