References
T. Curtius and J. Rissom, On HN3, J. Prakt. Chem., Vol 58 (No. 7–8), 1898, p 261–309 (in Russian). (Equi Diagram; Experimental)
H. Moissan, Preparation and Properties of RbH and CsH, Compt. Rend. Hebd. Seances Acad. Sci., Vol 136, 1903, p 587–591 (in French). (Equi Diagram; Experimental)
E. Tiede, The Decomposition of Alkali and Alkaline Earth Metal Azides in High Vacuum, Ber. Deut. Chem. Gesell., Vol 49, 1916, p 1742–1745 (in German). (Equi Diagram; Experimental)
R. Suhrmann and K. Clusius, The Preparation of Pure Alkali Metals, Z. Anorg. Allg. Chem., Vol 152 (No. 1), 1926, p 52–58 (in German). (Equi Diagram; Experimental)
W. Moldenhauer and H. Möttig, The Combination of Alkali Metals and Nitrogen Under the Influence of Electrical Discharge, Ber. Deut. Chem. Gesell., Vol 62, 1929, p 1954–1959 (in German). (Equi Diagram; Experimental)
K. Clusius, On Rb3N and Cs3N, Ber. Deut. Chem. Gesell., Vol 194, 1930, p 47–50 (in German). (Equi Diagram; Experimental)
L.K. Frevel, The Configuration of the Azide Ion, J. Am. Chem. Soc., Vol 58 (No. 5), 1936, p 774–782. (Crys Structure; Experimental)
F. Ephraim, Inorganic Chemistry, 6th ed., P.C.L. Thorne and E.R. Roberts, Ed., Interscience, 1954. (Equi Diagram; Review)
P. Gray and T.C. Waddington, Thermochemistry and Reactivity of the Azides. I. Thermochemistry of the Inorganic Azides, Proc. R. Soc. A, Vol 235, 1956, p 106–119. (Thermo; Experimental)
P. Gray and T.C. Waddington, Thermochemistry and Reactivity of the Azides. II. Lattice Energies of Ionic Azides, Electron Affinity and Heat of Formation of the Azide Radical, and Related Properties, Proc. R. Soc. A, Vol 235, 1956, p 481–495. (Thermo; Theory)
B.L. Evans and A.D. Yoffe, Structure and Stability of Inorganic Azides, Proc. R. Soc. A, Vol 238, 1957, p 568–574. (Crys Structure; Experimental)
B.L. Evans, A.D. Yoffe, and P. Gray, Physics and Chemistry of the Inorganic Azides, Chem. Rev., Vol 59 (No. 4), 1959, p 515–567. (Crys Structure, Thermo; Review)
A.W. Scholl and L.A. Walker, The X-Ray Powder Pattern of CsN3, Proc. West Va. Acad. Sci., Vol 34, 1962, p 89–91. (Crys Structure; Experimental)
P. Gray. Chemistry of the Inorganic Azides, Quart. Rev., Vol 17 (No. 4), 1963, p 441–473. (Crys Structure; Review)
F. Tepper, A. Murchison, and J. Zelenek, Thermophysical Properties of Rb and Cs, Proc. USAF Aerospace Fluids Lubricants Conf., San Antonio, 1963, U.S. Air Force, p 368–387. (Equi Diagram; Experimental)
F. Tepper, A. Murchison, J. Zelenek, and F. Roehlich, Thermophysical Properties of Rb and Cs, in Proc. High-Temp. Liquid Metal Heat Transfer Technol. Meeting, Vol 1, ORNL-3605, Oak Ridge National Laboratory, 1964, p 26–65. (Equi Diagram; Experimental)
H.J. Müller and J.A. Jöbstl. High Temperature Modifications of Alkali Azides, Z. Kristallogr. A, Vol 121 (No. 5), 1965, p 385–391. (Crys Structure; Experimental)
J.I. Bryant, Vibrational Spectrum of CsN3 Crystals, J. Chem. Phys., Vol 45 (No. 2), 1966, p 689–699. (Crys Structure; Experimental)
C.W.F.T. Pistorius, Phase Diagrams to High Pressures of the Univalent Azides Belonging to the Space Group D 184h -14/mcm, J. Chem. Phys., Vol 51 (No. 6), 1969, p 2604–2609. (Pressure; Experimental)
C.E. Hathaway and P.A. Temple, Raman Spectra of KN3, RbN3 and CsN3, Phys. Rev. B, 3rd Se., Vol 3 (No. 10), 1971, p 497. (Crys Structure; Experimental)
U. Muller, Crystal Structure Refinements of KN3, RbN3, CsN3 and T1N3, Z. Anorg. Allg. Chem., Vol 392 (No. 2), 1972, p 159–166 (in German). (Crys Structure; Experimental)
Z. Iqbal and C.W. Christoe, Phase Transition in Cesium Azide. Temperature and Pressure Dependent Raman Studies, J. Chem. Phys., Vol 62 (No. 8), p 3246–3251 (Crys Structure; Experimental)
H.G. Winkler, H.T. Spath, and K. Torkar, The Melting Diagrams of the Systems CsN3-Zn(N3)2 and KN3-Zn(N3)2, Monatsh. Chem., Vol 106 (No. 2), 1975, p 535–545. (Equi Diagram; Experimental)
Y. Sears and M. Steinberg, The Catalytic Effect of Cs Oxides on the Thermal Decomposition of CsN3, Thermochim. Acta, Vol 75, 1984, p 233–238. (Equi Diagram; Experimental)
F. Blatter and E. Schumacher, Production of High Purity Cs, J. Less-Common Met., Vol 115 (No. 2), 1986, p 307–313. (Equi Diagram, Thermo; Experimental)
S.B. Sharma, P. Paliwal, and M. Kumar, Electronic Dielectric Constant, Energy Gap and Fractional Ionic Character of Polyatomic Binary Compounds, J. Phys. Chem., Vol 51 (No. 1), 1990, p 35–39. (Theory)
V.N. Belomestnykh, Acoustic Studies of Polymorphic Transformations in Inorganic Azides, Izv. Akad. Nauk SSSR, Neorg. Mater., Vol 29 (No. 2), 1993, p 221–226 (in Russian); TR, Inorg. Mater., Vol 29 (No. 2), 1993, p 217–223. (Crys Structure, Thermo; Review)
H.U. Borgstedt and C. Guminski, Solubilities and Solution Chemistry in Liquid Alkali Metals, Monatsh. Chem., Vol 131 (No. 9), 2000, p 917–930. (Equi Diagram; Review)
H.U. Borgstedt and C. Guminski, IUPAC-NIST Solubility Data Series. 75. Nonmetals in Liquid Alkali Metals, J. Phys. Chem. Ref. Data, Vol 30 (No. 4), 2001, p 835–1158. (Equi Diagram; Review)
M. Genken, S. Schneider, T. Schroer, R. Haiges, and K.O. Christie, Improved Synthesis of CsN3, Z. Anorg. Allg. Chem., Vol 628 (No. 5), 2002, p 909–910. (Equi Diagram; Experimental)
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Sangster, J. Cs-N (Cesium-Nitrogen). J Phs Eqil and Diff 25, 556–557 (2004). https://doi.org/10.1007/s11669-004-0080-2
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DOI: https://doi.org/10.1007/s11669-004-0080-2