Abstract
In order to improve the wet sliding wear performance of drilling tools in marine environment, the micro-structured and bimodal-structured WC-10Co4Cr coatings were prepared by High Velocity Oxygen Fuel (HVOF) technology, respectively. The microstructure, phase composition, mechanical properties, corrosion resistance and wet sliding wear performance of the coatings were investigated in simulated seawater drilling fluid. Compared with the micro-structured coatings, the bimodal-structured coatings have denser microstructure, lower porosity and higher microhardness. The WC-10Co4Cr coatings have been corroded by soaking in simulated seawater drilling fluid with different pH values. And then the wet sliding wear is carried out in simulated seawater drilling fluid. It is found that corrosion inhibits wear and shows negative synergistic effect. When the pH value of the simulated seawater drilling fluid is 11, the negative synergistic effect is the most significant and the wear rate is the lowest. Under the same conditions, the bimodal-structured coating has better wet sliding wear resistance. The main failure mechanisms of the coatings are abrasive wear, corrosion wear and fatigue wear.
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References
J.Z. Wang, J. Chen, B.B. Chen, F.Y. Yan and Q.J. Xue, Wear Behaviors and Wear Mechanisms of Several Alloys Under Simulated Deep-Sea Environment Covering Sea Water Hydrostatic Pressure, Tribol. Int., 2012, 56, p 38–46.
X.R. Wang, B.J. Sun, P.Y. Luo, Z.Y. Wang, N. Wang, K. Ke and H. Zhang, Transient Temperature and Pressure Calculation Model of a Wellbore for Dual Gradient Drilling, J. Hydrodyn., 2018, 30(4), p 701–714.
S.N. Verichev, W. Mishakin, D.A. Nuzhdin and E.N. Razov, Experimental Study of Abrasive Wear of Structural Materials Under the High Hydrostatic Pressure, Ocean Eng., 2015, 99, p 9–13.
J.R. Lin, S. Hong, Y. Zheng, W. Sun, M. Kang and X.Q. Xiu, Cavitation Erosion Resistance in NaCl Medium of HVOF Sprayed WC-Based Cermet Coatings at Various Flow Velocities: A Comparative Study on the Effect of Ni and CoCr Binder Phases, Int. J. Refract. Met. Hard Mat., 2021, 94, p 105407.
N. Chen, M.S. Liu and P. He, Influence of Adhesive Strength, Fatigue Strength and Contact Mechanics on the Drilling Performance of Diamond Coating, Materials, 2020, 13(6), p 1402.
Y.B. Guo, Z. Zhang and S.W. Zhang, Advances in the Application of Biomimetic Surface Engineering in the Oil and Gas Industry, Friction, 2019, 7(4), p 289–306.
T.K. Mishra, A. Kumar and S.K. Sinha, Experimental Investigation and Study of HVOF Sprayed WC-12Co, WC-10Co-4Cr and Cr3C2-25NiCr Coating on its Sliding Wear Behavior, Int. J. Refract. Met. Hard Mat., 2021, 94, p 105404.
Z.Y. Piao, B.S. Xu, H.D. Wang and X.X. Yu, Rolling Contact Fatigue Behavior of Thermal-Sprayed Coating: A Review, Crit. Rev. Solid State Mat. Sci., 2019, 6, p 1–28.
L. Lin, G.L. Li, H.D. Wang, J.J. Kang, Z.L. Xu and H.J. Wang, Structure and Wear Behavior of NiCr-Cr3C2 Coatings Sprayed by Supersonic Plasma Spraying and High Velocity Oxy-Fuel Technologies, Appl. Surf. Sci., 2015, 356, p 383–390.
S. Hong, Y.P. Wu, W.W. Gao, J.F. Zhang, Y.G. Zheng and Y. Zheng, Slurry Erosion-Corrosion Resistance and Microbial Corrosion Electrochemical Characteristics of HVOF Sprayed WC-10Co-4Cr Coating for Offshore Hydraulic Machinery, Int. J. Refract. Met. Hard Mat., 2018, 74, p 7–13.
R.P.S. Chakradhar, G. Prasad, K. Venkateswarlu and M. Srivastava, An Investigation on the Wear and Corrosion Behavior of HVOF-Sprayed WC-12Co-Al2O3 Cermet Coating, J. Mater. Eng. Perform, 2018, 27(3), p 1241–1248.
