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Effect of Oxidation Behavior on the Mechanical and Thermal Properties of Plasma Sprayed Tungsten Coatings

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Abstract

Tungsten (W) coatings have been prepared via air (APS) and vacuum plasma spraying (VPS) technologies, respectively. The microstructures and chemical compositions of the coatings were comparatively studied; meanwhile, the mechanical and thermal properties were evaluated. The results obtained showed that oxide content in the VPS-W coating was apparently lower than that of the APS-W coating because of the different surrounding atmosphere, which influenced the mechanical and thermal properties of the coatings directly. Similar microstructures were observed for the VPS-W and the APS-W coating, but the VPS-W coating was much denser. The bonding strength of the VPS-W coating was much higher than that of the APS-W coating. Thermal conductivity of the VPS-W coating was 59.3 W/m · K at room temperature while the APS-W coating was 32.2 W/m  K. Thermal loading experiments of electron beam showed that the VPS-W coating could withstand the heat load of 10.75 MW/m2, while the APS-W coating formed serious cracks on its surface at the load of 7.5 MW/m2.

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References

  1. B. Vastra, B. Schedler, M. Merola, F. Jacquinot, A. Cottin, D. Cauvin, M. Febvre, Y. Leblanc, Manufacturing of Prototype Components for the ITER Divertor Baffle, Fusion Eng. Des., 2003, 66–68, p 341–346

    Article  CAS  Google Scholar 

  2. N. Yoshida, Review of Recent Works in Development and Evaluation of High-Z Plasma Facing Materials, J. Nucl. Mater., 1999, 266–269, p 197–206

    Article  CAS  Google Scholar 

  3. H. Maier, J. Luthin, M. Balden, J. Linke, F. Koch, H. Bolt, Properties of Tungsten Coatings Deposited onto Fine Grain Graphite by Different Methods, Surf. Coat. Technol., 2001, 142–144, p 733–737

    Article  CAS  Google Scholar 

  4. A. Cambe, E. Gauthier, J.M. Layet, S. Bentivegna, Development of Tungsten Coating for Fusion Applications, Fusion Eng. Des., 2001, 56–57, p 331–336

    Article  CAS  Google Scholar 

  5. S. Tamura, K. Tokunaga, N. Yoshida, Damage Process of Resolidified Part on CVD-W Coated Molybdenum under High Heat Load, J. Nucl. Mater., 2003, 313–316, p 250–254

    Article  CAS  Google Scholar 

  6. J. Matějíček, P. Chráska, J. Linke, Thermal Spray Coating for Fusion Applications-Review, J. Therm. Spray Technol., 2007, 16(1), 64–83

    Article  CAS  Google Scholar 

  7. T. Hirai, A. Kreter, J. Malzbender, T. Ohgo, V. Philipps, G. Pintsuk, A. Pospieszczyk, Y. Sakaw, G. Sergienko, T. Tanabe, Y. Ueda, M. Wada, Critical Heat Flux Loading Experiments on CVD-W Coating in the TEXTOR Tokamak, Fusion Eng. Des., 2006, 81, p 175–180

    Article  CAS  Google Scholar 

  8. K. Nakamura, S. Suzuki, T. Tanabe, M. Dairaku, K. Yokoyama, M. Akiba, Disruption Erosions of Various Kinds of Tungsten, Fusion Eng. Des., 1998, 39–40, p 295–301

    Article  CAS  Google Scholar 

  9. S. Deschka, C. Garcia-Rosales, W. Hohenauer, R. Duwe, E. Gauthier, J. Linke, M. Lochter, W. Mallener, L. Plöchl, P. Rödhammer, A. Salito, Manufacturing and High Heat Flux Loading of Tungsten Coatings on Fine Grain Graphite for the ASDEX-upgrade Divertor, J. Nucl. Mater., 1996, 233–237, p 645–649

