Abstract
In this research, the effects of different amounts of titanium on the sinterability, microstructure, hardness, and flexural strength of spark plasma sintered hBN-based materials were studied. The addition of 20 wt.% Ti improved the relative density of hBN by almost 6% because of progressing a chemical reaction between Ti and the hBN matrix. Although the x-ray diffraction spectrums suggested the in-situ formation of TiN0.9, together with the TiB2 phase, further investigation revealed the diffusion of boron atoms from the TiB2 compound into the non-stoichiometric TiN0.9, creating Ti(N,B) solid solution. This phenomenon was also found to be responsible for improvements in the mechanical properties of the SPSed samples. The flexural strength of hBN was noticeably improved by incorporating titanium additive, benefiting from the in-situ formation of titanium diboride and Ti(N,B) compounds. The composite reinforced with 20 wt.% Ti secured the highest Vickers hardness (~ 95 VH0.1 kg) and flexural strength (~ 150 MPa).
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M. Abdolahpour Salari, G. Merhan Muğlu, M. Rezaei, M. Saravana Kumar, H. Pulikkalparambil, and S. Siengchin, In-Situ Synthesis of TiN and TiB2 Compounds during Reactive Spark Plasma Sintering of BN-Ti Composites, Syn. Sint., 2021, 1, p 48–53. https://doi.org/10.53063/synsint.2021.119
W.L. Du Frane, O. Cervantes, G.F. Ellsworth, and J.D. Kuntz, Consolidation of Cubic and Hexagonal Boron Nitride Composites, Diam. Relat. Mater., 2016, 62, p 30–41. https://doi.org/10.1016/j.diamond.2015.12.003
X.J. Gao, D.M. Yan, J.W. Cao, C. Zhang, X.M. Mu, Y.W. Zhou, M. Wang, F.Z. Qu, G. Bin Li, G.J. Wang, and D.J. Zhang, The Study on the Property and the Microstructure of Pressureless Sintered h-BN Ceramics, Adv. Mat. Res., 2015, 1104, p 9–14. https://doi.org/10.4028/www.scientific.net/amr.1104.9
X. Duan, D. Jia, Z. Wang, D. Cai, Z. Tian, Z. Yang, P. He, S. Wang, and Y. Zhou, Influence of Hot-Press Sintering Parameters on Microstructures and Mechanical Properties of h-BN Ceramics, J. Alloys Compd., 2016, 684, p 474–480. https://doi.org/10.1016/j.jallcom.2016.05.153
A. Lipp, K.A. Schwetz, and K. Hunold, Hexagonal Boron Nitride: Fabrication, Properties and Applications, J. Eur. Ceram. Soc., 1989, 5, p 3–9. https://doi.org/10.1016/0955-2219(89)90003-4
T.B. Wang, C.C. Jin, J. Yang, C.F. Hu, and T. Qiu, Physical and Mechanical Properties of Hexagonal Boron Nitride Ceramic Fabricated by Pressureless Sintering Without Additive, Adv. Appl. Ceram., 2015, 114, p 273–276. https://doi.org/10.1179/1743676114Y.0000000226
I. FarahBakhsh, R. Antiochia, and H.W. Jang, Pressureless Sinterability Study of ZrB2-SiC Composites Containing Hexagonal BN and Phenolic Resin Additives, Syn. Sint., 2021, 1, p 99–104. https://doi.org/10.53063/synsint.2021.1231
T. Hagio and H. Yoshida, Sintering and Crystallization of Ground Hexagonal Boron Nitride Powders, J. Mater. Sci. Lett., 1994, 13, p 653–655. https://doi.org/10.1007/BF00271224
H. Yang, F. Gao, M. Dai, D. Jia, Y. Zhou, and P. Hu, Recent Advances in Preparation, Properties and Device Applications of Twodimensional h-BN and its Vertical Heterostructures, J. Semicond., 2017 https://doi.org/10.1088/1674-4926/38/3/031004
T. Hagio, K. Kobayashi, H. Yoshida, H. Yasunaga, and H. Nishikawa, Sintering of the Mechanochemically Activated Powders of Hexagonal Boron Nitride, J. Am. Ceram. Soc., 1989, 72, p 1482–1484. https://doi.org/10.1111/j.1151-2916.1989.tb07682.x
B. Ertug, Powder Preparation, Properties and Industrial Applications of Hexagonal Boron Nitride, Sintering Applications. B. Ertug Ed., InTech, 2013. https://doi.org/10.5772/53325
