Abstract
Corrosion inhibition mechanisms of Rubber, Neem and Jatropha seeds oils on low-alloyed low-carbon steel in 0.5 M·H2SO4 environment have been investigated herein. Potentiodynamic polarization, electrochemical impedance spectroscopy and scanning electron spectroscopy techniques were employed for the experimental process. The results obtained showed that inhibition efficiencies for Rubber, Neem and Jatropha seeds oils reached values of 99.957, 99.275 and 99.998%, respectively. The most shifts in corrosion potentials were > 85 and < 85 in positive directions for Rubber and Neem seeds oils, respectively, while Gibbs free energy of adsorption had values − 29.29 and − 15.06 and − 11.90 kJ/mol for Rubber, Neem and Jatropha seeds oils, respectively. Addition of oil inhibitors initiated formation of protective oxide films on substrate which contributed to increased inhibition efficiencies. The porosity of formed oxide film directly had impact on corrosion inhibition process as it led to localized reactions on substrate. Morphological examination of corroded substrates revealed that RSO was less prone to local corrosive attack. Inhibition efficiencies under the two electrochemical techniques employed corroborated, and corrosion inhibition occurred by retarding charge transfer reactions.
Similar content being viewed by others
References
O.R. Adetunji, P.O. Aiyedun, O.J. Alamu, A.S. Surakat, Electrochemical properties of metals in cassava fluid. J. Eng. Technol. Res. 3(10), 292–297 (2011)
O.A. Omotosho, J.O. Okeniyi, J.O. Ikotun, C.A. Loto, A.P.I. Popoola, Corrosion behaviour of mild steel in 0.5 M sulphuric acid media in the presence of potassium chromate. J. Eng. Appl. Sci. 13(14), 5789–5795 (2018)
V.I. Astaschenko, E.A. Zapadnova, N.N. Zapadnova, G.F. Mukhametzyanova, Predicting structure micro-alloyed steel products of different purpose. IOP Conf. Ser. Mater. Sci. Eng. 134, 1–3 (2016)
S.S. Rawat, M.K. Sharma, M.S. Gurjar, Investigation on trip behaviour of low carbon micro alloyed steel. Inter. J. Eng. Technol. Sci. Res. 3(5), 25–33 (2016)
Y. Tian, H. Wang, Y. Li, Z. Wang, G. Wang, The analysis of the microstructure and mechanical properties of low carbon microalloyed steels after ultra fast cooling. Mater. Res. 20(3), 853–859 (2017)
M. Faisal, A. Saeed, D. Shahzad, N. Abbas, F.A. Larik, General properties of and comparison of the corrosion inhibition efficiency of the triazole derivatives for mild steel. Corros. Rev. 36(6), 507–545 (2018)
American Iron and Steel Institute, A Designers’ Handbook Series No 9001: Cleaning and Descaling Stainless Steels. Nickel Development Institute. North Carolina, USA. 36pp (1988) (Original Work Published 1982)
L. Messaadia, O.I.D. El Mouden, A. Anejjar, M. Messali, R. Salghi, O. Benali, O. Cherkaoui, A. Lallam, Adsorption and corrosion inhibition of new synthesized pyridazinium-based ionic liquid on carbon steel in 0.5 M H2SO4. J. Mater. Environ. Sci. 6(2), 598–606 (2015)
M.S. Al-Otaibi, A.M. Al-Mayouf, M. Khan, A.A. Moussa, S.A. Al-Mazroa, H.Z. Alkhathlan, Corrosion inhibitory action of some plant extracts on the corrosion of mild steel in acidic media. Arab. J. Chem. 7, 340–346 (2014)
