Abstract
In this study, we develop a large tubular solid oxide fuel cells design with several cells in series on a porous cermet support, which has many characteristics such as self-sealing, low Ohmic loss, high strength, and good thermal expansion coefficient matching. Here, we investigate aspects of the cell design, manufacture, performance, and application. Firstly, the cell length and number of cells in series are optimized by theoretical analysis. Then, thermal spraying is applied as a cost-effective method to prepare all the cell components. Finally, the performance of different types of cells and two types of stacks is characterized. The maximum output power of one tube, which had 20 cells in series, reaches 31 and 40.5 W at 800 and 900 °C, respectively. Moreover, the output power of a stack assembled with 56 tubes, each with ten cells in series, reaches 800 W at 830 °C. The excellent single tube and cell stack performance suggest that thermally sprayed tubular SOFCs have significant potential for commercialized application.
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References
S. Singhal, High-Temperature Solid Oxide Fuel Cells: Fundamentals, Design and Applications: Fundamentals, Elsevier, Design and Applications, 2003
S. Basu and B.M. Cetegen, Modeling of Liquid Ceramic Precursor Droplets in a High Velocity Oxy-Fuel Flame Jet, Acta Mater., 2008, 56(12), p 2750-2759
Y. Yoo, Y. Wang, X. Deng, D. Singh, and J.-G. Legoux, Metal Supported Tubular Solid Oxide Fuel Cells Fabricated by Suspension Plasma Spray and Suspension High Velocity Oxy-Fuel Spray, J. Power Sources, 2012, 215, p 307-311
R.A. George, Status of Tubular SOFC Field Unit Demonstrations, J. Power Sources, 2000, 86(1-2), p 134-139
S.C. Singhal, Advances in Solid Oxide Fuel Cell Technology, Solid State Ion., 2000, 135(1-4), p 305-313
B. Borglum and H. Ghezel-Ayagh, Development of Solid Oxide Fuel Cells at Versa Power Systems and Fuel Cell Energy, ECS Trans., 2015, 68(1), p 89-94
L. Blum, P. Batfalsky, Q. Fang, L.G.J. de Haart, J. Malzbender, N. Margaritis, N.H. Menzler, and R. Peters, Solid Oxide Fuel Cell, Stack and System Development Status at Forschungszentrum Jülich, ECS Trans., 2015, 68(1), p 157-169
H. Tsukuda, A. Notomi, and N. Histatome, Application of Plasma Spraying to Tubular-Type Solid Oxide Fuel Cells Production, J. Therm. Spray Technol., 2000, 9(3), p 364-368
K. Miyamoto, M. Mihara, H. Oozawa, K. Hiwatashi, K. Tomida, M. Nishiura, H. Kishizawa, R. Mori, and Y. Kobayashi, Recent Progress of SOFC Combined Cycle System with Segmented-in-Series Tubular Type Cell Stack at MHPS, ECS Trans., 2015, 68(1), p 51-58
L. Yang, S.Z. Wang, K. Blinn, M.F. Liu, Z. Liu, Z. Cheng, and M.L. Liu, Enhanced Sulfur and Coking Tolerance of a Mixed Ion Conductor for SOFCs: BaZr0.1Ce0.7Y0.2−x Yb x O3−δ, Science, 2009, 326, p 126-129
L. Yang, Y. Choi, W. Qin, H. Chen, K. Blinn, M. Liu, P. Liu, J. Bai, T.A. Tyson, and M. Liu, Promotion of Water-Mediated Carbon Removal by Nanostructured Barium Oxide/Nickel Interfaces in Solid Oxide Fuel Cells, Nat. Commun., 2011, 2, p 357
D. Ding, X. Li, S. Lai, K. Gerdes, and M. Liu, Enhancing SOFC Cathode Performance by Surface Modification Through Infiltration, Energy Environ. Sci., 2014, 7, p 552-575
E.D. Wachsman and K.T. Lee, Lowering the Temperature of Solid Oxide Fuel Cells, Science, 2011, 334, p 935-939
E.D. Wachsman, C.A. Marlowe, and K.T. Lee, Role of Solid Oxide Fuel Cells in a Balanced Energy Strategy, Energy Environ. Sci., 2012, 5(2), p 5498-5509
