Skip to main content
SpringerLink
Log in

Absorption and Decomposition of CO2 by Active Ferrites Prepared by Atmospheric Plasma Spraying

  • Technical Note
  • Published:
Journal of Thermal Spray Technology Aims and scope Submit manuscript

Abstract

Active ferrites, which play an important role in the catalytic decomposition of CO2, have been fabricated by atmospheric plasma spraying to incorporate FeO and anoxic iron oxide [Fe3O4−δ (0 < δ < 1)]. The complexity of phase composition, especially the presence of FeO, gives the resulting powder a greater ability to decompose CO2 when compared to hydrogen-reduced Fe3O4 or Fe2O3 particles. Spraying distance is found to play an important role in modulating the decomposition ability of the powders, while elevated temperatures can also enhance the catalytic decomposition of CO2.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6

Similar content being viewed by others

References

  1. H. Liu, S. Szunerits, W. Xu, and R. Boukherroub, Preparation of Superhydrophobic Coatings on Zinc as Effective Corrosion Barriers, Acs Appl. Mater. Interfaces, 2009, 1(6), p 1150-1153

    Article  Google Scholar 

  2. X.Y. Ling, I.Y. Phang, G.J. Vancso, J. Huskens, and D.N. Reinhoudt, Stable and Transparent Superhydrophobic Nanoparticle Films, Langmuir, 2009, 25(5), p 3260-3263

    Article  Google Scholar 

  3. C.H. Choi, U. Ulmanella, J. Kim, C.M. Ho, and C.J. Kim, Effective Slip and Friction Reduction in Nanograted Superhydrophobic Microchannels, Phys. Fluids, 2006, 18(8), p 087105

    Article  Google Scholar 

  4. T. Ishizaki, Y. Masuda, and M. Sakamoto, Corrosion Resistance and Durability of Superhydrophobic Surface Formed on Magnesium Alloy Coated with Nanostructured Cerium Oxide Film and Fluoroalkylsilane Molecules in Corrosive NaCl Aqueous Solution, Langmuir, 2011, 27(8), p 4780-4788

    Article  Google Scholar 

  5. P. Roach, N.J. Shirtcliffe, and M.I. Newton, Progess in Superhydrophobic Surface Development, Soft Matter., 2008, 4(2), p 224-240

    Article  Google Scholar 

  6. J. Long, M. Zhong, H. Zhang, and P. Fan, Superhydrophilicity to Superhydrophobicity Transition of Picosecond Laser Microstructured Aluminum in Ambient Air, J. Colloid Interface Sci., 2015, 441, p 1-9

    Article  Google Scholar 

  7. J. Long, M. Zhong, P. Fan, D. Gong, and H. Zhang, Wettability Conversion of Ultrafast Laser Structured Copper Surface, J. Laser Appl., 2015, 27(S2), p S29107

    Article  Google Scholar 

  8. Z. Li, Y. Zheng, J. Zhao, and L. Cui, Wettability of Atmospheric Plasma Sprayed Fe, Ni, Cr and Their Mixture Coatings, J. Therm. Spray Technol., 2012, 21(2), p 255-262 (in English)

    Article  Google Scholar 

  9. F. Arena, G. Italiano, K. Barbera, S. Bordiga, G. Bonura, L. Spadaro, and F. Frusteri, Solid-State Interactions, Adsorption Sites and Functionality of Cu-ZnO/ZrO2 Catalysts in the CO2 Hydrogenation to CH3OH, Appl. Catal. A, 2008, 350(1), p 16-23

    Article  Google Scholar 

  10. S. Natesakhawat, J.W. Lekse, J.P. Baltrus, P.R. Ohodnicki, B.H. Howard, X. Deng, and C. Matranga, Active Sites and Structure-Activity Relationships of Copper-Based Catalysts for Carbon Dioxide Hydrogenation to Methanol, ACS Catal., 2012, 2(8), p 1667-1676

