Abstract
Corrosion inhibition studies of 5-[(4-chlorophenoxy) methyl]-4H-1, 2, 4-triazole-3-thiol (CMTT) on 6061 Al alloy in 0.05 M HCl were carried out at different concentrations and temperatures. Weight loss method, potentiodynamic polarization and electrochemical impedance spectroscopy (EIS) were employed in the study. Higher concentration and temperature were found to improve the efficiency of inhibitor. Highest corrosion resistance of 95.29% was recorded with 100 ppm CMTT at 333 K. Adsorption of the inhibitor was spontaneous as indicated by Langmuir adsorption isotherm. Thermodynamic parameters, SEM, AFM results indicated that inhibitor used protects the alloy from corrosion. Quantum chemical parameters such as highest occupied molecular orbital energy (EHOMO), lowest unoccupied molecular orbital energy (ELUMO), energy gap (ΔE), dipole moment (l) and Mulliken charges are calculated. Quantum chemical calculations also endorsed experimental information and the adsorption of inhibitor molecules onto the metal surface.
Similar content being viewed by others
References
G.M. Scamans, N. Birbilis, R.G. Buchheit, Shreir’s Corrosion, , in T.J. Richardson (Ed) Elsevier, Amsterdam, Vol. 2, pp. 1974, (2010)
K.A. Yasakau, J. Tedim, M.L. Zheludkevich, M.G.S. Ferreira, Handbook of Smart Coatings for Materials Protection, in A.S. Hamdy (Ed), pp. 224, (2014)
N.L. Sukiman, X. Zhou, N. Birbilis, A.E. Hughes, J.M.C. Mol, S.J. Garcia, X. Zhou, G.E. Thompson, Durability and corrosion of aluminium and its alloys: Overview, property space, techniques and developments, Intech, Croatia, Europe, pp. 47–97, (2011)
W.A. Badawy, F.M. Al-Kharafi, A.S. El-Azab, Corros. Sci. 41, 709–727 (1999)
A.J. Trowsdale, B. Noble, S.J. Haris, I.S.R. Gibbins, G.E. Thomson, G.C. Wood, Corros. Sci. 38, 177–191 (1996)
S.I. Pyun, K.H. Na, W.J. Lee, J.J. Pank, Corros. Sci. 56, 1015–1021 (2000)
M.A. Amin, Q. Mohsen, O.A. Hazzai, Mater Chem Phy 114, 908–914 (2009)
C.C. Nathan, Corrosion Inhibitors, National Association of Corrosion Engineers (NACE), Houston, pp. 279, (1973)
F. Hunkeler, H. Bohni, Corrosion 40(10), 534–540 (1984)
Y. Abboud, A. Abourriche, T. Saffaj, M. Berrada, Appl. Surf. Sci. 252, 8178–8184 (2006)
S.V. Lamaka, M.L. Zheludkevich, K.A. Yasakau, M.F. Montemor, M.G.S. Ferreira, Electrochim. Acta 52, 7231–7247 (2007)
T. Kosec, I. Milošev, B. Pihlar, Appl. Surf. Sci. 253, 8863–8873 (2007)
E. Abdullayev, Y. Lvov, J. Mater. Chem. 20, 6681–6687 (2010)
S. Marcelin, N. Pébère, Corros. Sci. 101, 66–74 (2015)
F. Bentiss, C. Jama, B. Mernari, H.E. Attari, L.E. Kadi, M. Lebrini, M. Traisnel, M. Lagrenée, Corros. Sci. 51, 1628–1635 (2009)
M. Tourabi, K. Nohair, M. Traisnel, C. Jama, F. Bentiss, Corros. Sci. 75, 123–133 (2013)
M.E. Belghiti, Y. Karzazi, A. Dafali, B. Hammouti, F. Bentiss, I.B. Obot, I. Bahadur, E.E. Ebenso, J. Mol. Liq. 218, 281–293 (2016)
B.E. Mehdi, B. Mernari, M. Traisnel, F. Bentiss, M. Lagrenée, Mater. Chem. Phys. 77, 489–496 (2002)
M.A. Quraishi, R. Sardar, Corros. Sci. 58, 748–755 (2002)
A.Y. Musa, A.A.H. Kadhum, A.B. Mohamad, M.S. Takriff, Corros. Sci. 52, 3331–3340 (2010)