G. Aziate, A. El Yadini, H. Saufi, A. Almaofari, A. Benhmama, H. Harhar, S. Gharby, S. El Hajjaji, Study of jojoba vegetable oil as inhibitor of carbon steel C38 corrosion in different acidic media. J. Mater. Environ. Sci. 6(7), 1877–1884 (2015)
A.S. Yaro, A.A. Khadom, R.K. Wael, Apricot juice as green corrosion inhibitor of mild steel in phosphoric acid. Alexandria Eng. J. 52, 129–135 (2013)
M.H. Nazari, M.S. Shihab, L. Cao, E.A. Haven, X. Shi, A peony–leaves-derived liquid corrosion inhibitor: protecting carbon steel form NaCl. Green Chem. Lett. Rev. 10(4), 359–379 (2017)
N. Belarbi, F. Dergal, I. Chikhi, S. Merah, D. Lerari, K. Bachari, Study of anti-corrosion activity of Algerian L. stoechas oil on C38 carbon steel in 1 M HCl medium. Int. J. Ind. Chem. 9(2), 115–125 (2018)
M. Zouarhi, M. Chellouli, S. Abbout, H. Hammouch, A. Dermaji, S.O. Said Hassane, P. Decaro, N. Bettach, N. Hajjaji, A. Srhiri, Inhibiting effect of a green corrosion inhibitor containing Jatropha curcas seed oil for iron in an acidic medium. Portugaliae Electrochimi Acta 36(3), 179–195 (2018)
K. Chatoui, S. Echihi, H. Harhar, A. Zarrouk, M. Tabyaoui, An investigation of carbon steel corrosion inhibition in 1 M HCl by Lepidium sativum oil as green inhibitor. J. Mater. Environ. Sci. 9(4), 1212–1223 (2018)
O. Mokhtari, I. Hamdani, A. Chetouani, A. Lahrach, A. ElHalouani, A. Aounit, M. Berrabah, Inhibition of steel corrosion in 1 M HCl by Jatropha curcas Oil. J. Mater. Environ. Sci. 5(1), 310–319 (2014)
V.M. Abbasov, I.T. Ismayilov, H.M. Abd El-Lateef, S.F. Akhmadbeyovea, Anti-corrosive activities of some novel surfactants based on vegetable oils. Eur. Chem. Bull. 3(5), 437–440 (2014)
S.O. Ajeigbe, N. Basar, M.A. Hassan, M. Aziz, Optimization of corrosion inhibition of essential oils of Alpina galanga on mild steel using response surface methodology. ARPN J. Eng. Appl. Sci. 12(9), 2763–2771 (2017)
B.U. Ugi, T.O. Magu, Inhibition, adsorption and thermodynamic investigation of iron corrosion by green inhibitors in acidic medium. Int. J. Sci. Technol. 5(4), 56–64 (2017)
S. Aribo, O.J. Samuel, S.J. Olusegun, A.S. Ogunbadejo, O.O. Ige, Jatropha curcas as a corrosion inhibitor for API 5L-X65 steel under sand deposit in CO2 and aerated oil field environments. Afr. Corros. J. 2(2), 17–27 (2016)
A.O. Okewale, A. Olaitan, The use of rubber leaf extract as a corrosion inhibitor for mild steel in acidic solution. Inter. J. Mater. Chem. 7(1), 5–12 (2017)
M.E. Mohadyaldinn, N. Azad, A.K. Azad, Evaluation of Jatropha curcas oil as corrosion inhibitor of CO2 corrosion in petroleum production environment. J. Appl. Environ. Biol. Sci. 7(35), 28–34 (2017)
R.T. Loto, Corrosion polarization behaviour and inhibition of S40977 stainless steel in benzosulfonazole/3M H2SO4 solution. S. Afr. J. Chem. Eng. 24, 148–155 (2017)
E. Ituen, O. Akaranta, A. James, Evaluation of performance of corrosion inhibitors using adsorption isotherm models: an overview. Chem. Sci. Inter. J. 18, 1–34 (2017)
A. Chaouiki, H. Lgaz, R. Salghi, S.L. Gaonkar, K.S. Bhat, S. Jodeh, K. Toumiat, H. Oudda, New benzohydrazide derivative as corrosion inhibitor for carbon steel in a 1.0 M HCl solution: electrochemical, DFT and Monte Carlo simulation studies. Portugaliae Electrochimi. Acta 37(3), 147–165 (2019)
