Yttria-stabilized zirconia (YSZ) has received great attention as a thermal barrier coating (TBC) material for its excellent thermal and mechanical properties. However, the grain growth of YSZ, particularly under temperatures higher than 1200 °C, limits its further applications to a great extent. In our present study, to develop better understanding of the aforementioned phenomenon and explore effective methods to conquer this challenge, TBCs using traditional and La2O3-modified YSZ powders were deposited by atmospheric plasma spraying and their microstructures were investigated. The results show that the La2O3 addition can effectively alleviate the grain growth of coatings under high temperatures.
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References
D.R. Clarke, S.R. Phillpot Thermal Barrier Coating Materials, Mater. Today, 2005, 8(6), p 22-29, in English
X.Q. Cao Application of Rare Earths in Thermal Barrier Coating Materials, J. Mater. Sci. Technol., 2007, 23(1), p 15-35, in English
F. Cernuschi, L. Lorenzoni, S. Ahmaniemi, P. Vuoristo, T. Mäntylä Studies of the Sintering Kinetics of Thick Thermal Barrier Coatings by Thermal Diffusivity Measurements, J. Euro. Ceram. Soc., 2005, 25(4), p 393-400, in English
A. Maricocchi, A. Bartz, D. Wortman PVD TBC Experience on GE Aircraft Engines, J. Therm. Spray Technol., 1997, 6(2), p 193-198, in English
N.P. Padture, M. Gell, E.H. Jordan Thermal Barrier Coatings for Gas-Turbine Engine Applications, Science, 2002, 296(4), p 280-284, in English
X.Q. Cao, R. Vassen, D. Stoever Ceramic Materials for Thermal Barrier Coatings, J. Eur. Ceram. Soc., 2004, 24(1), p 1-10, in English
S. Paul, I.O. Golosnoy, A. Cipitria, T.W. Clyne, L. Xie, and M.R. Dorfman, Effect of Heat Treatment on Pore Architecture and Associated Property Changes in Plasma Sprayed TBCs, Proceedings of the International Thermal Spray Conference 2007, 1st ed., B. Marple, M. Hyland, Y.C. Lau, C.J. Li, R. Lima, and G. Montavon, Eds., May 14-17, 2007 (Beijing, China), ASM International, 2007, p 411-416 (in English)
D.R. Clarke, C.G. Levi Materials Design for the Next Generation Thermal Barrier Coatings, Annu. Rev. Mater. Res. 2003, 33, p 383-417, in English
M. Matsumoto, N. Yamaguchi, H. Matsubara Low Thermal Conductivity and High Temperature Stability of ZrO2-Y2O3-La2O3 Coatings Produced by Electron Beam PVD, Scr. Mater. 2004, 50(6), p 867-871, in English
Y.F. Gao, Y. Masuda, K. Koumoto Micropatterning of Lanthanum-Based Oxide Thin Film on Self-Assembled Monolayers, J. Colloid Interf. Sci. 2004, 274(2), p 392-397, in English
B. Bastide, P. Odier, J.P. Coutures Phase Equilibrium and Martensitic Transformation in Lanthana-Doped Zirconia, J. Am. Ceram. Soc. 1988, 71(6), p. 449-453, in English
S.L. Hwan, I.W. Chen Grain Size Control of Tetragonal Zirconia Polycrystals Using the Space Charge Concept, J. Am. Ceram. Soc., 1990, 73(11), p 3269-3277, in English
Acknowledgments
The authors would like to thank Ms. J. H. Gao and Mr. W. Wu for the SEM and EDS measurements. YFG thanks the Century Program (One-Hundred-Talent Program) of the Chinese Academy of Sciences for special funding support.
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This article is an invited paper selected from presentations at the 2008 International Thermal Spray Conference and has been expanded from the original presentation. It is simultaneously published in Thermal Spray Crossing Borders, Proceedings of the 2008 International Thermal Spray Conference, Maastricht, The Netherlands, June 2-4, 2008, Basil R. Marple, Margaret M. Hyland, Yuk-Chiu Lau, Chang-Jiu Li, Rogerio S. Lima, and Ghislain Montavon, Ed., ASM International, Materials Park, OH, 2008.
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Liu, Y., Gao, Y., Tao, S. et al. Microstructure of Plasma Sprayed La2O3-Modified YSZ Coatings. J Therm Spray Tech 17, 603–607 (2008). https://doi.org/10.1007/s11666-008-9226-9
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DOI: https://doi.org/10.1007/s11666-008-9226-9