B.D. Mert, M.E. Mert, G. Kardaş, B. Yazici, Corros. Sci. 53, 4265–4272 (2010)
A. Lesar, I. Milošev, Chem. Phys. Lett. 483, 198–203 (2009)
H.H. Hassan, E. Abdelghani, M.A. Amin, Electrochim. Acta 52, 6359–6366 (2007)
H.H. Hassan, Electrochim. Acta 53, 1722–1730 (2007)
M.K. Awad, M.R. Mustafa, Elnga, J. Mol. Struct. Theochem. 959, 66–74 (2010)
S. John, A. Joseph, Mater. Chem. Phys. 133, 1083–1091 (2012)
M.G. Fontana, Corrosion Engineering, 3rd edn. (McGraw-Hill, Singapore, 1987)
R. Agrawal, S.S. Pancholi, Der Pharma Chemica 3(6), 32–40 (2011)
E.S. Ferreira, C. Giancomelli, F.C. Giacomelli, A. Spinelli, Mater. Chem. Phy. 83, 129–134 (2004)
W.H. Li, Q. He, C.L. Pei, B.R. Hou, Electrochem. Acta 52, 6386–6394 (2007)
W.H. Li, Q. He, C.L. Pei, B.R. Hou, J. Appl. Electrochem. 38, 289–295 (2008)
V.O. Njoku, E.E. Oguzie, C. Obi, A.A. Ayuk, Adv. Chem. 10, 1125–1155 (2014)
R. Rosliza, H.B. Senin, W.B. Wan Nik, Colloids Surf. 312, 185–189 (2008)
G.M. Pinto, J. Nayak, A. Nityananda Shetty, Mater. Chem. Phy. 125, 628–640 (2011)
M.A. Migahed, Mater. Chem. Phy. 93, 48–53 (2005)
A.K. Singh, M.A. Quraishi, Corros. Sci. 52(1), 152–160 (2010)
I.D. Raistrick, D.R. Franceschetti, J.R. Macdonal, A Review of: Impedance Spectroscopy, Theory, Experiment, and Applications (Wiley, New York, 2005)
E.M. Kenton et al., Electrochem. Acta 53, 6024–6032 (2008)
J. Yahalom, Corros. Sci. 12, 867–868 (1972)
A. Popava, M. Christov, S. Raicheva, E. Sokolov, Corros. Sci. 46, 1333–1350 (2004)
H. Ashassi-Sorkhabi, B. Shaabani, D. Seifzadeh, Appl. Surf. Sci. 239, 154–164 (2005)
N. Soltani, M. Behpour, S.M. Ghoreishi, H. Naeimi, Corros. Sci. 52, 1351–1361 (2010)
Zhihua Tao, Shengtao Zhang, Weihua Li, Baorong Hou, Corros. Sci. 51, 2588–2595 (2009)
A.M. Fekry, M.A. Ameer, Int. J. Hydrog. Energy 35, 7641–7651 (2010)
S.P. Fakrudeen, A. Murthyh, R.V. Bheema, J. Chil. Chem. Soc. 57, 1364–1370 (2012)
S. Martinez, I. Stern, Appl. Surf. Sci. 199, 83–86 (2012)
S. Rajenran, J. Electrochem. Soc. 54, 61–71 (2005)
J. Bhawsar, P.K. Jain, P. Jain, Alex Eng. J. 54, 769–775 (2015)
C. Verma, T.W. Quadri, L.O. Olasunkanmi, E.S.M. Sherif, E.E. Ebenso, J. Phys. Chem. C (2018). https://doi.org/10.1021/acs.jpcc.8b02740
L.O. Olasunkanmi, I.B. Obot, M.M. Kabanda, E.E. Ebenso, J. Phys. Chem. 119, 16004–16019 (2015)
L.O. Olasunkanmi, M.F. Sebona, E.E. Ebenso, J. Mol. Strut. 1149, 549–559 (2017)
S.K. Saha, M. Murmu, N.C. Murmu et al., J. Mol. Liq. 224, 629–638 (2016)
Author information
Authors and Affiliations
Corresponding author
Ethics declarations
Conflict of interest
The authors declare that there is no conflict of interest.
Additional information
Publisher's Note
Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.
Rights and permissions
About this article
Cite this article
Raviprabha, K., Bhat, R.S. Electrochemical and Quantum Chemical Studies of 5-[(4-Chlorophenoxy) Methyl]-4H-1,2,4-Triazole-3-Thiol on the Corrosion Inhibition of 6061 Al Alloy in Hydrochloric Acid. J Fail. Anal. and Preven. 20, 1598–1608 (2020). https://doi.org/10.1007/s11668-020-00954-2
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s11668-020-00954-2