Skip to main content

Advertisement

Log in

Influence of Feedstock on the Microstructure of Sm2Zr2O7 Thermal Barrier Coatings Deposited by Plasma Spraying

  • Peer Reviewed
  • Published:
Journal of Thermal Spray Technology Aims and scope Submit manuscript

Abstract

Four Sm2Zr2O7 (SZO) powders with different morphologies were deposited by atmospheric plasma spraying on superalloy substrates using the same spraying parameters. Both the particle size distribution and microstructure of the powders had an important effect on the coating microstructure. SZO thermal barrier coatings (TBCs) deposited using the powder with a narrow particle size distribution showed a better “molten state” and exhibited a higher average bonding strength compared with the SZO TBCs deposited using the powder with a wide particle size distribution. The dense microstructure of the calcined powder sintered at high temperature and of the powder spheroidized by plasma spraying gun (SF) improved the melting capacity of the powders, and the resulting coatings showed a compact microstructure with unique bimodal structures. Furthermore, the SF SZO TBCs presented an excellent “molten state” with a smooth surface and exhibited a high bonding strength of 29.6 ± 0.15 MPa.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6

Similar content being viewed by others

References

  1. N.P. Padture, M. Gell, and E.H. Jordan, Thermal Barrier Coatings for Gasturbine Engine Applications, Science, 2002, 296, p 279-284

    Article  Google Scholar 

  2. E. Bakan and R. Vaßen, Ceramic Top Coats of Plasma-Sprayed Thermal Barrier Coatings: Materials, Processes, and Properties, J. Therm. Spray Technol., 2017, 26(6), p 992-1010

    Article  CAS  Google Scholar 

  3. C.U. Hardwicke and Y.C. Lau, Advances in Thermal Spray Coatings for Gas Turbines and Energy Generation: A Review, J. Therm. Spray Technol., 2013, 22, p 564-576

    Article  Google Scholar 

  4. W.W. Zhang, G.R. Li, Q. Zhang, and G.J. Yang, Comprehensive Damage Evaluation of Localized Spallation of Thermal Barrier Coatings, J. Adv. Ceram., 2017, 6(3), p 230-239

    Article  CAS  Google Scholar 

  5. R. Vassen, X.Q. Cao, F. Tietz, D. Basu, and D. Stöver, Zirconates as New Material for Thermal Barrier Coatings, J. Am. Ceram. Soc., 2000, 83(8), p 2023-2028

    Article  CAS  Google Scholar 

  6. H. Lehmann, D. Pitzer, G. Pracht, R. Vassen, and D. Stöver, Thermal Conductivity and Thermal Expansion Coefficients of the Lanthanum Rare-Earth-Element Zirconate System, J. Am. Ceram. Soc., 2003, 86(8), p 1338-1344

    Article  CAS  Google Scholar 

  7. N. Nakanishi and T. Shigematsu, Martensitic Transformations in Zirconia Ceramics, Mater. Trans., 1992, 33(3), p 318-323

    Article  CAS  Google Scholar 

  8. X.Q. Cao, R. Vassen, and D. Stoever, Ceramic Materials for Thermal Barrier Coatings, J. Eur. Ceram. Soc., 2004, 24, p 1-10

    Article  CAS  Google Scholar 

  9. S.A. Tsipas, Effect of Dopants on the Phase Stability of Zirconia-Based Plasma Sprayed Thermal Barrier Coatings, J. Eur. Ceram. Soc., 2010, 30, p 61-72

    Article  CAS  Google Scholar 

  10. X.Q. Cao, R. Vassen, W. Jungen, S. Schwartz, F. Tietz, and D. Stover, Thermal Stability of Lanthanum Zirconate Plasma-Sprayed Coating, J. Am. Ceram. Soc., 2001, 84(9), p 2086-2090

    Article  CAS  Google Scholar 

  11. T. Liu, X.T. Luo, X. Chen, G.J. Yang, C.X. Li, and C.J. Li, Morphology and Size Evolution of Interlamellar Two-dimensional Pores in Plasma-Sprayed La2Zr2O7 Coatings During Thermal Exposure at 1300 °C, J. Therm. Spray Technol., 2015, 24(5), p 739-748

    Article  CAS  Google Scholar 

  12. R. Vassen, M.O. Jarligo, T. Steinke, D.E. Mack, and D. Stover, Overview on Advanced Thermal Barrier Coatings, Surf. Coat. Technol., 2010, 205(4), p 938-942

    Article  CAS  Google Scholar 

  13. L.L. Cai, W. Ma, B. Ma, F. Guo, W.D. Chen, H.Y. Dong, and Y.C. Shuang, Air Plasma-Sprayed La2Zr2O7-SrZrO3 Composite Thermal Barrier Coating Subjected to CaO-MgO-Al2O3-SiO2 (CMAS), J. Therm. Spray Technol., 2017, 26(6), p 1076-1083

