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Influence of Powder Morphology and Microstructure on the Cold Spray and Mechanical Properties of Ti6Al4V Coatings

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Abstract

The powder microstructure and morphology has significant influence on the cold sprayability of Ti6Al4V coatings. Here, we compare the cold sprayability and properties of coatings obtained from Ti6Al4V powders of spherical morphology (SM) manufactured using plasma gas atomization and irregular morphology (IM) manufactured using the Armstrong process. Coatings deposited using IM powders had negligible porosity and better properties compared to coatings deposited using SM powders due to higher particle impact velocities, porous surface morphology and more deformable microstructure. To evaluate the cohesive strength, multi-scale indentation was performed and hardness loss parameter was calculated. Coatings deposited using SM powders exhibited poor cohesive strength compared to coatings deposited using IM powders. Images of the residual indents showed de-bonding and sliding of adjacent splats in the coatings deposited using SM powders irrespective of the load. Coatings deposited using IM powders showed no evidence of de-bonding at low loads. At high loads, splat de-bonding was observed resulting in hardness loss despite negligible porosity. Thus, while the powders from Armstrong process lead to a significant improvement in sprayability and coating properties, further optimization of powder and cold spray process will be required as well as consideration of post-annealing treatments to obtain acceptable cohesive strength.

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References

  1. E. Brandl, F. Palm, V. Michailov, B. Viehweger, and C. Leyens, Mechanical Properties of Additive Manufactured Titanium (Ti-6Al-4V) Blocks Deposited by a Solid-State Laser and Wire, Mater. Des., 2011, 32(10), p 4665-4675

    Article  Google Scholar 

  2. E. Brandl, A. Schoberth, and C. Leyens, Morphology, Microstructure, and Hardness of Titanium (Ti-6Al-4V) Blocks Deposited by Wire-Feed Additive Layer Manufacturing (ALM), Mater. Sci. Eng. A, 2012, 532, p 295-307

    Article  Google Scholar 

  3. J. Cizek, O. Kovarik, J. Siegl, K.A. Khor, and I. Dlouhy, Influence of Plasma and Cold Spray Deposited Ti Layers on High-Cycle Fatigue Properties of Ti6Al4V Substrates, Surf. Coatings Technol., 2013, 217, p 23-33

    Article  Google Scholar 

  4. L.E. Murr, S.A. Quinones, S.M. Gaytan, M.I. Lopez, A. Rodela, E.Y. Martinez, D.H. Hernandez, E. Martinez, F. Medina, and R.B. Wicker, Microstructure and Mechanical Behavior of Ti-6Al-4V Produced by Rapid-Layer Manufacturing, for Biomedical Applications, J. Mech. Behav. Biomed. Mater., 2009, 2(1), p 20-32

    Article  Google Scholar 

  5. D.E. Wolfe, T.J. Eden, J.K. Potter, and A.P. Jaroh, Investigation and Characterization of Cr3C2-Based Wear-Resistant Coatings Applied by the Cold Spray Process, J. Therm. Spray Technol., 2006, 15(3), p 400-412

    Article  Google Scholar 

  6. H. Assadi, H. Kreye, F. Gärtner, and T. Klassen, Cold Spraying—A Materials Perspective, Acta Mater., 2016, 116, p 382-407

    Article  Google Scholar 

  7. D. Goldbaum, R.R. Chromik, N. Brodusch, and R. Gauvin, Microstructure and Mechanical Properties of Ti Cold-Spray Splats Determined by Electron Channeling Contrast Imaging and Nanoindentation Mapping, Microsc. Microanal., 2015, 21(3), p 570-581

    Article  Google Scholar 

  8. H. Assadi, F. Gärtner, T. Stoltenhoff, and H. Kreye, Bonding Mechanism in Cold Gas Spraying, Acta Mater., 2003, 51(15), p 4379-4394

    Article  Google Scholar 

  9. A. Moridi, S.M. Hassani-Gangaraj, M. Guagliano, and M. Dao, Cold Spray Coating: Review of Material Systems and Future Perspectives, Surf. Eng., 2014, 30(6), p 369-395

    Article  Google Scholar 

  10. V.K. Champagne, The Cold Spray Materials Deposition Process Fundamentals and Applications, Woodhead Publishing Limited, Cambridge, 2007

    Book  Google Scholar 

  11. A. Papyrin, Cold Spray Technology, Elsevier, New York, 2007

    Google Scholar 

  12. P. Vo, E. Irissou, J.G. Legoux, and S. Yue, Mechanical and Microstructural Characterization of Cold-Sprayed Ti-6Al-4V After Heat Treatment, J. Therm. Spray Technol., 2013, 22(6), p 954-964

    Article  Google Scholar 

  13. T. Schmidt, F. Gärtner, H. Assadi, and H. Kreye, Development of a Generalized Parameter Window for Cold Spray Deposition, Acta Mater., 2006, 54(3), p 729-742