T. Hibino, A. Hashimoto, T. Inoue, J.I. Tokuno, S.I. Yoshida, and M. Sano, A Low-Operating-Temperature Solid Oxide Fuel Cell in Hydrocarbon-Air Mixtures, Science, 2000, 288(5473), p 2031-2033
C. Ding and T. Hashida, High Performance Anode-Supported Solid Oxide Fuel Cell Based on Thin-Film Electrolyte and Nanostructured Cathode, Energy Environ. Sci., 2010, 3, p 1729-1731
R.A. George and N.F. Bessette, Reducing the Manufacturing Cost of Tubular Solid Oxide Fuel Cell Technology, J. Power Sources, 1998, 71(1-2), p 131-137
R. Hansch, M.R.R. Chowdhury, and N.H. Menzler, Screen Printing of Sol-Gel-Derived Electrolytes for Solid Oxide Fuel Cell (SOFC) Application, Ceram. Int., 2009, 35(2), p 803-811
C. Pijolat, Screen-Printing for the Fabrication of Solid Oxide Fuel Cells (SOFC), M. Prudenziati and J. Hormadaly, Ed., Printed Filmsed, Woodhead Publishing Limited, Oxford, 2012, p 469-495
M. Letilly, O. Joubert, M.T. Caldes, and A.L.G. La Salle, Tape Casting Fabrication, Co-sintering and Optimisation of Anode/electrolyte Assemblies for SOFC Based on BIT07-Ni/BIT07, Int. J. Hydrogen Energy, 2012, 37(5), p 4346-4355
C. Suciu, H. Tikkanen, I. Wærnhus, F. Goga, and E. Dorolti, Water-Based Tape-Casting of SOFC Composite 3YSZ/8YSZ Electrolytes and Ionic Conductivity of Their Pellets, Ceram. Int., 2012, 38(1), p 357-365
J.-H. Myung, H.J. Ko, C.H. Im, J. Moon, and S.-H. Hyun, Development of Solid Oxide Fuel Cells (SOFCs) by Tape-Casting and Single-Step Co-firing of Monolithic Laminates, Int. J. Hydrogen Energy, 2014, 39(5), p 2313-2319
H. Tikkanen, C. Suciu, I. Wærnhus, and A.C. Hoffmann, Dip-Coating of 8YSZ Nanopowder for SOFC Applications, Ceram. Int., 2011, 37(7), p 2869-2877
Z. Zhou, D. Han, H. Wu, and S. Wang, Fabrication of Planar-type SOFC Single Cells by a Novel Vacuum Dip-Coating Method and Co-firing/Infiltration Techniques, Int. J. Hydrogen Energy, 2014, 39(5), p 2274-2278
W. Sun, N. Zhang, Y. Mao, and K. Sun, Preparation of Dual-Pore Anode Supported Sc2O3-Stabilized-ZrO2 Electrolyte Planar Solid Oxide Fuel Cell by Phase-Inversion and Dip-Coating, J. Power Sources, 2012, 218, p 352-356
T. Talebi, M. Haji, and B. Raissi, Effect of Sintering Temperature on the Microstructure, Roughness and Electrochemical Impedance of Electrophoretically Deposited YSZ Electrolyte for SOFCs, Int. J. Hydrogen Energy, 2010, 35(17), p 9420-9426
R. Kiebach, W.-W. Zhang, W. Zhang, M. Chen, K. Norrman, H.-J. Wang, J.R. Bowen, R. Barfod, and P.V. Hendriksen, Stability of La0.6Sr0.4Co0.2Fe0.8O3/Ce0.9Gd0.1O2 Cathodes During Sintering and Solid Oxide Fuel Cell Operation, J. Power Sources, 2015, 283, p 151-161
S.J. Skinner, Recent Advances in Perovskite-Type Materials for SOFC Cathodes, Fuel Cells Bull., 2001, 4(33), p 6-12
M. Koi, S. Yamashita, and Y. Matsuzaki, Development of Segmented-in-series Cell-Stacks with Flat-Tubular Substrates, ECS Trans., 2007, 7, p 235-243
H. Yoshida, T. Seyama, T. Sobue, and S. Yamashita, Development of Residential SOFC CHP System with Flatten Tubular Segmented-in-Series Cells Stack, ECS Trans., 2011, 35, p 97-103
C.-X. Li, L.-L. Yun, Y. Zhang, C.-J. Li, and L.-J. Guo, Microstructure, Performance and Stability of Ni/Al2O3 Cermet-Supported SOFC Operating with Coal-Based Syngas Produced Using Supercritical Water, Int. J. Hydrogen Energy, 2012, 37(17), p 13001-13006
G. Tadashi, K. Yoshinori, A. Yoshimasa, H. Nagao, K. Tatsuo, and K. Kenichiro, Development of 200 kW Class SOFC Combined Cycle System and Future View, Technical Review, vol. 45, Mitsubishi Heavy Industries, Ltd, Tokyo, 2008, p 33-36
K. Fujita, T. Seyama, T. Sobue, and Y. Matsuzaki, Development of Segmented-in-Series-Type Solid Oxide Fuel Cells for Residential Applications, Energy Procedia, 2012, 28, p 153-161
