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Corrosion and Wear Resistance of HVOF-Sprayed Ni-Cr-Co Multi-principal Element Alloy Coating on Copper Plate

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Abstract

The development of protective coatings on copper alloy surfaces represents a critical research direction to enable the widespread industrial application of copper alloys. To improve the corrosion resistance and wear resistance of the copper alloy plates, a Ni-Cr-Co-based multi-principal element alloy coating was prepared via high-velocity oxygen fuel (HVOF). Then, the microstructure, corrosion resistance, and wear resistance of the Ni-Cr-Co coating and the electroplated NiCo coating were analyzed comparatively. The research results show that the phases of the Ni-Cr-Co coating contained face-centered cubic (FCC) solid solution, CrB and M23C6. The NiCo coating exhibited a single-phase FCC solid solution structure. Compared to the NiCo coating, the corrosion current density of the Ni-Cr-Co coating was reduced by 92.1% in NaF solution. A highly protective passive film was formed on the Ni-Cr-Co coating, and its low ΣCSL grain boundary proportion reached as high as 25.7%. Therefore, the Ni-Cr-Co coatings demonstrated superior corrosion resistance. The scratch wear coefficient of the Ni-Cr-Co coating was only 51.9% of that of the NiCo coating, due to the synergistic strengthening of the matrix and hard second phase. This research offers technical support and a theoretical basis foundation for the development of coatings on copper alloys with excellent corrosion resistance and wear resistance.

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Funding

This work was supported by the National Natural Science Foundation of China (Grant No. 51971001) and the Key Research and Development Project of Anhui Province (No. 2022a05020017).

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Authors and Affiliations

  1. School of Materials Science and Engineering, Anhui University of Technology, Maanshan, 243002, China

    Dongbao Huang, Zhenlin Xu, Yizhu He, Xiquan Jia & Tingwei Zhou

  2. Anhui Key Lab of Metal Material and Processing, Maanshan, 243002, China

    Zhenlin Xu & Yizhu He

  3. Fujian Provincial Key Laboratory of Terahertz Functional Devices and Intelligent Sensing, School of Mechanical Engineering and Automation, Fuzhou University, Fuzhou, 350108, China

    Ming Liu

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Huang, D., Xu, Z., He, Y. et al. Corrosion and Wear Resistance of HVOF-Sprayed Ni-Cr-Co Multi-principal Element Alloy Coating on Copper Plate. J Therm Spray Tech (2024). https://doi.org/10.1007/s11666-024-01788-2

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