Abstract
The powder microstructure and morphology has significant influence on the cold sprayability of Ti6Al4V coatings. Here, we compare the cold sprayability and properties of coatings obtained from Ti6Al4V powders of spherical morphology (SM) manufactured using plasma gas atomization and irregular morphology (IM) manufactured using the Armstrong process. Coatings deposited using IM powders had negligible porosity and better properties compared to coatings deposited using SM powders due to higher particle impact velocities, porous surface morphology and more deformable microstructure. To evaluate the cohesive strength, multi-scale indentation was performed and hardness loss parameter was calculated. Coatings deposited using SM powders exhibited poor cohesive strength compared to coatings deposited using IM powders. Images of the residual indents showed de-bonding and sliding of adjacent splats in the coatings deposited using SM powders irrespective of the load. Coatings deposited using IM powders showed no evidence of de-bonding at low loads. At high loads, splat de-bonding was observed resulting in hardness loss despite negligible porosity. Thus, while the powders from Armstrong process lead to a significant improvement in sprayability and coating properties, further optimization of powder and cold spray process will be required as well as consideration of post-annealing treatments to obtain acceptable cohesive strength.
Similar content being viewed by others
References
E. Brandl, F. Palm, V. Michailov, B. Viehweger, and C. Leyens, Mechanical Properties of Additive Manufactured Titanium (Ti-6Al-4V) Blocks Deposited by a Solid-State Laser and Wire, Mater. Des., 2011, 32(10), p 4665-4675
E. Brandl, A. Schoberth, and C. Leyens, Morphology, Microstructure, and Hardness of Titanium (Ti-6Al-4V) Blocks Deposited by Wire-Feed Additive Layer Manufacturing (ALM), Mater. Sci. Eng. A, 2012, 532, p 295-307
J. Cizek, O. Kovarik, J. Siegl, K.A. Khor, and I. Dlouhy, Influence of Plasma and Cold Spray Deposited Ti Layers on High-Cycle Fatigue Properties of Ti6Al4V Substrates, Surf. Coatings Technol., 2013, 217, p 23-33
L.E. Murr, S.A. Quinones, S.M. Gaytan, M.I. Lopez, A. Rodela, E.Y. Martinez, D.H. Hernandez, E. Martinez, F. Medina, and R.B. Wicker, Microstructure and Mechanical Behavior of Ti-6Al-4V Produced by Rapid-Layer Manufacturing, for Biomedical Applications, J. Mech. Behav. Biomed. Mater., 2009, 2(1), p 20-32
D.E. Wolfe, T.J. Eden, J.K. Potter, and A.P. Jaroh, Investigation and Characterization of Cr3C2-Based Wear-Resistant Coatings Applied by the Cold Spray Process, J. Therm. Spray Technol., 2006, 15(3), p 400-412
H. Assadi, H. Kreye, F. Gärtner, and T. Klassen, Cold Spraying—A Materials Perspective, Acta Mater., 2016, 116, p 382-407
D. Goldbaum, R.R. Chromik, N. Brodusch, and R. Gauvin, Microstructure and Mechanical Properties of Ti Cold-Spray Splats Determined by Electron Channeling Contrast Imaging and Nanoindentation Mapping, Microsc. Microanal., 2015, 21(3), p 570-581
H. Assadi, F. Gärtner, T. Stoltenhoff, and H. Kreye, Bonding Mechanism in Cold Gas Spraying, Acta Mater., 2003, 51(15), p 4379-4394
A. Moridi, S.M. Hassani-Gangaraj, M. Guagliano, and M. Dao, Cold Spray Coating: Review of Material Systems and Future Perspectives, Surf. Eng., 2014, 30(6), p 369-395
V.K. Champagne, The Cold Spray Materials Deposition Process Fundamentals and Applications, Woodhead Publishing Limited, Cambridge, 2007