C. Steinborn, M. Herrmann, U. Keitel, A. Schönecker, J. Räthel, D. Rafaja, and J. Eichler, Correlation Between Microstructure and Electrical Resistivity of Hexagonal Boron Nitride Ceramics, J. Eur. Ceram. Soc., 2013, 33, p 1225–1235. https://doi.org/10.1016/j.jeurceramsoc.2012.11.024
H. Yang, H. Fang, H. Yu, Y. Chen, L. Wang, W. Jiang, Y. Wu, and J. Li, Low Temperature Self-Densification of High Strength Bulk Hexagonal Boron Nitride, Nat. Commun., 2019 https://doi.org/10.1038/s41467-019-08580-9
N.S. Peighambardoust, Ç. Çevik, T. Assar, S. Jung, S.Y. Lee, and J.H. Cha, Pulsed Electric Current Sintering of TiB2-Based Ceramics Using Nitride Additives, Syn. Sint., 2021, 1, p 28–33. https://doi.org/10.53063/synsint.2021.1112
X. Duan, D. Jia, Z. Wu, Z. Tian, Z. Yang, S. Wang, and Y. Zhou, Effect of Sintering Pressure on the Texture of Hot-Press Sintered Hexagonal Boron Nitride Composite Ceramics, Scr. Mater., 2013, 68, p 104–107. https://doi.org/10.1016/j.scriptamat.2012.09.012
J.X. Xue, J.X. Liu, B.H. Xie, and G.J. Zhang, Pressure-Induced Preferential Grain Growth, Texture Development and Anisotropic Properties of Hot Pressed Hexagonal Boron Nitride Ceramics, Scr. Mater., 2011, 65, p 966–969. https://doi.org/10.1016/j.scriptamat.2011.08.025
S. Haghgooye Shafagh, S. Jafargholinejad, and S. Javadian, Beneficial Effect of low BN Additive on Densification and Mechanical Properties of Hot-Pressed ZrB2-SiC Composites, Syn. Sint., 2021, 1, p 69–75. https://doi.org/10.53063/synsint.2021.1224
T. Kusunose and T. Sekino, Thermal Conductivity of Hot-Pressed Hexagonal Boron Nitride, Scr. Mater., 2016, 124, p 138–141. https://doi.org/10.1016/j.scriptamat.2016.07.011
M. Hubacek and M. Ueki, Pressureless-Sintered Limited Content Boron of Boric Nitride Oxide, Mater. Sci. Res. Int., 1995, 1, p 209–212.
F.R. Zhai, M. Lu, K. Shan, Z.Z. Yi, and Z.P. Xie, Spark Plasma Sintering and Characterization of Mixed h-BN Powders with Different Grain Sizes, Solid State Phenomena, 2018, 281, p 414–419. https://doi.org/10.4028/www.scientific.net/SSP.281.414
F. Olevsky, P. Mogilevsky, E.Y. Gutmanas, and I. Gotman, Synthesis of In Situ TiB2/TiN Ceramic Matrix Composites from Dense BN-Ti and BN-Ti-Ni Powder Blends, Metall. Mater Trans, A Phys. Metall. Mater. Sci., 1996, 27, p 2071–2079. https://doi.org/10.1007/BF02651860
T. Saito and F. Honda, Chemical Contribution to Friction Behavior of Sintered Hexagonal Boron Nitride in Water, Wear, 2000, 237, p 253–260. https://doi.org/10.1016/S0043-1648(99)00346-4
Y. Cao, L. Du, C. Huang, W. Liu, and W. Zhang, Wear Behavior of Sintered Hexagonal Boron Nitride under Atmosphere and Water Vapor Ambiences, Appl. Surf. Sci., 2011, 257, p 10195–10200. https://doi.org/10.1016/j.apsusc.2011.07.018
M. Kitiwan, A. Ito, and T. Goto, Phase Transformation and Densification of hBN-TiN Composites Fabrication by Spark Plasma Sintering, Key Eng. Mater., 2012, 508, p 52–55. https://doi.org/10.4028/www.scientific.net/KEM.508.52
N. Ay and I. Tore, Pressureless Sintering of Hexagonal Boron Nitride Powders, Mater. Sci. Forum, 2007, 554, p 207–212. https://doi.org/10.4028/www.scientific.net/msf.554.207
S.A. Delbari, J. Lee, M. Sheikhlou, A.S. Namini, S. Jung, J.H. Cha, S.-H. Lee, R.S. Varma, H.W. Jang, and M. Shokouhimehr, Effect of IRON Nanoparticles on Spark Plasma Sinterability of ZrB2-Based Ceramics, J. Aust. Ceram. Soc., 2022, 58, p 1117–1128. https://doi.org/10.1007/s41779-022-00777-4
S.A. Delbari, A.S. Namini, S. Lee, S. Jung, J. Wang, S.-H. Lee, J.H. Cha, J.H. Cho, H.W. Jang, S.Y. Kim, and M. Shokouhimehr, Microstructural and Nanoindentation Study of TaN Incorporated ZrB2 and ZrB2-SiC Ceramics, Sci. Rep., 2022, 12, p 13765. https://doi.org/10.1038/s41598-022-17797-6
