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Effect of Mn on the Formation of Oxide Buildups Upon HVOF-Sprayed MCrAlY-Ceramic-Type Cermet Coatings

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Abstract

Thermal spray coatings have been widely used on hearth rolls in a continuous annealing line to improve steel sheet quality and to prolong the roll service life. One of the common defects formed on a working hearth roll is the oxide buildup. HVOF-sprayed CoCrAlY-CrB2-Y2O3 coating was used in this study to duplicate buildups by reacting with Fe and Mn oxides. The reaction was performed in a furnace at 900 °C with inert gases flowing through. After reacting for 8 days, large Mn-rich buildups were formed on the coating while the buildups without Mn were very small. Mn was shown to enhance the formation of buildups. Buildups from a hearth roll were also examined and compared with the laboratory ones.

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References

  1. S. Midorikawa, S. Katoh, Cermet Powder for Sprayed Coating Excellent in Build-up Resistance and Roll Having Sprayed Coating Thereon, U.S. Patent 6572518, June 3, 2003

  2. J.E. Jackson, H. Nitta, K. Shoichi, M. Amano, Y. Kurisu, K. Ohno, Process for Forming a Refractory Oxide Coating, U.S. Patent 5418015, May 23, 1995

  3. W. Brandl, G. Marginean, D. Maghet, and D. Utu, Effects of Specimen Treatment and Surface Preparation on the Isothermal Oxidation Behaviour of the HVOF-sprayed MCrAlY Coatings, Surf. Coat. Technol, 2004, 188-189, p 20-26

    Article  CAS  Google Scholar 

  4. N. Yasuo, T. Suidzu, S. Hashimoto, Development of Thermal Spray Coatings for Hearth Rolls with Superior Build-up Resistance, The Third Baosteel Biennial Academic Conference, 2008, Sep. 26-28, 2008 (Shanghai, China), Vol 3, Shanghai Scientific and Technological Literature Publishing House, p J93-J98

  5. R. Hao, Developments and Practices of Thermal Spraying Technology in the Iron and Steel Industry in China, The Third Baosteel Biennial Academic Conference, 2008, Sep. 26-28, 2008 (Shanghai, China), Vol 3, Shanghai Scientific and Technological Literature Publishing House, p J74-J79.

  6. Y. Gao, Hearth Roll with Superior Endurance Capacity, U.S. Patent 5700423, Dec. 23, 1997.

  7. M. Hiroaki, T. Satoshi, A. Isao, Y. Noriyuki, S. Tatsuo, H. Sho, Thermal Spraying Powder, Thermal Spray Coating, and Hearth Roll, U.S. Patent 20080241522, Oct. 2, 2008.

  8. H. Huang, T. Zhang, J. Cheng, Y. Li, G. Bi, Y. Zhang, X. Tan, Development of Simulating Tester for Evaluation of Build-up Characterizing in CAL Hearth Rolls, op. cit. ref. 4, p J86-J92.

  9. H.H. Fukubayashi, Present Furnace and Pot Roll Coatings and Future Development, Thermal Spray 2004: Advances in Technology and Application, May 10-12, 2004 (Osaka, Japan), ASM International, 2004, p 125-131

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Correspondence to Tsai-Shang Huang.

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Huang, TS. Effect of Mn on the Formation of Oxide Buildups Upon HVOF-Sprayed MCrAlY-Ceramic-Type Cermet Coatings. J Therm Spray Tech 20, 447–455 (2011). https://doi.org/10.1007/s11666-010-9531-y

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  • DOI: https://doi.org/10.1007/s11666-010-9531-y

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