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Enhanced Energy Storage Characteristics of Bi(Mg0.5Ce0.5)O3 Modified (Sr0.7Bi0.2)TiO3 Lead-Free Ceramics

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Abstract

(1 − x)Sr0.7Bi0.2TiO3-xBi(Mg0.5Ce0.5)O3 (x = 0.02, 0.04, 0.06, and 0.1) ceramics were prepared through the solid-state reaction method. Structural, microstructural, dielectric, and energy storage characteristics were thoroughly examined. A dense microstructure with a single perovskite phase was obtained for x ≤ 0.06. A high energy storage density of ~ 1.86 J/cm3, recoverable energy density of ~ 1.67 J/cm3, and a high efficiency of ~ 90% at a breakdown electric field strength of 240 kV/cm were achieved for x = 0.06. Further, this composition also shows a ΔC/C25°C in the range of − 55 to 135 °C. The above characteristics indicate that this material is a suitable candidate for power-pulsed capacitor applications.

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Acknowledgments

The financial support extended by Higher Education Commission (HEC), Islamabad Pakistan through the Local Challenge Fund (20-LCF-5/RGM/RF&D/HEC/2020) and National Research Program for Universities (Ref No. 20-17387/NRPU/R&D/HEC/2021 2021) for this work is highly acknowledged.

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Authors and Affiliations

  1. Laboratory for Research in Advanced Materials, Department of Physics, University of Science & Technology Bannu, Bannu, 28100, Khyber Pakhtunkhwa, Pakistan

    Murad Ali Khan, Abdul Manan, Maqbool Ur Rehman, Hidayat Ullah Shah & Sami Ullah Khan

  2. Department of Chemistry, University of Science & Technology Bannu, Bannu, 28100, Khyber Pakhtunkhwa, Pakistan

    Shah Faisal

  3. Department of Physics, Khushal Khan Khattak University Karak, Karak, Khyber Pakhtunkhwa, Pakistan

    Abdul Hakim Shah

  4. Department of Physics, College of Science, Qassim University, Buraidah, Saudi Arabia

    Faisal Alresheedi

  5. National Center of Excellence in Physical Chemistry, University of Peshawar, Peshawar, 25120, Khyber Pakhtunkhwa, Pakistan

    Zahid Ali Ghazi

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Khan, M.A., Manan, A., Ur Rehman, M. et al. Enhanced Energy Storage Characteristics of Bi(Mg0.5Ce0.5)O3 Modified (Sr0.7Bi0.2)TiO3 Lead-Free Ceramics. J. of Materi Eng and Perform 33, 1538–1547 (2024). https://doi.org/10.1007/s11665-023-08622-w

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