E. Postek and T. Sadowski, Thermomechanical Effects During Impact Testing of WC/Co Composite Material, Compos. Struct., 2020, 241, p 112054.
B. Song, J.W. Murray, R.G. Wellman, Z. Pala and T. Hussain, Dry Sliding Wear Behaviour of HVOF Thermal Sprayed WC-Co-Cr and WC-CrxCy-Ni Coatings, Wear, 2020, 442, p 203114.
J.B. Cheng, B. Sun, Y.Y. Ge, X.L. Hu, L.H. Zhang, X.B. Liang and X.C. Zhang, Effect of B/Si Ratio on Structure and Properties of High-Entropy Glassy Fe25Co25Ni25(BxSi1-x)25 Coating Prepared by Laser Cladding, Surf. Coat. Technol., 2020, 402, p 126320.
L.N. Zhu, C.B. Wang, H.D. Wang, B.S. Xu, D.M. Zhuang, J.J. Liu and G.L. Li, Microstructure and Tribological Properties of WS2/MoS2 Multilayer Films, Appl. Surf. Sci., 2012, 258(6), p 1944–1948.
J.M. Guilemany, S. Dosta, J. Nin and J.R. Miguel, Study of the Properties of WC-Co Nanostructured Coatings Sprayed by High-Velocity Oxyfuel, J. Therm. Spray Tech., 2005, 14(3), p 405–413.
A.H. Dent, S. DePalo and S. Sampath, Examination of the Wear Properties of HVOF Sprayed Nanostructured and Conventional WC-Co Cermets with Different Binder Phase Contents, J. Therm. Spray Tech., 2002, 11(4), p 551–558.
X.B. Liu, J.J. Kang, W. Yue, Z.Q. Fu, L.N. Zhu, D.S. She, J. Liang and C.B. Wang, Performance Evaluation of HVOF Sprayed WC-10Co4Cr Coatings Under Slurry Erosion, Surf. Eng., 2019, 35(9), p 816–825.
G.C. Ji, H.T. Wang, X. Chen, X.B. Bai, Z.X. Dong and F.G. Yang, Characterization of Cold-Sprayed Multimodal WC-12Co Coating, Surf. Coat. Technol., 2013, 235, p 536–543.
Q. Wang, Z.H. Chen, L.X. Li and G.B. Yang, The Parameters Optimization and Abrasion Wear Mechanism of Liquid Fuel HVOF Sprayed Bimodal WC-12Co Coating, Surf. Coat. Technol., 2012, 206(8–9), p 2233–2241.
H.B. Wang, T. Yang, X.Y. Song, X.M. Liu, X.Z. Wang and X. Wu, Wear Resistance Enhancement of Bimodal-Grained Cemented Carbide Coating, Surf. Coat. Technol., 2017, 309, p 759–766.
V.A.D. Souza and A. Neville, Corrosion and Erosion Damage Mechanisms During Erosion-Corrosion of WC-Co-Cr Cermet Coatings, Wear, 2003, 255, p 146–156.
B. Bozzini, G.P.D. Gaudenzi, A. Fanigliulo and C. Mele, Electrochemical Oxidation of WC in Acidic Sulphate Solution, Corros. Sci., 2004, 46, p 453–469.
S. Hochstrasser-Kurz, Y. Mueller, C. Latkoczy, S. Virtanen and P. Schmutz, Analytical Characterization of the Corrosion Mechanisms of WC-Co by Electrochemical Methods and Inductively Coupled Plasma Mass Spectroscopy, Corros. Sci., 2007, 49(4), p 2002–2020.
J.K.W. Robert, H. Stephen and R.T. Mandar, A Critical Review of the Tribocorrosion of Cemented and Thermal Sprayed Tungsten Carbide, Tribo. Int., 2018, 119, p 491–509.
M.R. Thakare, J.A. Wharton, R.J.K. Wood and C. Menger, Exposure Effects of Strong Alkaline Conditions on the Microscale Abrasion–Corrosion of D-Gun Sprayed WC-10Co4Cr Coating, Tribol. Int., 2008, 41(7), p 629–639.
