Skip to main content
Log in

Sliding Wear Response of Nanostructured YSZ Suspension Plasma-Sprayed Coating

  • Peer Reviewed
  • Published:
Journal of Thermal Spray Technology Aims and scope Submit manuscript

Abstract

Nanostructured yttria-stabilized zirconia coatings for applications in high-temperature environments can be deposited by suspension plasma spraying (SPS) techniques. The present research has been conducted in order to study the sliding wear response of a SPS ZrO2–8% mol. Y2O3 coating (75 μm in thickness) deposited onto a Haynes 230 substrate, using pin-on-disc tests. Some of the coated samples were subsequently heat-treated for 1 h at 300 and 600 °C. Samples characterization prior and after the wear tests was carried out by SEM, EDS, XRD and optical profilometry techniques. Instrumented indentation was employed to determine elastic modulus and hardness. The results have shown that the as-sprayed and heat-treated samples experienced severe wear (10−13 m3/Nm) and the worst wear performance corresponded to the sample heat treated at 600 °C. Such a behavior could be related to both the structural changes that took place during heat treatment and the nature and level of the residual stresses in the coatings. In general, the morphologies of the wear tracks observed by SEM have shown a smoothing of the surface, brittle fracture, smearing and grain pull-out.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7
Fig. 8
Fig. 9
Fig. 10
Fig. 11

Similar content being viewed by others

References

  1. J.R. Davis, Protective Coatings for Superalloys. ASM Specially Handbook, Heat-Resistance Materials. ASM International Materials Park, OH. 1997, p 335-344

  2. O. Tingaud, R. Etchart-Salas, V. Rat, J.F. Coudert, H. Ageorges, A. Grimaud, A. Denoirjean, P. Fauchais, G. Montavon, N. Caron and S. Alexandre, Suspension Plasma Spraying of Zirconia Coatings: Process and Coating Structure, 18th International Symposium on Plasma Chemistry, Japan, 2007

  3. G. Darut, F. Ben-Ettouil, A. Denoirjean, G. Montavon, H. Ageorges, and P. Fauchais, Dry Sliding Behavior of Sub-Micrometer-Sized Suspension Plasma Sprayed Ceramic Oxide Coatings, J. Therm. Spray Technol., 2010, 19(1–2), p 275-285

    Article  Google Scholar 

  4. S.C. Tjong and H. Chen, Nanocrystalline Materials and Coatings, Mater. Sci. Eng. R, 2004, 45(1-2), p 1-88

    Article  Google Scholar 

  5. Y. Zeng, S.W. Lee, L. Gao, and C.X. Ding, Atmospheric Plasma Sprayed Coatings of Nanostructured Zirconia, J. Eur. Ceram. Soc., 2002, 22(3), p 347-351

    Article  Google Scholar 

  6. L. Pawlowski, Finely Grained Nanometric and Submicrometric Coatings by Thermal Spraying, Surf. Coat. Technol., 2008, 202(18), p 4318-4328

    Article  Google Scholar 

  7. M. Gell, Application Opportunities for Nonostructured Materials and Coatings, Mater. Sci. Eng., 1995, 204(1), p 246-251

    Article  Google Scholar 

  8. P. Fauchais and A. Vardelle, Solution and Suspension Plasma Spraying of Nanostructured Coatings. In H. Salimi Advanced Thermal Spray Applications, Ed. InTech, 2012, Chapter 7

  9. E. Brousse, G. Montavon, P. Fauchais, A. Denoirjean, V. Rat, J.-F.Coudert, and H. Ageorges, Thin and Dense Yttria-Partially Stabilized Zirconia Electrolytes for IT-SOFC Manufactured by Suspension Plasma Spraying, Thermal Spray 2008: Crossing Borders (DVS-ASM), 2008, p 535-540

  10. O. Tingaud, A. Grimaud, A. Denoirjean, G. Montavon, V. Rat, J.-F.Coudert, P. Fauchais, and T. Chartier, Suspension Plasma-Sprayed Alumina Coating Structures: Operating Parameters vs. Coating Architecture, Thermal Spray 2008: Crossing Borders (DVS-ASM), 2008, p 311-316

  11. L. Pawlowski, Suspension and Solution Thermal Spraying Coatings, Surf. Coat. Technol., 2009, 203, p 2807-2829

    Article  Google Scholar 

  12. A. Bacciochini, G. Montavon, J. Llavsky, A. Denoirjean, and P. Fauchais, Porous Architecture of SPS Thick YSZ Coatings at the Nanometer Scale (~50 nm), J. Therm. Spray Technol., 2010, 19(1–2), p 198-206