A. Papyrin, Cold Spray Technology, Elsevier, New York, 2007
P. Vo, E. Irissou, J.G. Legoux, and S. Yue, Mechanical and Microstructural Characterization of Cold-Sprayed Ti-6Al-4V After Heat Treatment, J. Therm. Spray Technol., 2013, 22(6), p 954-964
T. Schmidt, F. Gärtner, H. Assadi, and H. Kreye, Development of a Generalized Parameter Window for Cold Spray Deposition, Acta Mater., 2006, 54(3), p 729-742
D. Goldbaum, J.M. Shockley, R.R. Chromik, A. Rezaeian, S. Yue, J.G. Legoux, and E. Irissou, The Effect of Deposition Conditions on Adhesion Strength of Ti and Ti6Al4V Cold Spray Splats, J. Therm. Spray Technol., 2012, 21(2), p 288-303
N.W. Khun, A.W.Y. Tan, K.J.W. Bi, and E. Liu, Effects of Working Gas on Wear and Corrosion Resistances of Cold Sprayed Ti-6Al-4V Coatings, Surf. Coat. Technol., 2016, 302, p 1-12
H. Aydin, M. Alomair, W. Wong, and P. Vo, Cold Sprayability of Mixed Commercial Purity Ti Plus Ti6Al4V Metal Powders, J. Therm. Spray Technol., 2017, 26(3), p 360-370
W. Sun, A.W.Y. Tan, I. Marinescu, W.Q. Toh, and E. Liu, Adhesion, Tribological and Corrosion Properties of Cold-Sprayed CoCrMo and Ti6Al4V Coatings on 6061-T651 Al Alloy, Surf. Coatings Technol., 2017, 326, p 291-298
A.W.Y. Tan, W. Sun, Y.P. Phang, M. Dai, I. Marinescu, Z. Dong, and E. Liu, Effects of Traverse Scanning Speed of Spray Nozzle on the Microstructure and Mechanical Properties of Cold-Sprayed Ti6Al4V Coatings, J. Therm. Spray Technol., 2017, 26(7), p 1484-1497
V.S. Bhattiprolu, K.W. Johnson, O.C. Ozdemir, and G.A. Crawford, Influence of Feedstock Powder and Cold Spray Processing Parameters on Microstructure and Mechanical Properties of Ti-6Al-4V Cold Spray Depositions, Surf. Coatings Technol., 2018, 335, p 1-12
D. MacDonald, R. Fernandez, F. Delloro, and B. Jodoin, Cold Spraying of Armstrong Process Titanium Powder for Additive Manufacturing, J. Therm. Spray Technol., 2017, 26(4), p 598-609
M.V. Vidaller, A. List, F. Gaertner, T. Klassen, S. Dosta, and J.M. Guilemany, Single Impact Bonding of Cold Sprayed Ti-6Al-4V Powders on Different Substrates, J. Therm. Spray Technol., 2015, 24(4), p 644-658
X.T. Luo, Y.K. Wei, Y. Wang, and C.J. Li, Microstructure and Mechanical Property of Ti and Ti6Al4V Prepared by an in-Situ Shot Peening Assisted Cold Spraying, Mater. Des., 2015, 85, p 527-533
K. Araci, D. Mangabhai, and K. Akhtar, Production of Titanium by the Armstrong Process®, in Titanium Powder Metall. (2015), pp. 149–162. https://doi.org/10.1016/B978-0-12-800054-0.00009-5
A.M. Birt, V.K. Champagne, R.D. Sisson, and D. Apelian, Microstructural Analysis of Ti-6Al-4V Powder for Cold Gas Dynamic Spray Applications, Adv. Powder Technol., 2015, 26(5), p 1335-1347
Y. Zhang, N. Brodusch, S. Descartes, R.R. Chromik, and R. Gauvin, Microstructure Refinement of Cold-Sprayed Copper Investigated by Electron Channeling Contrast Imaging, Microsc. Microanal., 2014, 20, p 1499-1506
W.C. Oliver and G.M. Pharr, An Improved Technique for Determining Hardness and Elastic Modulus Using Load and Displacement Sensing Indentation Experiments, J. Mater. Res., 1992, 7, p 1564-1583
D. Goldbaum, J. Ajaja, R.R. Chromik, W. Wong, S. Yue, E. Irissou, and J.G. Legoux, Mechanical Behavior of Ti Cold Spray Coatings Determined by a Multi-Scale Indentation Method, Mater. Sci. Eng. A, 2011, 530(1), p 253-265
A.M. Birt, V.K. Champagne, R.D. Sisson, and D. Apelian, Microstructural Analysis of Cold-Sprayed Ti-6Al-4V at the Micro- and Nano-Scale, J. Therm. Spray Technol., 2015, 24(7), p 1277-1288