    Article  CAS  Google Scholar 

  14. Y. Li, C.J. Li, G.J. Yang, and C.X. Li, Relation Between Microstructure and Thermal Conductivity of Plasma-Sprayed 8YSZ Coating, Int. J. Mod. Phys. B, 2010, 24, p 3017-3022

    Article  CAS  Google Scholar 

  15. Q.B. Fan, F. Zhang, F.C. Wang, and L. Wang, Molecular Dynamics Calculation of Thermal Expansion Coefficient of a Series of Rare-Earth Zirconates, Comput. Mater. Sci., 2009, 46, p 716-719

    Article  CAS  Google Scholar 

  16. A. Sharma, T. Dudykevych, D. Sansom, and R. Subramanian, Increased Reliability of Gas Turbine Components by Robust Coatings Manufacturing, J. Therm. Spray Technol., 2017, 26(6), p 1084-1094

    Article  Google Scholar 

  17. H.X. Wu, Z. Ma, L. Liu, Y.B. Liu, and D.Y. Wang, Thermal Cycling Behavior and Bonding Strength of Single-Ceramic-Layer Sm2Zr2O7, and Double-Ceramic-Layer Sm2Zr2O7 /8YSZ Thermal Barrier Coatings Deposited by Atmospheric Plasma Spraying, Ceram. Int., 2016, 42(11), p 12922-12927

    Article  CAS  Google Scholar 

  18. P. Carpio, R. Moreno, A. Gómez, M.D. Salvador, and E. Sánchez, Role of Suspension Preparation in the Spray Drying Process to Obtain Nano/Submicrostructured YSZ Powders for Atmospheric Plasma Spraying, J. Eur. Ceram. Soc., 2015, 35(1), p 237-247

    Article  CAS  Google Scholar 

  19. A.H. Pakseresht, M.R. Rahimipour, M.R. Vaezi, and M. Salehi, Thermal Plasma Spheroidization and Spray Deposition of Barium Titanate Powder and Characterization of the Plasma Sprayable Powder, Mater. Chem. Phys., 2016, 173, p 395-403

    Article  CAS  Google Scholar 

  20. P. Fauchais, Topical Review: Understanding Plasma Spraying, J. Appl. Phys., 2004, 37(9), p 86-108

    Google Scholar 

  21. L.L. Shaw, D. Goberman, R. Ren, M. Gell, S. Jiang, Y. Wang, T.D. Xiao, and P.R. Strutt, The Dependency of Microstructure and Properties of Nanostructured Coatings on Plasma Spray Conditions, Surf. Coat. Technol., 2000, 130(1), p 1-8

    Article  CAS  Google Scholar 

  22. D.R. Clarke, Materials Selection Guidelines for Low Thermal Conductivity Thermal Barrier Coatings, Surf. Coat. Technol., 2003, 163-164(02), p 67-74

    Article  CAS  Google Scholar 

  23. W.G. Chi, S. Sampath, and H. Wang, Microstructure-Thermal Conductivity Relationships for Plasma-Sprayed Yttria-Stabilized Zirconia Coatings, J. Am. Ceram. Soc., 2008, 91, p 2636-2645

    Article  CAS  Google Scholar 

  24. J.A. Thompson and T.W. Clyne, The Effect of Heat Treatment on the Stiffness of Zirconia Top Coats in Plasma-Sprayed TBCs, Acta Mater., 2001, 49, p 1565-1575

    Article  CAS  Google Scholar 

  25. R.S. Lima, S.E. Kruger, G. Lamouche, and B.R. Marple, Elastic Modulus Measurements via Laser-Ultrasonic and Knoop Indentation Techniques in Thermally Sprayed Coatings, J. Therm. Spray Technol., 2005, 14, p 52-60

    Article  CAS  Google Scholar 

  26. S. Guo and Y. Kagawa, Young’s Moduli of Zirconia Top-Coat and Thermally Grown Oxide in a Plasma-Sprayed Thermal Barrier Coating System, Scripta Mater., 2004, 50, p 1401-1406

    Article  CAS  Google Scholar 

  27. Y. Tan, A. Shyam, W.B. Choi, E. Lara-Curzio, and S. Sampath, Anisotropic Elastic Properties of Thermal Spray Coatings Determined via Resonant Ultrasound Spectroscopy, Acta Mater., 2010, 58, p 5305-5315

    Article  CAS  Google Scholar 

Download references

Acknowledgments

This work was financially supported by the National Natural Science Foundation of China (No. 51772027).

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Ling Liu.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Guo, W., Ma, Z., Liu, L. et al. Influence of Feedstock on the Microstructure of Sm2Zr2O7 Thermal Barrier Coatings Deposited by Plasma Spraying. J Therm Spray Tech 27, 1524–1531 (2018). https://doi.org/10.1007/s11666-018-0803-2

Download citation

  • Received:

  • Revised:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11666-018-0803-2

Keywords

Navigation