Journal of Phase Equilibria and Diffusion

, Volume 25, Issue 1, pp 59–67 | Cite as

Experimental study of the Bi2O3-Fe2O3 pseudo-binary system

  • A. Maître
  • M. François
  • J. C. Gachon
Basic And Applied Research


As part of a general contribution to the study of accelerator driven system (ADS) nuclear reactor feasibility, a study of the five-component system Bi-Fe-Hg-O-Pb was undertaken. New results about the quasi-binary Bi2O3-Fe2O3 are presented in this paper. The phase diagram was reinvestigated by differential scanning calorimetry, x-ray diffraction, and electron probe microanalysis. A new compound was discovered and characterized: Bi25FeO40. Its crystallographic structure was refined. Invariant and transition temperatures are given, as well as phase compositions.


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© ASM International 2004

Authors and Affiliations

  • A. Maître
    • 1
  • M. François
    • 1
  • J. C. Gachon
    • 1
  1. 1.Laboratoire de Chimie du Solide Minéral UMR CNRS 7555Université Henri Poincaré, Faculty of Science and TechnologyVandoeuvre-les-Nancy, CedexFrance

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