    Article  Google Scholar 

  13. R. Vert, P. Carles, E. Meillot, E. Laborde, G. Mariaux, and A. Vardelle, Adhesion of Ceramic Coating on Thin and Smooth Metal Substrate: A Novel Approach with a Nanostructured Ceramic Interlayer, J. Therm. Spray Technol., 2012, 21(6), p 1128-1134

    Article  Google Scholar 

  14. G. Darut, H. Ageorges, A. Denoirjean, and P. Fauchais, Tribological Performances of YSZ Composite Coatings Manufactured by Suspension Plasma Spraying, Surf. Coat. Technol., 2013, 217, p 172-180

    Article  Google Scholar 

  15. C. Piconi and G. Maccauro, Zirconia as a Ceramic Biomaterial, Biomaterials, 1999, 20, p 1-25

    Article  Google Scholar 

  16. R. Hannink, P. Kelly, and B. Muddle, Transformation Toughening in Zirconia-Containing Ceramics, J. Am. Ceram. Soc., 2000, 83(3), p 461-487

    Article  Google Scholar 

  17. S. Tao, B. Llang, C. Ding, H. Llao, and C. Coddet, Wear Characteristics of Plasma-Sprayed Nanostructured Yttria Partially Stabilized Zirconia Coatings, J. Therm. Spray Technol., 2004, 14(4), p 518-523

    Article  Google Scholar 

  18. H. Ahn, J. Kim, and D. Lim, Tribological Behavior of Plasma Sprayed Zirconia Coatings, Wear, 1997, 203(204), p 77-87

    Article  Google Scholar 

  19. T.E. Fischer, M.P. Anderson, S. Jahanmir, and R. Salher, Friction and Wear of Tough and Brittle Zirconia in Nitrogen, Air, Water, and Hexadecadene Containing Stearic Acid, Wear, 1988, 124, p 133-148

    Article  Google Scholar 

  20. J.H. Ouyang and S. Sasaki, Unlubricated Friction and Wear Behavior of Low-Pressure Plasma-Sprayed ZrO2 Coating at Elevated Temperatures, Ceram. Int., 2001, 27, p 251-260

    Article  Google Scholar 

  21. A. Erdemir, A Review of the lubrication of ceramics with thin solid films. Friction and Wear of Ceramics, S. Jahanmir, Ed., Marcel Dekker, 1994, p 119-161

  22. J. Ilavsky and J.K. Stalick, Phase Composition and Its Changes During Annealing of Plasma-Sprayed YSZ, Surf. Coat. Technol., 2000, 127, p 120-129

    Article  Google Scholar 

  23. W.C. Oliver and G.M. Pharr, Improved Technique for Determining Hardness and Elastic Modulus Using Load and Displacement Sensing Indentation Experiments, J. Mater. Res., 1992, 7(6), p 1564-1580

    Article  Google Scholar 

  24. W.C. Oliver and G.M. Pharr, Measurement of Hardness and Elastic Modulus by Instrumented Indentation: Advances in Understanding and Refinements to Methodology, J. Mater. Res., 2004, 19(1), p 3-20

    Article  Google Scholar 

  25. K. VanEvery, M. Krane, R. Trice, H. Wang, W. Porter, M. Besser, D. Sordelet, J. Ilavsky, and J. Almer, Column Formation in Suspension Plasma-Sprayed Coatings and Resultant Thermal Properties, J. Therm. Spray Technol., 2011, 20, p 817-828

    Article  Google Scholar 

  26. R. Vert, Elaboration Par Projection Plasma d’un revêtement céramique sur un substrat métallique mince et de faible rugosité : Usage d’une sous-couche d’adhérence nanostructurée. PhD thesis, Université de Limoges, 2011, (in French)

  27. D.N. Argyriou and C.J. Howard, Reinvestigation of Yttria-Tetragonal Zirconia Polycrystal (Y-TZP) by Neutron Powder Diffraction—A Cautionary Tale, J. Appl. Crystallogr., 1995, 28, p 206-208

    Article  Google Scholar 

  28. R. Srinivasan, R. De Angelis, G. Ice, and B. Davis, Identification of Tetragonal and Cubic Structures of Zirconia Using Synchrotron X-Radiation Source, J. Mater. Res., 1991, 6, p 1287-1292

    Article  Google Scholar 

  29. J. Swab, Role of Oxide Additives in Stabilizing Zirconia for Coating Applications, Army Research Laboratory, 2001, ARL-TR-2591

  30. X. Xing, Thesis: Computational modeling study of yttria stabilized zirconia. PhD thesis. University College of London, 2010

  31. S. Giraud and J. Canel, Young’s Modulus of Some SOFCs Materials as a Function of Temperature, J. Eur. Ceram. Soc., 2008, 28, p 77-83