    Article  CAS  Google Scholar 

  10. H. Maier, J. Luthin, M. Balden, S. Lindig, J. Linke, V. Rohde, H. Bolt, ASDEX Upgrade Team, Development of Tungsten Coated First Wall and High Heat Flux Components for Application in ASDEX Upgrade, J. Nucl. Mater., 2002, 307–311, p 116–120

    Article  CAS  Google Scholar 

  11. B. Riccardi, A. Pizzuto, A. Orsini, S. Libera, E. Visca, L. Bertamini, F. Casadei, E. Severini, R. Montanari, R. Vesprini, P. Varone, G. Filacchioni, and N. Litunovsky, Tungsten Thick Coatings for Plasma Facing Components, Proc. 18th Symp. Fusion Technology, B. Beaumont, P. Libeyre, B. de Gentile, and G. Tonon, Eds. (Marseille, France, CEA), 1998, p 223-226

  12. J. Matějíček, Y. Koza, V. Weinzettl, Plasma Sprayed Tungsten-based Coatings and their Performance under Fusion Relevant Conditions, Fusion Eng. Des., 2005, 75–79, p 395–399

    Article  CAS  Google Scholar 

  13. S. Boire-Lavigne, C. Moreau, R.G. Saint-Jacques, The Relationship between the Microstructure and Thermal Diffusivity of Plasma-sprayed Tungsten Coatings, J. Therm. Spray Technol., 1995, 4(3), p 261–267

    Article  CAS  Google Scholar 

  14. H. Greuner, H. Bolt, B. Böswirth, S. Lindig, W. Kühnlein, T. Huber, K. Sato, S. Suzuki, Vacuum Plasma-sprayed Tungsten on EUROFER and 316L: Results of Characterisation and Thermal Loading Tests, Fusion Eng. Des., 2005, 75–79, 333–338

    Article  CAS  Google Scholar 

  15. H.-K. Kang, Thermal Properties of Plasma-Sprayed Tungsten Deposits, J. Nucl. Mater., 2004, 335, p 1–4

    Article  CAS  Google Scholar 

  16. S.H. Leigh, C.K. Lin, C.C. Berndt, Elastic Response of Thermal Spray Deposits under Indentation Tests, J. Am. Ceram. Soc., 1997, 80(8), p 2093–2099

    Article  CAS  Google Scholar 

  17. PPMS-Hardware&Options Manuals, Quantum Design Co. Ltd., 2003, p 1-7

  18. J. Du, Z. Li, G. Liu, H. Zhou, C. Huang, Surface Characterization of CVD Tungsten Coating on Molybdenum Substrate, Surf. Coat. Technol., 2005, 198, p 169–172

    Article  CAS  Google Scholar 

  19. P. Wang, X. Li, C. Lu, T. Chen, G. Chen, S. Zhuo, G. Tao, H. Gu, L. Yu, Chemical and Structural Characterization for Advanced Inorganic Materials, 1st ed., Beijing: Higher Education Press, 2006, p 315–323 (in Chinese)

    Google Scholar 

  20. É. Hegetüs, J. Neugebauer, M. Mészáros, Apparent Reversibility of the β-w → α-w Transformation, Int. J. Refract. Met. Hard Mater., 1998, 16, p 31–35

    Article  Google Scholar 

  21. C. Bigey, L. Hilaire, G. Maire, Catalysis on Pd/WO3 and Pd/WO2: Effect of the Modifications of the Surface States Due to Redox Treatments on the Skeletal Rearrangement of Hydrocarbons, J. Catal., 1999, 184, p 406–420

    Article  CAS  Google Scholar 

  22. T. Polar, N.M.G. Parreira, A. Cavaleiro, Tungsten Oxide with Different Oxygen Contents: Sliding Properties, Vacuum, 2007, 81(11–12), p 1426–1429

    Article  CAS  Google Scholar 

  23. C. Huang, X. Zhou, C. Ding, Investigation of the Thermomechanical Properties of a Plasma-Sprayed Nanostructured Zirconia Coating, J. Eur. Ceram. Soc., 2003, 23(9), p 1449–1455

