Skip to main content
Log in

Electrochemical Behavior of 1,3-bis(1-Phenylethyl) Urea as a Corrosion Inhibitor for Carbon Steel in 1 M HCl

  • Technical Article---Peer-Reviewed
  • Published:
Journal of Failure Analysis and Prevention Aims and scope Submit manuscript

Abstract

1,3-bis(1-Phenylethyl) urea was investigated as a good corrosion inhibitor for carbon steel by electrochemical techniques in 1 M HCl at a temperature range of 305–335 K. The investigation was done by electrochemical techniques such as potentiodynamic Tafel polarization and impedance spectroscopy. The calculated corrosion inhibition efficiency of inhibitor increases with their increasing concentrations. The Tafel polarization method reveals that the inhibitor acts as mixed type inhibitor. The inhibition effect of inhibitor attributed due to the adsorption on surface of carbon steel from 1 M HCl. The adsorption of inhibitor obeys the Langmuir’s adsorption isotherm. The activation parameters indicate that the adsorption process is exothermic in nature. The scanning electron microscopic measurement gives a visual idea about the formation of protective layer on carbon steel surfaces, which retards the corrosion process.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7
Fig. 8
Fig. 9

Similar content being viewed by others

References

  1. H.L. Fan, H.B. Zheng, Inhibition of mild steel in hydrochloric acid solution by a mercapto-triazole compound. J. Mater. Chem. Phys. 77, 655–661 (2002)

    Google Scholar 

  2. M. Yadav, D. Behera, U. Sharma, Nontoxic corrosion inhibitors for N80 steel in hydrochloric acid. Chem. Sin. 3, 262–268 (2012)

    CAS  Google Scholar 

  3. I. Ahamad, M.A. Quraishi, Bis (benzimidazol-2-yl) disulphide: an efficient water soluble inhibitor for corrosion of mild steel in acid media. Corros. Sci. 51, 2006–2013 (2009)

    Article  CAS  Google Scholar 

  4. Q.B. Zhang, Y.X. Hua, Carbon steel corrosion behavior in aqueous carbonated solution of MEA/[bmim] [DCA]. Electrochim. Acta 54, 1881–1887 (2009)

    Article  CAS  Google Scholar 

  5. B.M. Prasanna, B.M. Praveen, N. Hebbar, T.V. Venkatesha, H.C. Tandon, Inhibition study of mild steel corrosion in 1 M hydrochloric acid solution by 2-chloro 3-formyl quinolone. Int. J. Ind. Chem. 7(1), 9–19 (2016)

    Article  CAS  Google Scholar 

  6. S.A. Ali, A.M. El-Shareef, R.F. Al-Ghandi, M.T. Saeed, The isoxazolidines: the effects of steric factor and hydrophobic chain length on the corrosion inhibition of mild steel in acidic medium. Corros. Sci. 47, 2659–2678 (2005)

    Article  CAS  Google Scholar 

  7. D. Jayaperumal, Effects of alcohol-based inhibitors of corrosion of mild steel in hydrochloric acid. Mater. Chem. Phys. 119, 478–484 (2010)

    Article  CAS  Google Scholar 

  8. E.S. Ferreira, C. Giancomlli, F.C. Giacomlli, A. Spinelli, Evaluation of the inhibitor effect of L-ascorbic acid on the corrosion of mild steel. Mater. Chem. Phys. 83, 129–134 (2004)

    Article  CAS  Google Scholar 

  9. A.M. Badiea, K.N. Mohana, Effect of temperature and fluid velocity on corrosion mechanism of low carbon steel in presence of 2-hydrazino-4,7-dimethylbenzothiazole in industrial water medium. Corros. Sci. 51, 2231–2241 (2009)

    Article  CAS  Google Scholar 

  10. B.M. Prasanna, B.M. Praveen, Hebbar Narayana, T.V. Venkatesha, H.C. Tandon, Ketosulfone drug as a green corrosion inhibitor for mild steel in acidic medium. I&EC Res. 53, 8436–8444 (2014)

    Google Scholar 

  11. B.M. Prasanna, B.M. Praveen, N. Hebbar, Theoretical and experimental approach of inhibition effect by sulfamethoxazole on mild steel corrosion in 1 M HCl. Surf Interface Anal. (2018). https://doi.org/10.1002/sia.6457

    Article  Google Scholar 

  12. A. Ostovari, S.M. Hoseinieh, M. Peikari, S. Hashemi, Corrosion inhibition of mild steel in 1 M HCl solution by henna extract: a comparative study of the inhibition by henna and its constituents (Lawsone, Gallic acid, α-d-Glucose and Tannic acid). J. Corros. Sci. 51, 1935–1949 (2009)

    Article  CAS  Google Scholar 

  13. E.E. Oguzie, V.O. Njoku, C.K. Enenebeaku, C.O. Akalezi, C. Obi, Effect of hexamethylpararosaniline chloride (crystal violet) on mild steel corrosion in acidic media. Corros. Sci. 50, 3480–3486 (2008)

    Article  CAS  Google Scholar 

  14. S. Martinez, I. Stern, Thermodynamic characterization of metal dissolution and inhibitor adsorption processes in the low carbon steel/mimosa tannin/sulfuric acid system. Appl. Surf. Sci. 199, 83–89 (2002)

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to B. Padmashree.

Additional information

Publisher's Note

Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Padmashree, B., Manjunatha, K. & Prasanna, B.M. Electrochemical Behavior of 1,3-bis(1-Phenylethyl) Urea as a Corrosion Inhibitor for Carbon Steel in 1 M HCl. J Fail. Anal. and Preven. 20, 226–234 (2020). https://doi.org/10.1007/s11668-020-00822-z

Download citation

  • Received:

  • Revised:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11668-020-00822-z

Keywords

Navigation