    Article  Google Scholar 

  32. R. Vert, D. Chicot, C. Dublanche-Tixier, E. Meillot, A. Vardelle, and G. Mariaux, Adhesion of YSZ Suspension Plasma-Sprayed Coating on Smooth and Thin Substrates, Surf. Coat. Technol., 2010, 205, p 999-1003

    Article  Google Scholar 

  33. R.S. Lima, A. Kucuk, and C.C. Berndt, Bimodal Distribution of Mechanical Properties on Plasma Sprayed Nanostructured Partially Stabilized Zirconia, Mater. Sci. Eng., 2002, A327, p 224-232

    Article  Google Scholar 

  34. P. Carpio, E. Rayón, L. Pawłowski, A. Cattini, R. Benavente, E. Bannier, M.D. Salvador, and E. Sánchez, Microstructure and Indentation Mechanical Properties of YSZ Nanostructured Coatings Obtained by Suspension Plasma Spraying, Surf. Coat. Technol., 2013, 220, p 237-243

    Article  Google Scholar 

  35. C.S. Ramachandran, V. Balasubramanian, P.V. Ananthapadmanabhan, and V. Viswabaskaran, Understanding the Dry Sliding Wear Behaviour of Atmospheric Plasma-Sprayed Rare Earth Oxide Coatings, Mater. Des., 2012, 39, p 234-252

    Article  Google Scholar 

  36. S. Jahanmir, Advanced Ceramics in Tribological Applications. Friction and Wear of Ceramics, S. Jahanmir, Ed., Marcel Dekker, 1994, p 3-12

  37. S.T. Aruna, N. Balaji, and K.S. Rajam, Phase Transformation and Wear Studies of Plasma Sprayed Yttria Stabilized Zirconia Coatings Containing Various mol% of Yttria, Mater. Charact., 2011, 62, p 697-705

    Article  Google Scholar 

  38. S.M. Wiederhorn, S.W. Freiman, E.R. Fuller, and C.J. Simmons, Effect of Water and Other Dielectrics on Crack Growth, J. Mater. Sci., 1982, 17, p 3460-3478

    Article  Google Scholar 

  39. T.A. Michalske and B.C. Bunker, Slow Fracture Model Based on Strained Silicate Structures, J. Appl. Phys., 1984, 56, p 2686

    Article  Google Scholar 

  40. R.K. Iler, The Chemistry of Silica, Wiley, New York, 1979, p 896

    Google Scholar 

  41. S. Nazarpour, C. López-Gándaraa, C. Zamania, J.M. Fernández-Sanjuán, F. Ramos, and A. Cirera, Phase Transformation Studies on YSZ Doped with Alumina. Part 2: Yttria Segregation, J. Alloys Compd., 2010, 505, p 534-554

    Article  Google Scholar 

  42. G. Witz, V. Shklover, W. Steurer, S. Bachegowda, and H. Bossmann, Phase Evolution in Yttria-Stabilized Zirconia Thermal Barrier Coatings Studied by Rietveld Refinement of X-Ray Powder Diffraction Patterns, J. Am. Ceram. Soc., 2007, 90(9), p 2935-2940

    Article  Google Scholar 

  43. B.D. Cullity, Elements of X-Ray Diffraction, 2nd ed., Addison-Wesley, Boston, 1978

    Google Scholar 

  44. S. Kuroda, T. Dendo, and S. Kitahara, Quenching Stress in Plasma Sprayed Coatings and Its Correlation with Deposit Microstructure, J. Therm. Spray Technol., 1995, 4(1), p 75-84

    Article  Google Scholar 

  45. A. Macwan. Residual Stresses in Suspension Plasma Sprayed Electrolytes in Metal-Supported Solid Oxide Fuel Cell. Master thesis. Ryerson University, Canada, 2012

  46. K. Kato and K. Adachi, Wear Mechanisms. Modern Tribology Handbook Vol. I, B. Bhushan, CRC, 2001, Chapter 7

Download references

Acknowledgements

The present investigation has been carried out with the support of the Scientific and Humanistic Development Council of the Universidad Central de Venezuela (CDCH-UCV) through the Projects No AIB-08-85-39-2012 and PG-08-8645-2013. Ms. S. Kossman gratefully acknowledges the financial support through the scholarship “Stages Master “received from University of Lille 1 to carry out part of the experiments in LML UST Lille and Arts et Métiers ParisTech, MSMP, Lille, France. Professor Puchi acknowledges the financial support of the Conseil Régional Nord-Pas de Calais, France through the International Chair Program 2011.

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to S. Kossman.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Kossman, S., Chicot, D., Decoopman, X. et al. Sliding Wear Response of Nanostructured YSZ Suspension Plasma-Sprayed Coating. J Therm Spray Tech 23, 1350–1361 (2014). https://doi.org/10.1007/s11666-014-0146-6

Download citation

  • Received:

  • Revised:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11666-014-0146-6

Keywords

Navigation