    Article  Google Scholar 

  11. T. Kodama, M. Tabata, K. Tominaga, T. Yoshida, and Y. Tamaura, Decomposition of CO2 and CO into Carbon with Active Wüstite Prepared from Zn(II)-Bearing Ferrite, J. Mater. Sci., 1993, 28, p 547-552

    Article  Google Scholar 

  12. Y. Tamaura and M. Tahata, Complete Reduction of Carbon Dioxide to Carbon Using Cation-Excess Magnetite, Nature, 1990, 346(6281), p 255-256

    Article  Google Scholar 

  13. A.A. Farghali, M.H. Khedr, and A.A.A. Khalek, Catalytic Decomposition of Carbondioxide over Freshly Reduced Activated CuFe2O4 Nano-crystals, J. Mater. Process. Technol., 2007, 181(1-3), p 81-87

    Article  Google Scholar 

  14. G. Espie, A. Denoirjean, P. Fauchais, J.C. Labbe, J. Dubsky, O. Schneeweiss, and K. Volenik, In-Flight Oxidation of Iron Particles Sprayed Using Gas and Water Stabilized Plasma Torch, Surf. Coat. Technol., 2005, 195(1), p 17-28

    Article  Google Scholar 

  15. K. Akanuma, K. Nishizawa, T. Kodama, M. Tabata, K. Mimori, T. Yoshida, M. Tsuji, and Y. Tamaura, Carbon Dioxide Decomposition into Carbon with the Rhodium-Bearing Magnetite Activated by H2-Reduction, J. Mater. Sci., 1993, 28, p 547-552

    Article  Google Scholar 

  16. R.K. Mehta, K. Yang, and M. Misra, Mixed Waste Ferrite as a Novel Sorbent for Carbon Dioxide Derived from Flue Gases, J. Mater. Sci., 1996, 31, p 1873-1877

    Article  Google Scholar 

  17. M.H. Khedr, M. Bahgat, M.I. Nasr, and E.K. Sedeek, CO2 Decomposition over Freshly Reduced Nanocrystalline Fe2O3, Colloids Surf A, 2007, 302(1-3), p 517-524

    Article  Google Scholar 

  18. C. Nordhei, K. Mathisen, O. Safonova, W. van Beek, and D.G. Nicholson, Decomposition of Carbon Dioxide at 500 °C over Reduced Iron, Cobalt, Nickel, and Zinc Ferrites: A Combined XANES-XRD Study, J. Phys. Chem. C, 2009, 113(45), p 19568-19577

    Article  Google Scholar 

  19. C.L. Zhang, S. Li, T.H. Wu, and S.Y. Peng, Reduction of Carbon Dioxide into Carbon by the Active Wustite and the Mechanism of the Reaction, Mater. Chem. Phys., 1999, 58(2), p 139-145

    Article  Google Scholar 

  20. J. Zieliński, I. Zglinicka, L. Znak, and Z. Kaszkur, Reduction of Fe2O3 with Hydrogen, Appl. Catal. A, 2010, 381(1-2), p 191-196

    Article  Google Scholar 

Download references

Acknowledgments

The research is sponsored by Research Fund for the Doctoral Program of Higher Education of China (RFDP, No. 20110007110009) and Science Foundation of China University of Petroleum, Beijing.

Author information

Authors and Affiliations

  1. Department of Materials Science and Engineering, China University of Petroleum, Changping, Beijing, 102249, China

    Shaowei Li, Zhida He, Yanjun Zheng & Changfeng Chen

Authors
  1. Shaowei Li
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Zhida He
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Yanjun Zheng
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Changfeng Chen
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Yanjun Zheng.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Li, S., He, Z., Zheng, Y. et al. Absorption and Decomposition of CO2 by Active Ferrites Prepared by Atmospheric Plasma Spraying. J Therm Spray Tech 24, 1574–1578 (2015). https://doi.org/10.1007/s11666-015-0333-0

Download citation

  • Received:

  • Revised:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11666-015-0333-0

Keywords

Search

Navigation