M.R. Thakare, J.A. Wharton, R.J.K. Wood and C. Menger, Exposure Effects of Alkaline Drilling Fluid on the Microscale Abrasion–Corrosion of WC-Based Hardmetals, Wear, 2007, 263, p 125–136.
Y.J. Yao, B.S. Pan, W.Z. Wang and S.C. Tan, Effects of Benzotriazole and Imidazoline on the Tribocorrosion Behaviors of a WC-Based Material in Saline Silica Slurries, Int. J. Refract. Met. Hard Mat., 2021, 97, p 105523.
D.F. Wu, Y.S. Liu, D.L. Li, X.F. Zhao and Y. Liu, Tribo-Corrosion Properties of WC-10Co-4Cr Coating in Natural Silt-Laden Waters When Sliding Against Si3N4, Int. J. Refract. Met. Hard Mat., 2016, 58, p 143–151.
Y.K. Zhou, X.B. Liu, J.J. Kang, W. Yue, W.B. Qin, G.Z. Ma, Z.Q. Fu, L.N. Zhu, D.S. She, H.D. Wang, J. Liang, W. Weng and C.B. Wang, Corrosion Behavior of HVOF Sprayed WC-10Co4Cr Coatings in Simulated Seawater Drilling Fluid Under the High Pressure, Eng. Fail. Anal., 2020, 109, p 104338.
B. Yin, H.D. Zhou, D.L. Yi, J.M. Chen and F.Y. Yan, Microsliding Wear Behaviour of HVOF Sprayed Conventional and Nanostructured WC-12Co Coatings at Elevated Temperatures, Surf. Eng., 2010, 26(6), p 469–477.
M.M. El Rayes, H.S. Abdo and K.A. Khalil, Erosion-Corrosion of Cermet Coating, Int. J. Electrochem. Sci., 2013, 8(1), p 1117–1137.
F. Ghadami and A.S.R. Aghdam, Improvement of High Velocity Oxy-Fuel Spray Coatings by Thermal Post-Treatments: A Critical Review, Thin Solid Films, 2019, 678, p 42–52.
G. Straffelini and M. Federici, HVOF Cermet Coatings to Improve Sliding Wear Resistance in Engineering Systems, Coatings, 2020, 10, p 886.
S.Y. Park, M.C. Kim and C.G. Park, Mechanical Properties and Microstructure Evolution of the Nano WC-Co Coatings Fabricated by Detonation Gun Spraying with Post Heat Treatment, Mat. Sci. Eng. A-Struct., 2007, 449, p 894–897.
E. Huttunen-Saarivirta, V. Heino, E. Isotandon, L. Kilpi and H. Ronkainen, Tribocorrosion Behaviour of Thermally Sprayed Cermet Coatings in Paper Machine Environment, Tribol. Int., 2020, 142, p 106006.
J.Z. Shi, Y. Ge and D.J. Kong, Microstructure, dry Sliding Friction Performances and Wear Mechanism of Laser Cladded WC-10Co4Cr Coating with Different Al2O3 Mass Fractions, Surf. Coat. Technol., 2021, 406, p 126749.
S. Hong, Y.P. Wu, J.H. Wu, W. Zheng, Y.Q. Zhang, J.B. Cheng, J.H. Li and J.R. Lin, Effect of Flow Velocity on Cavitation Erosion Behavior of HVOF Sprayed WC-10Ni and WC-20Cr3C2-7Ni Coatings, Int. J. Refract. Met. Hard Mater., 2020, 92, p 105330.
X.B. Liu, J.J. Kang, W. Yue, G.Z. Ma, Z.Q. Fu, L.N. Zhu, D.S. She, J. Liang, W. Weng, H.D. Wang and C.B. Wang, Cavitation Erosion Behavior of HVOF Sprayed WC-10Co4Cr Cermet Coatings in Simulated Sea Water, Ocean Eng., 2019, 190, p 106449.
H.J.C. Voorwald, R.C. Souza, W.L. Pigatin and M.O.H. Cioffi, Evaluation of WC-17Co and WC-10Co-4Cr Thermal Spray Coatings by HVOF on the Fatigue and Corrosion Strength of AISI 4340 Steel, Surf. Coat. Technol., 2005, 190(2–3), p 155–164.