    Article  CAS  Google Scholar 

  24. P. Zhang, Thermal Spray Materials, 1st ed., National Defense Industry Press, Beijing, China, 2006, p 8–10 (in Chinese)

    Google Scholar 

  25. J. Matějíček, K. Neufuss, D. Kolman, O. Chumak, and V. Brožek, Development and Properties of Tungsten-based Coatings Sprayed by WSP, Proc. International Thermal Spray Conference (Basel, Switzerland), 2005, p 634-640

  26. N. Parreira, N. Carvalho, A. Cavaleiro, Synthesis, Structural and Mechanical Characterization of Sputtered Tungsten Oxide Coatings, Thin Solid Films, 2006, 510(1–2), p 191–196

    Article  CAS  Google Scholar 

  27. X.L. Zheng, S.R. Qiao, and X.P. Qin, Material Mechanical Properties, 2nd ed., Northwestern Polytechnical University Press, Xi’an, China, 2000, p 50, 54-56 (in Chinese)

  28. A. Kucuk, C.C. Berndt, U. Senturk, R.S. Lima, Influence of Plasma Spray Parameters on Mechanical Properties of Yttria Stabilized Zirconia Coatings. II: Acoustic Emission Response, Mater. Sci. Eng. A, 2000, 284(1–2), p 41–50

    Article  Google Scholar 

  29. R.G. Castro, A.H. Barlett, K.J. Hollis, R.D. Fields, The Effect of Substrate Temperature on the Thermal Diffusivity and Bonding Characteristics of Plasma Sprayed Beryllium, Fusion Eng. Des., 1997, 37, p 243–252

    Article  CAS  Google Scholar 

  30. B. Riccardi, R. Montanari, M. Casadei, G. Costanza, G. Filacchioni, A. Moriani, Optimisation and Characterisation of Tungsten Thick Coatings on Copper Based Alloy Substrates, J. Nucl. Mater., 2006, 352, p 29–35

    Article  CAS  Google Scholar 

  31. X. Liu, L. Yang, S. Tamura, K. Tokunaga, N. Yoshida, N. Noda, Z. Xu, Thermal Response of Plasma Sprayed Tungsten Coating to High Heat Flux, Fusion Eng. Des., 2004, 70, p 341–349

    Article  CAS  Google Scholar 

  32. S. Tamura, K. Tokunaga, N. Yoshida, M. Taniguchi, K. Ezato, K. Sato, S. Suzuki, M. Akiba, Y. Tsunekawa, M. Okumiya, Damage Process of High Purity Tungsten Coatings by Hydrogen Beam Heat Loads, J. Nucl. Mater., 2005, 337–339, p 1043–1047

    Article  CAS  Google Scholar 

  33. K. Tokunaga, N. Yoshida, N. Noda, T. Sogabe, T. Kato, High Heat Load Properties of Tungsten Coated Carbon Materials, J. Nucl. Mater., 1998, 258–263, p 998–1004

    Article  CAS  Google Scholar 

  34. K. Tokunaga, N. Yoshida, N. Noda, Y. Kubota, S. Inagaki, R. Sakamoto, T. Sogabe, L. Plöchl, Behavior of Plasma-Sprayed Tungsten Coatings on CFC and Graphite under High Heat Load, J. Nucl. Mater., 1999, 266–269, p 1224–1229

    Article  CAS  Google Scholar 

  35. Y.S. Touloukian, R.K. Kirby, R.E. Taylor, T.Y.R. Lee, Thermophysical Properties of Matter, Vol. 13, Thermal Expansion Nonmetallic Solids, IFI/Plenum Press, New York, 1975, p 405

    Google Scholar 

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Correspondence to Xuebin Zheng.

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Hu, D., Zheng, X., Niu, Y. et al. Effect of Oxidation Behavior on the Mechanical and Thermal Properties of Plasma Sprayed Tungsten Coatings. J Therm Spray Tech 17, 377–384 (2008). https://doi.org/10.1007/s11666-008-9190-4

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  • DOI: https://doi.org/10.1007/s11666-008-9190-4

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