    Article  Google Scholar 

  14. D. Goldbaum, J.M. Shockley, R.R. Chromik, A. Rezaeian, S. Yue, J.G. Legoux, and E. Irissou, The Effect of Deposition Conditions on Adhesion Strength of Ti and Ti6Al4V Cold Spray Splats, J. Therm. Spray Technol., 2012, 21(2), p 288-303

    Article  Google Scholar 

  15. N.W. Khun, A.W.Y. Tan, K.J.W. Bi, and E. Liu, Effects of Working Gas on Wear and Corrosion Resistances of Cold Sprayed Ti-6Al-4V Coatings, Surf. Coat. Technol., 2016, 302, p 1-12

    Article  Google Scholar 

  16. H. Aydin, M. Alomair, W. Wong, and P. Vo, Cold Sprayability of Mixed Commercial Purity Ti Plus Ti6Al4V Metal Powders, J. Therm. Spray Technol., 2017, 26(3), p 360-370

    Article  Google Scholar 

  17. W. Sun, A.W.Y. Tan, I. Marinescu, W.Q. Toh, and E. Liu, Adhesion, Tribological and Corrosion Properties of Cold-Sprayed CoCrMo and Ti6Al4V Coatings on 6061-T651 Al Alloy, Surf. Coatings Technol., 2017, 326, p 291-298

    Article  Google Scholar 

  18. A.W.Y. Tan, W. Sun, Y.P. Phang, M. Dai, I. Marinescu, Z. Dong, and E. Liu, Effects of Traverse Scanning Speed of Spray Nozzle on the Microstructure and Mechanical Properties of Cold-Sprayed Ti6Al4V Coatings, J. Therm. Spray Technol., 2017, 26(7), p 1484-1497

    Article  Google Scholar 

  19. V.S. Bhattiprolu, K.W. Johnson, O.C. Ozdemir, and G.A. Crawford, Influence of Feedstock Powder and Cold Spray Processing Parameters on Microstructure and Mechanical Properties of Ti-6Al-4V Cold Spray Depositions, Surf. Coatings Technol., 2018, 335, p 1-12

    Article  Google Scholar 

  20. D. MacDonald, R. Fernandez, F. Delloro, and B. Jodoin, Cold Spraying of Armstrong Process Titanium Powder for Additive Manufacturing, J. Therm. Spray Technol., 2017, 26(4), p 598-609

    Article  Google Scholar 

  21. M.V. Vidaller, A. List, F. Gaertner, T. Klassen, S. Dosta, and J.M. Guilemany, Single Impact Bonding of Cold Sprayed Ti-6Al-4V Powders on Different Substrates, J. Therm. Spray Technol., 2015, 24(4), p 644-658

    Article  Google Scholar 

  22. X.T. Luo, Y.K. Wei, Y. Wang, and C.J. Li, Microstructure and Mechanical Property of Ti and Ti6Al4V Prepared by an in-Situ Shot Peening Assisted Cold Spraying, Mater. Des., 2015, 85, p 527-533

    Article  Google Scholar 

  23. K. Araci, D. Mangabhai, and K. Akhtar, Production of Titanium by the Armstrong Process®, in Titanium Powder Metall. (2015), pp. 149–162. https://doi.org/10.1016/B978-0-12-800054-0.00009-5

  24. A.M. Birt, V.K. Champagne, R.D. Sisson, and D. Apelian, Microstructural Analysis of Ti-6Al-4V Powder for Cold Gas Dynamic Spray Applications, Adv. Powder Technol., 2015, 26(5), p 1335-1347

    Article  Google Scholar 

  25. Y. Zhang, N. Brodusch, S. Descartes, R.R. Chromik, and R. Gauvin, Microstructure Refinement of Cold-Sprayed Copper Investigated by Electron Channeling Contrast Imaging, Microsc. Microanal., 2014, 20, p 1499-1506

    Article  Google Scholar 

  26. W.C. Oliver and G.M. Pharr, An Improved Technique for Determining Hardness and Elastic Modulus Using Load and Displacement Sensing Indentation Experiments, J. Mater. Res., 1992, 7, p 1564-1583

    Article  Google Scholar 

  27. D. Goldbaum, J. Ajaja, R.R. Chromik, W. Wong, S. Yue, E. Irissou, and J.G. Legoux, Mechanical Behavior of Ti Cold Spray Coatings Determined by a Multi-Scale Indentation Method, Mater. Sci. Eng. A, 2011, 530(1), p 253-265

    Article  Google Scholar 

  28. A.M. Birt, V.K. Champagne, R.D. Sisson, and D. Apelian, Microstructural Analysis of Cold-Sprayed Ti-6Al-4V at the Micro- and Nano-Scale, J. Therm. Spray Technol., 2015, 24(7), p 1277-1288

    Article  Google Scholar 

  29. J.I. Qazi, O.N. Senkov, J. Rahim, A. Genc, and F.H. (Sam) Froes, Phase Transformations in Ti-6Al-4V–xH Alloys, Metall. Mater. Trans. A, 2001, 32A, p 2453-2463