T. Varis, T. Suhonen, J. Laakso, M. Jokipii and P. Vuoristo, Evaluation of Residual Stresses and their Influence on Cavitation Erosion Resistance of High Kinetic HVOF and HVAF-Sprayed WC-CoCr Coatings, J. Therm. Spray Technol., 2020, 29(6), p 1365–1381.
J.E. Cho, S.Y. Hwang and K.Y. Kim, Corrosion Behavior of Thermal Sprayed WC Cermet Coatings Having Various Metallic Binders in Strong Acidic Environment, Surf. Coat. Technol., 2006, 200, p 2653–2662.
M. Barletta, G. Bolelli, B. Bonferroni and L. Lusvarghi, Wear and Corrosion Behavior of HVOF-Sprayed WC-CoCr Coatings on Al Alloys, J. Therm. Spray Technol., 2010, 19(1–2), p 358–367.
X.Y. Cui, C.B. Wang, J.J. Kang, W. Yue, Z.Q. Fu and L.N. Zhu, Influence of the Corrosion of Saturated Saltwater Drilling Fluid on the Tribological Behavior of HVOF WC-10Co4Cr Coatings, Eng. Fail. Anal., 2017, 71, p 195–203.
V.A.D. Souza and A. Neville, Corrosion and Synergy in a WC-Co-Cr HVOF Thermal Spray Coating-Understanding their Role in Erosion-Corrosion Degradation, Wear, 2005, 259(1–6), p 171–180.
P.B. Mi, T. Wang and F.X. Ye, Influences of the Compositions and Mechanical Properties of HVOF Sprayed Bimodal WC-Co Coating on its High Temperature Wear Performance, Int. J. Refract. Met. Hard Mat., 2017, 69, p 158–163.
M.R. Thakare, J.A. Wharton, R.J.K. Wood and C. Menger, Exposure Effects of Strong Alkaline Conditions on the Microscale Abrasion–Corrosion of D-Gun Sprayed WC-10Co-4Cr Coating, Tribol. Int., 2008, 41, p 629–639.
J.A. Picas, E. Ruperez, M. Punset and A. Forn, Influence of HVOF Spraying Parameters on the Corrosion Resistance of WC–CoCr Coatings in Strong Acidic Environment, Surf. Coat. Technol., 2013, 225, p 47–57.
P.H. Shipway and L. Howell, Microscale Abrasion-Corrosion Behaviour of WC-Co Hardmetals and HVOF Sprayed Coatings, Wear, 2005, 258, p 303–312.
A. Lekatou, D. Zois, A.E. Karantzalis and D. Grimanelis, Electrochemical Behaviour of Cermet Coatings with a Bond Coat on Al7075: Pseudopassivity, Localized Corrosion and Galvanic Effect Considerations in a Saline Environment, Corros. Sci., 2010, 52, p 2616–2635.
S. Hong, Y.P. Wu, B. Wang, J.F. Zhang, Y. Zheng and L. Qiao, The Effect of Temperature on the Dry Sliding Wear Behavior of HVOF Sprayed Nanostructured WC-CoCr Coatings, Ceram. Int., 2017, 43(1), p 458–462.
G. Bolelli, L.M. Berger, T. Borner, H. Koivuluoto, L. Lusvarghi, C. Lyphout, N. Markocsan, V. Matikainen, P. Nylen, P. Sassatelli, R. Trache and P. Vuoristo, Tribology of HVOF- and HVAF-Sprayed WC-10Co4Cr Hardmetal Coatings: A Comparative Assessment, Surf. Coat. Technol., 2015, 265, p 125–144.
Acknowledgments
This project is supported by the National Natural Science Foundation of China (Grant No. 52175196), the Pre-Research Program in National 14th Five-Year Plan (Grant No. 61409230614), the Tribology Science Fund of State Key Laboratory of Tribology (Grant No. SKLTKF19B12), the Fundamental Research Funds for Central Universities (Grant Number 2652019069).
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Zhou, Yk., Kang, Jj., Yue, W. et al. Wet Sliding Wear of HVOF-Sprayed WC-10Co4Cr Coatings in Simulated Seawater Drilling Fluid. J Therm Spray Tech 30, 2174–2186 (2021). https://doi.org/10.1007/s11666-021-01287-8
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DOI: https://doi.org/10.1007/s11666-021-01287-8