A. Singh, M. Talha, X. Xu, Z. Sun, Y. Lin, Heterocyclic corrosion inhibitors for J55 steel in a sweet corrosive medium. ACS Omega 2, 8177–8186 (2017)
A. Kosari, M.H. Moayed, A. Davoodi, R. Parvizi, M. Momeni, H. Eshghi, H. Moradi, Electrochemical and quantum chemical assessment of two organic compounds from pyridine derivatives as corrosion inhibitors for mild steel in HCl solution under stagnant condition and hydrodynamic flow. Corros. Sci. 78, 138–150 (2014)
R.T. Loto, Electrochemical analysis of the corrosion inhibition properties of L-leucine and trypsin complex admixture on high carbon steel in 1 M H2SO4 solution. Rev. Colomb. Quim. 47(2), 12–20 (2018)
M. Taghavikish, N.K. Dutta, N.R. Choudhury, Emerging corrosion inhibitors for interfacial coating. Coatings 7, 1–28 (2017)
M. Butnariu, P. Negrea, L. Lupa, M. Ciopee, A. Negrea, M. Pentea, I. Sarac, I. Samfira, Remediation of rare earth element pollutants by sorption process using organic natural sorbents. Inter. J. Environ. Res. Public Health 12, 11278–11287 (2015)
V.M. Abbasov, H.M. Abd El-Lateef, L.I. Aliyeva, E.E. Qasimov, I.T. Ismayilov, M.M. Khalaf, A study of the corrosion inhibition of mild steel C1018 in CO2-saturated brine using some novel surfactants based on corn oil. Egypt. J. Pet. 22, 451–470 (2013)
M.Y. Diaz-Cardenas, M.G. Valladares-Cisneros, S. Lagunas-Rivera, V.M. Salinas-Bravo, R. Lopez-Sesenes, J.G. Gonzalez-Rodriguez, Peumus boldus extract as corrosion inhibitor for carbon steel in 0.5 M sulfuric acid. Green Chem. Lett. Rev. 10(4), 257–268 (2017)
Q. Wang, J. Yu, J. Xu, H. Fang, S. Liu, Y. Tang, Y. Xi, S. Bai, Realization of graphene on the surface of electroless Ni–P coating for short-term corrosion prevention. Coatings 130(8), 1–10 (2018)
Y. Xu, S. Zhang, W. Li, L. Guo, S. Xu, L. Feng, L.H. Madkour, Experimental and theoretical investigations of some pyrazolo–pyrimidine derivatives as corrosion inhibitors on copper in sulfuric acid solution. Appl. Surf. Sci. 459, 612–620 (2018)
A. Carmon-Hernandez, E. Vazquez-Velez, J. Uruchurtu-Chavarin, J.G. Gonzalez-Rodriguez, L. Martinez-Gomez, Use of an imidazol synthetized from palm oil as corrosion inhibitor for a supermartensitic stainless steel in H2S. Green Chem. Lett. Rev. 12(1), 89–99 (2019)
D.V. Ribeiro, C.A.A. Souza, J.C.C. Abrantes, Use of electrochemical impedance spectroscopy (EIS) to monitoring the corrosion of reinforced concrete. Ibracon Struct. Mater. J. 8(4), 529–546 (2015)
Acknowledgments
The authors wish to express their profound gratitude to MIDWAL engineering, Lagos, Nigeria, and Department of Metallurgical and Materials Engineering, Federal University of Technology, Akure, Nigeria, for use of equipment and facilities in the course of the experimental work.
Author information
Authors and Affiliations
Corresponding author
Additional information
Publisher's Note
Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.
Rights and permissions
About this article
Cite this article
Adesusi, O.M., Adetunji, O.R., Ismaila, S.O. et al. Electrochemical Inhibitory Effects of Non-edible Vegetable Oils on Low-Alloyed Low Carbon Steel in H2SO4. J Fail. Anal. and Preven. 20, 159–172 (2020). https://doi.org/10.1007/s11668-020-00808-x
Received:
Revised:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s11668-020-00808-x