    Article  Google Scholar 

  30. B. Jodoin, L. Ajdelsztajn, E. Sansoucy, A. Zúñiga, P. Richer, and E.J. Lavernia, Effect of Particle Size, Morphology, and Hardness on Cold Gas Dynamic Sprayed Aluminum Alloy Coatings, Surf. Coat. Technol., 2006, 201, p 3422-3429

    Article  Google Scholar 

  31. W.D. Nix and H. Gao, Indentation Size Effects in Crystalline Materials : A Law for Strain Gradient Plasticity, J. Mech. Phys. Solids, 1998, 46(3), p 411-425

    Article  Google Scholar 

  32. I. Sen, S. Roy, and M.F.X. Wagner, Indentation Response and Structure-Property Correlation in a Bimodal Ti-6Al-4V Alloy, Adv. Eng. Mater., 2017, 1700298, p 1-12

    Google Scholar 

  33. G.B. Viswanathan, E. Lee, D.M. Maher, S. Banerjee, and H.L. Fraser, Direct Observations and Analyses of Dislocation Substructures in the α Phase of an Α/β Ti-Alloy Formed by Nanoindentation, Acta Mater., 2005, 53(19), p 5101-5115

    Article  Google Scholar 

  34. T.B. Britton, H. Liang, F.P.E. Dunne, and A.J. Wilkinson, The Effect of Crystal Orientation on the Indentation Response of Commercially Pure Titanium: Experiments and Simulations, Proc. R. Soc. Lond. A Math. Phys. Eng. Sci., 2010, 466, p 695-719

    Article  Google Scholar 

  35. W. Sun, A. Wei, Y. Tan, N.W. Khun, I. Marinescu, and E. Liu, Effect of Substrate Surface Condition on Fatigue Behavior of Cold Sprayed Ti6Al4V Coatings, Surf. Coat. Technol., 2017, 320, p 452-457

    Article  Google Scholar 

  36. C.M. Lewandowski, N. Co-investigator, and C.M. Lewandowski, Powder Metal Technologies and Applications, ASM Int. Mater. Park. OH, 2015, 7, p 2762

    Google Scholar 

  37. W. Wong, P. Vo, E. Irissou, A.N. Ryabinin, J. Legoux, and S. Yue, Effect of Particle Morphology and Size Distribution on Cold-Sprayed Pure Titanium Coatings, J. Therm. Spray Technol., 2013, 22, p 1140-1153

    Article  Google Scholar 

  38. M. Winnicki, A. Małachowska, G. Dudzik, M. Rutkowska-Gorczyca, M. Marciniak, K. Abramski, A. Ambroziak, and L. Pawłowski, Numerical and Experimental Analysis of Copper Particles Velocity in Low-Pressure Cold Spraying Process, Surf. Coatings Technol., 2015, 268, p 230-240

    Article  Google Scholar 

  39. D. Lioma, N. Sacks, and I. Botef, Cold Gas Dynamic Spraying of WC–Ni Cemented Carbide Coatings, Int. J. Refract. Met. Hard Mater., 2015, 49, p 365-373

    Article  Google Scholar 

  40. S. Yin, E.J. Ekoi, T.L. Lupton, and P. Denis, Cold Spraying of WC-Co-Ni Coatings Using Porous WC-17Co Powders: Formation Mechanism, Microstructure Characterization and Tribological Performance, Mater. Des., 2017, 126, p 305-313

    Article  Google Scholar 

  41. P.H. Gao, Y.G. Li, C.J. Li, G.J. Yang, and C.X. Li, Influence of Powder Porous Structure on the Deposition Behavior of Cold-Sprayed WC-12Co Coatings, J. Therm. Spray Technol., 2008, 17(5–6), p 742-749

    Article  Google Scholar 

  42. K.H. Kim, M. Watanabe, J. Kawakita, and S. Kuroda, Grain Refinement in a Single Titanium Powder Particle Impacted at High Velocity, Scr. Mater., 2008, 59(7), p 768-771

    Article  Google Scholar 

  43. D. Goldbaum, Micromechanical Testing of Cold Sprayed Ti Splats nd Coatings, McGill University, Montreal, 2012

    Google Scholar 

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Acknowledgments

The authors are thankful for the technical assistance from Jean-Francois Alarie, Dina Goldbaum and Maniya Aghasibeig. The authors gratefully acknowledge the contributions of Rene Cooper from Cristal Metals for providing the irregular Ti6Al4V powders.

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Correspondence to Richard R. Chromik.

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Munagala, V.N.V., Akinyi, V., Vo, P. et al. Influence of Powder Morphology and Microstructure on the Cold Spray and Mechanical Properties of Ti6Al4V Coatings. J Therm Spray Tech 27, 827–842 (2018). https://doi.org/10.1007/s11666-018-0729-8

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  • DOI: https://doi.org/10.1007/s11666-018-0729-8

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