J.I. Qazi, O.N. Senkov, J. Rahim, A. Genc, and F.H. (Sam) Froes, Phase Transformations in Ti-6Al-4V–xH Alloys, Metall. Mater. Trans. A, 2001, 32A, p 2453-2463
B. Jodoin, L. Ajdelsztajn, E. Sansoucy, A. Zúñiga, P. Richer, and E.J. Lavernia, Effect of Particle Size, Morphology, and Hardness on Cold Gas Dynamic Sprayed Aluminum Alloy Coatings, Surf. Coat. Technol., 2006, 201, p 3422-3429
W.D. Nix and H. Gao, Indentation Size Effects in Crystalline Materials : A Law for Strain Gradient Plasticity, J. Mech. Phys. Solids, 1998, 46(3), p 411-425
I. Sen, S. Roy, and M.F.X. Wagner, Indentation Response and Structure-Property Correlation in a Bimodal Ti-6Al-4V Alloy, Adv. Eng. Mater., 2017, 1700298, p 1-12
G.B. Viswanathan, E. Lee, D.M. Maher, S. Banerjee, and H.L. Fraser, Direct Observations and Analyses of Dislocation Substructures in the α Phase of an Α/β Ti-Alloy Formed by Nanoindentation, Acta Mater., 2005, 53(19), p 5101-5115
T.B. Britton, H. Liang, F.P.E. Dunne, and A.J. Wilkinson, The Effect of Crystal Orientation on the Indentation Response of Commercially Pure Titanium: Experiments and Simulations, Proc. R. Soc. Lond. A Math. Phys. Eng. Sci., 2010, 466, p 695-719
W. Sun, A. Wei, Y. Tan, N.W. Khun, I. Marinescu, and E. Liu, Effect of Substrate Surface Condition on Fatigue Behavior of Cold Sprayed Ti6Al4V Coatings, Surf. Coat. Technol., 2017, 320, p 452-457
C.M. Lewandowski, N. Co-investigator, and C.M. Lewandowski, Powder Metal Technologies and Applications, ASM Int. Mater. Park. OH, 2015, 7, p 2762
W. Wong, P. Vo, E. Irissou, A.N. Ryabinin, J. Legoux, and S. Yue, Effect of Particle Morphology and Size Distribution on Cold-Sprayed Pure Titanium Coatings, J. Therm. Spray Technol., 2013, 22, p 1140-1153
M. Winnicki, A. Małachowska, G. Dudzik, M. Rutkowska-Gorczyca, M. Marciniak, K. Abramski, A. Ambroziak, and L. Pawłowski, Numerical and Experimental Analysis of Copper Particles Velocity in Low-Pressure Cold Spraying Process, Surf. Coatings Technol., 2015, 268, p 230-240
D. Lioma, N. Sacks, and I. Botef, Cold Gas Dynamic Spraying of WC–Ni Cemented Carbide Coatings, Int. J. Refract. Met. Hard Mater., 2015, 49, p 365-373
S. Yin, E.J. Ekoi, T.L. Lupton, and P. Denis, Cold Spraying of WC-Co-Ni Coatings Using Porous WC-17Co Powders: Formation Mechanism, Microstructure Characterization and Tribological Performance, Mater. Des., 2017, 126, p 305-313
P.H. Gao, Y.G. Li, C.J. Li, G.J. Yang, and C.X. Li, Influence of Powder Porous Structure on the Deposition Behavior of Cold-Sprayed WC-12Co Coatings, J. Therm. Spray Technol., 2008, 17(5–6), p 742-749
K.H. Kim, M. Watanabe, J. Kawakita, and S. Kuroda, Grain Refinement in a Single Titanium Powder Particle Impacted at High Velocity, Scr. Mater., 2008, 59(7), p 768-771
D. Goldbaum, Micromechanical Testing of Cold Sprayed Ti Splats nd Coatings, McGill University, Montreal, 2012
Acknowledgments
The authors are thankful for the technical assistance from Jean-Francois Alarie, Dina Goldbaum and Maniya Aghasibeig. The authors gratefully acknowledge the contributions of Rene Cooper from Cristal Metals for providing the irregular Ti6Al4V powders.
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Munagala, V.N.V., Akinyi, V., Vo, P. et al. Influence of Powder Morphology and Microstructure on the Cold Spray and Mechanical Properties of Ti6Al4V Coatings. J Therm Spray Tech 27, 827–842 (2018). https://doi.org/10.1007/s11666-018-0729-8
Received:
Revised:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s11666-018-0729-8