Abstract
Knudsen effusion mass spectrometry and a static method were used to study the vapor composition and the thermodynamic properties of the Si-P melt with the phosphorous content from 0.09 to 26.5 at.% in the temperature range 1507 to 1831 K. A representative file of experimental data comprising about 100 values of phosphorus activity at various concentrations and/or temperatures was obtained. The thermodynamic characteristics as functions of temperature and concentration were approximated by the ideal associated-solution model under the assumption that SiP and Si2P complexes exist in the melt. The boundaries of the region of liquid phase stability on the phase diagram were computed, and agreement with the available experimental information was obtained.
Similar content being viewed by others
References
B. Giessen and R. Vogel: Z. Metallkd., 1959, vol. 50 (5), pp. 274–77.
J.B. Mann: Proc Int. Conf. on Mass Spectroscopy, T. Ogata and T. Hayakawa, eds., University Park Press, Tokyo, 1970, pp. 814–17.
Y.A. Ugay, S.I. Meroschnichenko, E.P. Domaschevskaya, and M.A. Vasilevskaya: Neorg. Mater., 1973, vol. 9 (1), pp. 7–9 (in Russian).
S. Ban-ya and M. Suzuki: Tetsu-to-Hagané, 1975, vol. 61, pp. 2933–42 (in Japanese).
Y.A. Ugay, A.F. Demidenko, V.I. Koshchenko, V.E. Yachmenev, L.I. Sokolov, and E.G. Goncharov: Neorg. Mater., 1979, vol. 15 (5), pp. 739–43 (in Russian).
L.V. Gurvich: Vestn. Akad. Nauk SSSR, 1983, No. 3, pp. 54–65 (in Russian).
L.N. Sidorov, M.V. Korobov, and L.V. Zhuravlyeva: Mass-Spectral’nye Termodinamicheskie Issledovaniya, Moscow State University Press, Moscow, 1985, p. 208 (in Russian).
M.W. Chase, C.A. Davies, J.R. Downey, D.J. Frurip, R.A. McDonald, and A.N. Syverud: JANAF Thermochemical Tables. J. Phys. Chem. Ref. Data, 1985, vol. 14, suppl. 1, pp. 1735–47.
I. Karakaya and W.T. Thompson: Bull. Alloy Phase Diagrams, 1988, vol. 9 (3), pp. 232–36.
The Japan Society for Promotion of Science: The 19th Committee in Steelmaking: Steelmaking Data Sourcebook, Gordon and Beach Science Publishers, New York, NY, 1988, pp. 35–38.
A.I. Zaitsev, N.V. Korolyov, and B.M. Mogutnov: Teplofiz. Vys. Temp., 1989, vol. 27 (3), pp. 465–71 (in Russian).
A.I. Zaitsev, M.A. Zemchenko, and B.M. Mogutnov: Rasplavy., 1989, No. 2, pp. 9–19 (in Russian).
A.I. Zaitsev, M.A. Zemchenko, and B.M. Mogutnov: Zh. Fiz. Khim., 1990, vol. 64 (12), pp. 3377–78 (in Russian).
A.I. Zaitsev, N.V. Korolyov, and B.M. Mogutnov: High Temp. Sci., 1990, vol. 28, pp. 341–50.
A.I. Zaitsev, N.V. Korolyov, and B.M. Mogutnov: J. Chem. Thermodyn., 1991, vol. 23, pp. 11–23.
A.T. Dinsdale: CALPHAD, 1991, vol. 15 (4), pp. 317–425.
A.M. Katsnel’son, B.Y. Daschevskii, A.S. Krylov, and V.I. Kaschin: in Fizico-Khimicheskie Osnovy Metallurgicheskikh Protsessov, Chermetinformatsiya Press, Moscow, 1991, part 1, pp. 48–51 (in Russian).
A.I. Zaitsev, Z.V. Dobrokhotova, T.A. Elizarova, and B.M. Mogutnov: Neorg. Mater., 1995, vol. 31 (12), pp. 1509–19 (in Russian).
A.I. Zaitsev, Z.V. Dobrokhotova, A.D. Litvina, and B.M. Mogutnov J. Chem. Soc. Faraday Trans., 1995, vol. 91 (4), pp. 703–12.
A.I. Zaitsev and B.M. Mogutnov: High Temp. Mater. Sci., 1995, vol. 34 (1–3), pp. 155–71.
T. Miki, K. Morita, and N. Sano: Metall. Mater. Trans. B, 1996, vol. 27B, pp. 937–41.
A.I. Zaitsev, A.D. Litvina, N.E. Shelkova, Z.V. Dobrokhotova, and B.M. Mogutnov: Z. Metallkd., 1997, vol. 88 (1), pp. 76–86.
A.I. Zaitsev, A.D. Litvina, N.E. Shelkova, and B.M. Mogutnov: Thermochim. Acta, 1998, vol. 314, pp. 307–15.
A.I. Zaitsev, N.V. Korolyov, N.P. Lyakischev, and B.M. Mogutnov: Z. Neorg. Khim., 1999, vol. 44 (8), pp. 1384–88 (in Russian).
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Zaitsev, A.I., Shelkova, N.E. & Kodentsov, A.A. Thermodynamic properties and phase equilibria in the silicon-phosphorous system. JPE 21, 528 (2000). https://doi.org/10.1007/s11669-000-0021-7
Received:
Revised:
DOI: https://doi.org/10.1007/s11669-000-0021-7