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Electrochemical Behavior of N1-(3-Methylphenyl)Piperidine-1,4-Dicarboxamide as a Corrosion Inhibitor for Soft-Cast Steel Carbon Steel in 1 M HCl

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Abstract

The electrochemical corrosion behavior of N1-(3-methylphenyl)piperidine-1,4-dicarboxamide soft-cast steel in 1 M HCl was investigated at the temperature range of 303–333 K. The experiments used for this investigation are electrochemical potentiodynamic polarization and impedance spectroscopic measurements. The results found from this investigation suggested that N1-(3-methylphenyl)piperidine-1,4-dicarboxamide acts as a good corrosion inhibitor for soft-cast steel in 1 M HCl. We found 94% of inhibition efficiency at optimized inhibitor concentrations of 100 ppm. The inhibition efficiency of inhibitor increases with the increasing inhibitor concentration as well as the temperature of corrosive media. The polarization measurement suggested that the N1-(3-methylphenyl)piperidine-1,4-dicarboxamide inhibits the corrosion of soft-cast steel by the adsorption process and it acts as a mixed-type inhibitor. The adsorption of the inhibitor compound is determined, which obeys the Freundlich’s adsorption isotherm model. Surface investigation of surfaces of soft-cast steel was examined by scanning electron microscopic measurements.

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References

  1. H.L. Wang, H.B. Fan, J.S. Zheng, Corrosion Inhibition of Mild Steel in Hydrochloric Acid Solution by a Mercapto-Triazole Compound. Mater. Chem. Phys. 77, 655–661 (2002)

    Article  Google Scholar 

  2. M. Yadav, D. Behera, U. Sharma, Non-toxic Corrosion Inhibitors for N80 Steel in Hydrochloric Acid. Chem. Sin. 3, 262–268 (2012)

    CAS  Google Scholar 

  3. I. Ahamad, M.A. Quraishi, Bis (benzimidazol-2-yl) Disulfide: An Efficient Water-Soluble Inhibitor for Corrosion of Mild Steel in Acid Media. Corros. Sci. 51, 2006–2013 (2009)

    Article  CAS  Google Scholar 

  4. S.A. Ali, A.M. El-Shareef, R.F. Al-Ghandi, M.T. Saeed, The Isoxazolidines: The Effects of Steric Factor and Hydrophobic Chain Length on the Corrosion Inhibition of Mild Steel in Acidic Medium. Corros. Sci. 47, 2659–2678 (2005)

    Article  CAS  Google Scholar 

  5. D. Jayaperumal, Effects of Alcohol-Based Inhibitors of Corrosion of Mild Steel in Hydrochloric Acid. Mater. Chem. Phys. 119, 478–484 (2010)

    Article  CAS  Google Scholar 

  6. E.S. Ferreira, C. Giancomlli, F.C. Giacomlli, A. Spinelli, Evaluation of the Inhibitor Effect of l-Ascorbic Acid on the corrosion of mild steel. Mater. Chem. Phys. 83, 129–134 (2004)

    Article  CAS  Google Scholar 

  7. F. Bentiss, M. Lebrini, H. Vezin, F. Chai, M. Traisnel, M. Lagrenee, Enhanced Corrosion Resistance of Carbon Steel in Normal Sulfuric Acid Medium by Some Macrocyclic Polyether Compounds Containing a 1,3,4-Thiadiazole Moiety: AC Impedance and Computational Studies. Corros. Sci. 51, 2165–2173 (2009)

    Article  CAS  Google Scholar 

  8. B.M. Prasanna, B.M. Praveen, B.M. Narayana Hebbar, T.V. Venkatesha, H.C. Tandon, Ketosulfone Drug as a Green Corrosion Inhibitor for Mild Steel in Acidic Medium. Ind. Eng. Chem. Res. 53, 8436–8444 (2014)

    Article  Google Scholar 

  9. Q. Qu, S.A. Jiang, W. Bai, L. Li, Effect of Ethylenediaminetetraacetic Acid Disodium on the Corrosion Of Cold-Rolled Steel in the Presence of Benzotriazole in Hydrochloric Acid. Electrochim. Acta 52, 6811–6820 (2007)

    Article  CAS  Google Scholar 

  10. A.M. Badiea, K.N. Mohana, Effect of Temperature and Fluid Velocity on Corrosion Mechanism of Low Carbon Steel in Presence of 2-hydrazino-4,7-dimethylbenzothiazole in an Industrial Water Medium. Corros. Sci. 51, 2231–2241 (2009)

    Article  CAS  Google Scholar 

  11. G.E. Badr, The Role of Some Thiosemicarbazide Derivatives as Corrosion Inhibitors for C-Steel in Acidic Media. Corros. Sci. 51, 2529–2536 (2009)

    Article  CAS  Google Scholar 

  12. L. Xianghong, D. Shuduan, F. Hui, Benzyltrimethylammonium Iodide as a Corrosion Inhibitor for Steel in Phosphoric Acid Produced by Dihydrate Wet Method Process. Corros. Sci. 53, 664–670 (2011)

    Article  Google Scholar 

  13. B.M. Prasanna, B.M. Praveen, N. Hebbar, M.K. Pavithra, T.S. Manjunatha, R.S. Malladi, Theoretical and Experimental Approach of Inhibition Effect by Sulfamethoxazole on Mild Steel Corrosion in 1-M HCl. Surf. Interface Anal. 50, 779–789 (2018)

    Article  CAS  Google Scholar 

  14. B.M. Prasanna, B.M. Praveen, N. Hebbar, T.V. Venkatesha, H.C. Tandon, Inhibition Study of Mild Steel Corrosion in 1 M Hydrochloric Acid Solution by 2-Chloro 3-formyl quinoline. Int J Ind Chem (2015). https://doi.org/10.1007/s40090-015-0064-6

    Article  Google Scholar 

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Authors and Affiliations

  1. Department of Chemistry, Davanagere University, Davanagere, 577 002, India

    S. Rajendraprasad & Shoukath Ali

  2. Department of Chemistry, Jain Institute of Technology, Davanagere, Visvesvaraya Technological University, Belagavi, 577 003, India

    B. M. Prasanna

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  1. S. Rajendraprasad
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  2. Shoukath Ali
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  3. B. M. Prasanna
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Correspondence to S. Rajendraprasad.

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Rajendraprasad, S., Ali, S. & Prasanna, B.M. Electrochemical Behavior of N1-(3-Methylphenyl)Piperidine-1,4-Dicarboxamide as a Corrosion Inhibitor for Soft-Cast Steel Carbon Steel in 1 M HCl. J Fail. Anal. and Preven. 20, 235–241 (2020). https://doi.org/10.1007/s11668-020-00824-x

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