T.S. Lai and S.A. Barnett, Design Considerations for Segmented-in-Series Fuel Cells, J. Power Sources, 2005, 147(1-2), p 85-94
K. Tomida, N. Hisatome, T. Kabata, H. Tsukuda, and Y. Yamazaki, Structural Modification of Segmented-in-Series Tubular SOFCs Using Performance Simulation and the Effect of (Sm, Ce)O2 Cathode Interlayer on the Generation Characteristics Under Pressurization, Electrochemistry, 2009, 77(10), p 865-875
D. Cui and M. Cheng, Design for Segmented-in-Series Solid Oxide Fuel Cell Through Mathematical Modeling, J. Power Sources, 2010, 195(5), p 1435-1440
R. Hui, Z. Wang, O. Kesler, L. Rose, J. Jankovic, S. Yick, R. Maric, and D. Ghosh, Thermal Plasma Spraying for SOFCs: Applications, Potential Advantages, and Challenges, J. Power Sources, 2007, 170(2), p 308-323
M.R. Pillai, D. Gostovic, I. Kim, and S.A. Barnett, Short-Period Segmented-in-Series Solid Oxide Fuel Cells on Flattened Tube Supports, J. Power Sources, 2007, 163(2), p 960-965
S.-L. Zhang, C.-X. Li, C.-J. Li, and G.-J. Yang, Microstructure and Properties of Porous Ni50Cr50-Al2O3 Cermet Support for Solid Oxide Fuel Cells, J. Therm. Spray Technol., 2012, 22(2-3), p 158-165
C.-J. Li, C.-X. Li, and X.-J. Ning, Performance of YSZ Electrolyte Layer Deposited by Atmospheric Plasma Spraying for Cermet-Supported Tubular SOFC, Vacuum, 2004, 73(3-4), p 699-703
C.-J. Li, X.-J. Ning, and C.-X. Li, Effect of Densification Processes on the Properties of Plasma-Sprayed YSZ Electrolyte Coatings for Solid Oxide Fuel cells, Surf. Coat. Technol., 2005, 190(1), p 60-64
A. Utz, H. Störmer, A. Leonide, A. Weber, and E. Ivers-Tiffée, Degradation and Relaxation Effects of Ni Patterned Anodes in H2-H2O Atmosphere, J. Electrochem. Soc., 2010, 157(6), p B920-B930
D. Ding, B. Liu, Z. Zhu, S. Zhou, and C. Xia, High Reactive Ce0.8Sm0.2O1.9 Powders Via a Carbonate Co-precipitation Method as Electrolytes for Low-Temperature Solid Oxide Fuel Cells, Solid State Ion., 2008, 179(21-26), p 896-899
C. Li, C. Li, Y. Xing, M. Gao, and G. Yang, Influence of YSZ Electrolyte Thickness on the Characteristics of Plasma-Sprayed Cermet Supported Tubular SOFC, Solid State Ion., 2006, 177(19-25), p 2065-2069
C.-J. Li, C.-X. Li, H.-G. Long, Y.-Z. Xing, and G.-J. Yang, Performance of Tubular Solid Oxide Fuel Cell Assembled with Plasma-Sprayed Sc2O3-ZrO2 Electrolyte, Solid State Ion., 2008, 179(27-32), p 1575-1578
C.-X. Li, C.-J. Li, and L.-J. Guo, Performance of a Ni/Al2O3 Cermet-Supported Tubular Solid Oxide Fuel Cell Operating with Biomass-Based Syngas Through Supercritical Water, Int. J. Hydrogen Energy, 2010, 35(7), p 2904-2908
Acknowledgments
The present project was supported by the National High Technology Research and Development Program of China (Grant No. 2007AA05Z135) and National Basic Research Program (Grant No. 2012CB625100). The authors would like to thank Kai Wang, Zhun-Zhun Wang, Liang-Liang Yun, Wen-Bo Chen, Qing-Zhong Zheng, Jia-Feng Xiong, and Hong-Liang Wu for cell design and fabrication work. The authors also would like to thank Dr. Samson Yuxiu Lai and Prof. Meilin Liu from Georgia Institute of Technology for our paper’s polishing and fruitful discussions.
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Zhang, SL., Li, CX., Liu, S. et al. Thermally Sprayed Large Tubular Solid Oxide Fuel Cells and Its Stack: Geometry Optimization, Preparation, and Performance. J Therm Spray Tech 26, 441–455 (2017). https://doi.org/10.1007/s11666-016-0506-5
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DOI: https://doi.org/10.1007/s11666-016-0506-5