Journal of Failure Analysis and Prevention

, Volume 15, Issue 3, pp 445–456 | Cite as

Electron Probe Microanalyzer Evaluation of Fatigue Fracture Surface of Nanoclay–Epoxy Composite Materials

  • M. N. A. Nordin
  • Y. Matsuda
  • K. Tokuno
  • K. Goda
Technical Article---Peer-Reviewed


The use of nano-size fillers for polymer and rubber has become a trend in composite manufacturing industries because the amount of the fillers needed to improve the bulk properties of the material can be reduced to less than the amount necessary for normal size fillers. It has been clarified, however, that the formation of small agglomerates of fillers that occurs during fabrication affects the mechanical properties of the material, such as crack initiation and propagation, and fatigue life. Therefore, fatigue tests of a nanoclay–epoxy composite material were conducted in this study. Results show that the composite fatigue life decreases with increased nanoclay contents. To investigate the effects of nanoclay agglomeration or clustering on the fatigue life, an elemental analysis of the fracture surface was conducted using an electron probe microanalyzer (EPMA). From EPMA images, several factors related with agglomerates causing the premature fatigue cracks were analyzed quantitatively and discussed further.


Nanocomposites Nanoclay Fatigue Electron microscopy Agglomeration Clustering 



The authors are grateful to Huntsman Co., Ltd. and Nanocor Inc., which supplied the epoxy resin and nanoclay. The authors are also grateful to Mr. Morifuku from the Centre of Instrumental Analysis, Yamaguchi University for his encouragement and cooperation on guiding and assistance in using the EPMA machine.


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Copyright information

© ASM International 2015

Authors and Affiliations

  • M. N. A. Nordin
    • 1
    • 3
  • Y. Matsuda
    • 1
  • K. Tokuno
    • 1
  • K. Goda
    • 2
  1. 1.Graduate School of Science and EngineeringYamaguchi UniversityUbeJapan
  2. 2.Department of Mechanical EngineeringYamaguchi UniversityUbeJapan
  3. 3.Faculty of Mechanical EngineeringUniversiti Teknikal Malaysia MelakaDurian TunggalMalaysia

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