V.-H. Nguyen, M. Shahedi Asl, S.A. Delbari, Q. Van Le, A. Sabahi Namini, J.H. Cha, S.-H. Lee, H.W. Jang, M. Mustapha, M. Mohammadi, and M. Shokouhimehr, Microstructural Evolution during Spark Plasma Sintering of TiC-AlN-Graphene Ceramics, Int. J. Refract. Metals Hard Mater., 2021, 96, p 105496. https://doi.org/10.1016/j.ijrmhm.2021.105496
A. Sabahi Namini, S.A. Delbari, N. Baydogan, M. Vajdi, F. Sadegh Moghanlou, and M. Shahedi Asl, Spark Plasma Sinterability of TiC Ceramics with Different Nitride Additives, J. Taiwan Inst. Chem. Eng., 2021, 123, p 363–370. https://doi.org/10.1016/j.jtice.2021.05.004
H. Yu, A. Sabahi Namini, S.A. Delbari, M. Sheikhlou, A. Abdolmaleki, S. Jung, J. Lee, J. Wang, Q. Van Le, S.Y. Kim, H.W. Jang, and M. Shokouhimehr, Nanoindentation and TEM Investigation of Spark Plasma Sintered TiB2-SiC Composite, Ceram. Int., 2022, 48, p 20285–20293. https://doi.org/10.1016/j.ceramint.2022.03.309
M. Shahedi Asl, A. Sabahi Namini, S.A. Delbari, Q. Van Le, M. Shokouhimehr, and M. Mohammadi, A TEM Study on the Microstructure of Spark Plasma Sintered ZrB2-Based Composite with Nano-Sized SiC Dopant, Prog. Nat. Sci. Mater. Int., 2021, 31, p 47–54. https://doi.org/10.1016/j.pnsc.2020.11.010
S. Jafargholinejad and S. Soleymani, Effects of Carbon Nano-Additives on Characteristics of TiC Ceramics Prepared by Field-Assisted Sintering, Syn. Sint., 2021, 1, p 62–68. https://doi.org/10.53063/synsint.2021.1123
V.-H. Nguyen, S.A. Delbari, M. Shahedi Asl, Q. Van Le, Z. Ahmadi, M. Farvizi, M. Mohammadi, M. Shokouhimehr, and A. Sabahi Namini, ZrB2SiCw Composites with Different Carbonaceous Additives, Int. J. Refract. Metals. Hard Mater., 2021, 95, p 105457. https://doi.org/10.1016/j.ijrmhm.2020.105457
S.A. Delbari, M.S. Shakeri, I. Salahshoori, M. Shahedi Asl, A. Sabahi Namini, A. Abdolmaleki, M. Sheikhlou, M. Farvizi, H.W. Jang, and M. Shokouhimehr, Characterization of TiC Ceramics with SiC and/or WC Additives Using Electron Microscopy and Electron Probe Micro-Analysis, J. Taiwan Inst. Chem. Eng., 2021, 123, p 245–253. https://doi.org/10.1016/j.jtice.2021.05.039
H. Yu, A. Sabahi Namini, S.A. Delbari, Q. Van Le, D. Kim, J.H. Cha, S.-H. Lee, S.Y. Kim, H.W. Jang, and M. Shokouhimehr, Microstructure of Spark Plasma Sintered TiC-TiB2-SiCw Composite, Mater. Chem. Phys., 2022, 281, p 125877. https://doi.org/10.1016/j.matchemphys.2022.125877
Z. Bahararjmand, M.A. Khalilzadeh, F. Saberi-Movahed, T.H. Lee, J. Wang, S. Lee, and H.W. Jang, Role of Si3N4 on Microstructure and Hardness of Hot-Pressed ZrB2-SiC Composites, Syn. Sint., 2021, 1, p 34–40. https://doi.org/10.53063/synsint.2021.1113
H. Yu, M.S. Shakeri, A. Sabahi Namini, S.A. Delbari, Q. Van Le, J. Lee, S.Y. Kim, S.-H. Lee, H.W. Jang, Z. Swiatkowska-Warkocka, and M. Shokouhimehr, HRTEM and XPS Characterizations for Probable Formation of TiBxNy Solid Solution during Sintering Process of TiB2-20SiC-5Si3N4 Composite, Mater. Chem. Phys., 2022, 288, p 126380. https://doi.org/10.1016/j.matchemphys.2022.126380
M. Kitiwan, A. Ito, and T. Goto, B Deficiency in TiB2 and B solid Solution in TiN in TiN-TiB2 Composites Prepared by spark Plasma SINTERING, J. Eur. Ceram. Soc., 2012, 32, p 4021–4024. https://doi.org/10.1016/j.jeurceramsoc.2012.06.024
M. Shokouhimehr, S.A. Delbari, A.S. Namini, E. Taghizadeh, S. Jung, J.H. Cho, Q. Van Le, J.H. Cha, S.Y. Kim, and H.W. Jang, Nanostructure and Nanoindentation Study of Pulse Electric-Current Sintered TiB2-SiC-Cf Composite, Sci. Rep., 2023, 13, p 379. https://doi.org/10.1038/s41598-022-27186-8
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Li, Y., Liu, D., Zhang, B. et al. Hardening and Strengthening Effects Induced by Incorporation of Titanium in Hexagonal Boron Nitride Ceramics. J. of Materi Eng and Perform (2024). https://doi.org/10.1007/s11665-024-09516-1
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DOI: https://doi.org/10.1007/s11665-024-09516-1